FTIR GAS

2005.9.15
HORIBA, Ltd.

FTIR

Fourier Transform Infrared Spectrometer .

Fourier .

Sample,
Sample ( ) ,
Sample ( ), Sample
( ) .

0.0004nm 0.001nm

10nm 20nm

380nm

780nm

0.22mm 1mm

2.5m

25m

1mm

Sample .
spectrum .

0.7m

FTIR

100km

moment

moment

,
, ,
, ,
.

.
,

. ,
moment
, gas,
,, .

Prism

(Grating

Fourier

.
()
() ,
,
.

, fourier .
, Fourier

FOURIER
Fourier
Fourier
Jean Baptiste Joseph Fourier, 1768-1830
. , fourier
.

Fourier, ()
Interferogram,
.
() , Fourier
.
.
Fourier .

xe-j2xdx

SPECTRE

,
.
, .
.

1.0

0.5

0.0

5000

4500

4000

3500

3000
(cm-1)

2500

2000

1500

1000

SPECTRE

.
, ,
cm-1. ,
.
.
(-1)

DATA
.

SPECTRE

Power Spectrum Power Spectrum

Transmittance
Linear
Absorbance

Power Spectrum

SPECTRE

CELL

CELL

Sample

.
.

Sample power spectrum Background spectrum

. , Power spectrum
.

. ,
.

Beam splitter(
) ,
,
beam splitter
. type FTIR
.
Beam splitter


SCAN
SCAN
SCAN
. SCAN,
, ,
.

SCAN,
COS
.

.
, .

-d

+d

INTERFEROGAM .

 CENTER BURST

,
, .

.

CENTERBURST
BURST
CENTER
INTERFEROGAM
CENATER BURST .
Interferogam .
Center burst .
aliment
throughputcell ,
Sample

Fourier

-d

Interferogam
Interferogam

Power
spectrum
spectrum

()
)

1/t
1/t (Hz)

(cm)

1/
(cm-1)
1/

interferogam

(cm)

+d

Power spectrum

Fourier

cm-1

FTIR

Sample

,
,

Amp ,

,
CPU Fourier

FG-1XX
GasIn
GasOut

purge area
Gas cell
Gas cell
unit

Beam splitter

.

.

.

unit

Gas cell
cell
cell

mm cell

Whitecell
cell
White

mmm cell

Cell

FTIR
9

z
z
z

,
slit
Scan ,

9
z
9
z Scan
9
z

cell(
.
.
)
,
. ,
range .0.60
0.50
Absorbance

,

peak
,

gas

0.40

0.20
0.10
0.00
1300

1250

Wavenumber (cm-1)

1100

1050

, range
.

Zero gas

zero gas
cell .
.

Back ground

Back ground .

Sample gas

Sample gas cell .

Sample gas ,
.


Absorbance

0.30

0.00
1400 1300
1000 900
Wavenumber (cm-1)

Absorbance

gas peak
,

.

( ) peak

Search software

0.30
.

0.30

0.00
1400

0.00
1400 1300
1000 900
Wavenumber (cm-1)

1300

Absorbance

Absorbance

0.30

1000
Wavenumber (cm-1)

900

0.00
1400 1300
1000 900
Wavenumber (cm-1)