Bi Tp Cn Bng Oxi Ha Kh

Bi 1: (HPT-163-164) Cho E0(Fe3+/Fe2+) = 0,771V v E0(Ag+/Ag) = 0,779V ; E0(MnO4-/Mn2+) = 1,51V ; E0(Cl2/Cl-) =

1,359V ; E0(S/S2-) = -0,48V v pka1(H2S)=7,02 ; pka2(H2S) =12,9 . Tnh hng s cn bng ca phn ng sau:
Fe3+ + Ag Fe2+ + Ag ; K1
2MnO4- + 16H+ + 10Cl- 2Mn2+ + 5Cl2 + H2O ; K2
Fe3+ + H2S 2Fe2+ + S + 2H+ ; K3
Bi 2: (HPT-165) E0(Fe3+/Fe2+) = 0,771V v E0(Fe2+/Fe) = -0,44V ; E0(H2O2,H+/H2O) = 1,77V , E0(O2,H+/H2O) = 1,23V;
lg[FeF2+] = 5,18. Tnh E0(Fe3+/Fe) ; E0 (O2,H+/H2O2) ; E0(FeF2+/Fe) ; E0(FeF2+/Fe2+)
Bi 3: Cho dung dch cha hn hp gm Fe2+ 0,1M v Ce4+ 0,01M .Tnh nng cn bng cc ion trong dung dch .Bit
E0(Fe3+/Fe2+) = 0,68V ; E0(Ce4+/Ce3+) = 1,44V. Tnh th ca dung dch ti thi im cn bng
Bi 4: Chun 100ml dung dch FeSO4 0,01M v Fe2(SO4)3 0,02M bng dung dch Ce(SO4)2 0,02M pH = 0 .Tnh th
ca dung dch chun sau khi thm 49,00 ml ; 50,00 ml ; 51,00 ml. Bit E 0(Fe3+/Fe2+) = 0,68V ; E0(Ce4+/Ce3+) = 1,44V
Bi 5: Cho E0(PbSO4/Pb) = -0,356V ; E0 (Pb2+/Pb)= -0,126V .Tnh T(PbSO4).
Bi 6: (GT-100) Lp biu thc tnh E(Cr 2O72-,H+/Cr3+) theo pH bit E0(Cr2O72-,H+/Cr3+) = 1,36V
Bi 7: (GT-100) Tnh E(AsO43-/AsO32-) trong mi trng NaHCO3 c pH=8. Bit E0(AsO43-/AsO32-) = 0,57V
Bi 8: (GT-101) Lp biu thc tnh E(S/S2-) theo pH . Bit E0(S/S2-) = -0,48V , pka1(H2S) = 7,02 ; pka2(H2S) = 12,9.
Bi 9: (GT-102) Tnh E(Fe3+/Fe2+) trong dung dch cha NaF 0,01M .Bit E0(Fe3+/Fe2+) = 0,771V v ; lg[FeF2+] = 5,2 ;
lg[FeF2+] = 9,2 ; lg[FeF3] = 12.
Bi 10: (GT-103) Tnh E(Cu2+/Cu+) khi them I- to kt ta CuI vi T(CuI) = 10-12 .Bit E0(Cu2+/Cu+) = 0,17V v [I-] = 1M
Bi 11: (HPT- 174) Lp biu thc tnh E(Co(OH) 3/Co(OH)2) theo pH . Bit E0(Co(OH)3/Co(OH)2) = 1,33V
Bi 12: (HPT-179) nh gi kh nng oxy ha ca Fe3+ i vi I- khi c mt ca F- (CF- >> CFe3+). Bit lg[FeF3] = 12 ;
E0(Fe3+/Fe2+) = 0,771V ; E0(I2/2I-) = 0,54V.
Bi 13: (HPT-180) nh gi kh nng oxy ha I- bi Fe(CN)63- . Bit lg[Fe(CN)63-] = 42 v E0(Fe3+/Fe2+) = 0,771V ;
E0(I2/2I-) = 0,54V.
Bi 14: (HPT-181) D on chiu hng phn ng : Cu2+ + I- CuI . Bit E0(Cu2+/Cu+) = 0,153V ; E0(I2/2I-) = 0,5355V
v pT(CuI) = 12
Bi 15: (K61-M 613) Tnh hng s bn 4 ca phc gia Cu2+ v NH3 khi them NH3 1M vo v xc nh c
E0(Cu2+/Cu) = -0,07V .Coi cc gi tr 1,2 ,3 << 4.
Bi 16: (K66-M6603) Theo gi tr in th oxy ha kh chun ca cp MnO 2/Mn2+ v ca cp Cl2/2Cl- th gia phn
chng xy ra theo chiu no? Ti sao trong phng th nghim ngi ta c th iu ch c kh Cl 2 t HCl c (13N) v
MnO2. Bit E0(MnO2/Mn2+) = 1,23V v E0(Cl2/2Cl-) = 1,36V
Bi 17: (K66-M6606) Xc nh chiu hng ca phn ng , Vit phng trnh phn ng v tnh hng s cn bng khi
cho 10,00ml dung dch KI 0,12M trn vi 10,00ml dung dch A cha Fe(ClO4)2 0,01M ; Fe(ClO4)3 0,14M v Na2H2Y
0,3M trong iu kin 250C v pH = 9.

Bi 18: (K51) Nhng mt si dy Ag vo dung dch AgNO3 ( dung dch A) th in cc o c l 0,682V. Nu thm
0,8ml dung dch HCl 36% (d=1,18g/ml) vo 100ml dung dch A th pH ca dung dch thu c l bao nhiu ? V c hin
tng g xy ra , gii thch ? Cho pT(AgCl) = 16 ; pT(Ag(OH)) = 8 v E 0(Ag+/Ag) = 0,80V
Bi tp t cc thi HSG THPT:
Bi 2: (T207-208) Cho E0(Cu2+/Cu) = 0,15 V ; E0(I2/2I-) = 0,62 V
a, Vit cc phng trnh phn ng oxy ha kh v phng trnh Nernst tng ng , iu kin chun c th xy ra s oxy
ha I- bng Cu2+ khng ?
b, Khi dung dch KI vo dung dch Cu2+ thy c phn ng : Cu2+ + 2I- CuI + I2 . Hy xc nh hng s cn bng
ca phn ng trn bit T(CuI) = 10-12
/s: a, Khng xy ra ; b, K = 104
Bi 3: (T209) Cho bit chiu hng ca phn ng sau : 2FeF3 + 2I- 2Fe2+ + I2 + 6FBit E0(Fe3+/Fe2+) = 0,77V ; E0(I2/2I-) = 0,54V ; Fe3+ + 3F- FeF3 , 3 = 1012,06 (B qua cc qu trnh to phc khc ca
Fe3+ v Fe2+)
/s : Xy ra theo chiu nghch .
Bi 9: (T230-231) Xt phn ng: Cu(r) + 2Fe3+(d.d) Cu2+ (d.d) + Fe2+ (d.d)
Trong dung dch gm CuSO4 1N , FeSO4 0,025N , Fe2(SO4)3 0,25N .
a, phn ng xy ra theo chiu no ? Tnh hng s cn bng ca phn ng.
b, Tnh t l [Fe3+]/[Fe2+] phn ng i chiu ? Bit E0(Fe3+/Fe2+) = 0,77V ; E0(Cu2+/Cu) = 0,34V.
/s : a, Phn ng xy ra theo chiu thun , K = 3,77.1014
b, [Fe3+]/[Fe2+] < 3,6.10-8
Bi 15: (T274) Cho E0( MnO4-,H+/MnO42-) = 0,56V ; E0(MnO42-,H+/MnO2) = 2,26V ; E0(MnO2,H+/Mn3+) = 0,95V ;
E0(Mn3+/Mn2+) = 1,51V. Tnh E0(MnO4-,H+/Mn2+) ; E0(MnO2,H+/Mn2+) ; E0(MnO4-,H+/MnO2)
/s: E0(MnO4-,H+/Mn2+) = 1,51V ; E0(MnO2,H+/Mn2+) = 1,23V ; E0(MnO4-,H+/MnO2) = 1,697V
Bi 22: (T302) xc nh T(AgCl) ngi ta thit lp mt pin ( 25 oC):
(-)Ag, AgCl(r)| HCl (d.d) | Cl2(k) ,Pt(r) (+)
P(Cl2) = 1atm , Sc in ng ca pin bng 1,15V . Bit E0(Ag+/Ag) = 0,8V , E0(Cl2/2Cl-) = 1,36V. Tnh T(AgCl) 25oC.
/s: T(AgCl) = 10-10
Bi 24: (T321-322) Cho 2 cp oxy ha kh: O2/H2O c E01 = 1,23V ; Ag+/Ag c E02 = 0,779V ; Kn = 10-14. Tnh
E0(O2/H2O) v cho bit Ag c kh nng tan trong nc c ha tan O 2 hay khng ?
/s: E0(O2/H2O) = 0,404V ; Ag khng c kh nng tan trong nc c ha tan O2.
Bi 38: (T190-191)Cho T(Fe(OH)2)= 1,65.10-15;T(Fe(OH)3)= 3,8.10-38;E0(Fe3+/Fe) = -0,04V,E0(Fe2+/Fe) = -0,44V Gii
thch ti sao trong dung dch kim , mui Fe(II) li c kh nng kh mnh hn so vi trong nc.
/s: E0(Fe3+/Fe2+) > E0( Fe(OH)3/Fe(OH)2)

Bi 40: (T213-214) Xt chiu ca phn ng: Cu2+ + 4I- 2CuI + I2 . Bit E0(Cu2+/Cu+) = 0,17V ; E0(I2/2I-) = 0,54 ;
T(CuI) = 10-12
/s : Xy ra theo chiu thun.
Bi 42: (T337) Cho E0(Fe2+/Fe) = -0,44V , E0(Fe3+/Fe2+) = -0,04V ; T ( Fe(OH)2 ) = 10-14 , T(Fe(OH)3) = 10-36 . Tnh
E(Fe3+/Fe2+) trong mi trng c [OH-] = 1M.
/s E = -0,538V
Bi 43: (T338) Tnh nng mol ban u (CM) ca HSO4- ( pka = 2 ). Bit gi tr ca sc in ng ca pin 25oC l
0,824V v s pin: Pt | I- 0,1M; I3- 0,02M || MnO4- 0,05M; Mn2+ 0,01M ; HSO4- CM | Pt
Bit E0(MnO4-/Mn2+) = 1,51V , E0(I3-/I-) = 0,5355V
/s: CM = 0,336M
Bi 45: (T342-343) nh gi chiu hng phn ng v tnh nng cc ion ti thi im cn bng trong dung dch cha
Fe2+ 0,1M v KMnO4 0,1M pH = 2,0 ? Bit E0(Fe3+/Fe2+) = 0,771V , E0(MnO4-/Mn2+) = 1,51V . Hng s to phc
hidroxy : (Fe(OH)2+) = 10-2,17 , (Fe(OH)+) = 10-5,92 , (Mn(OH)+) = 10-10,6
/s : Fe2+ b oxy ha trong KMnO4 pH = 2 do E(Fe3+/Fe2+) = 0,758V cn E(MnO4-/Mn2+) = 1,321V
[Fe2+] = 2,3.10-11 M, [Fe3+] = 6.10-2 M, [MnO4-] = 0,08M , [Mn2+] = 0,02M
Bi 47: (T349) Trn ng th tch hai dung dch SnCl2 0,1M v FeCl3 0,1M . Tnh nng cc ion ti thi im cn bng
v th ca cc cp oxy ha kh khi cn bng . Bit E 0(Sn4+/Sn2+) = 0,15V , E0(Fe3+/Fe2+) = 0,77V
/s: [Fe2+] = 0,05M ; [Sn4+] = 0,025M ; [Sn2+] = 0,025M ; [Fe3+] = 1,58.10-12 ; Ecb = 0,15V
Bi 48: (T349) Nhng mt si bc vo dung dch Fe2(SO4)3 2,5.10-2 M . Xc nh nng cn bng ca cc ion trong
dung dch v th ca cc cp oxy ha kh khi cn bng . Bit E 0(Fe3+/Fe2+) = 0,77V , E0(Ag+/Ag) = 0,8V
/s : [Ag+] = [Fe2+] = 4,38.10-2 M , [Fe3+] = 6.10-3 M . Ecb = 0,72V
Bi 53: (T381) Mt pin gm 2 in cc : in cc 1: gm 1 thanh ng nhng vo dung dch Cu 2+ nng 0,01M. in
cc 2 gm 1 thanh ng nhng trong dung dch [Cu(NH3)4]2+ 0,01M . Sc in ng ca pin 25oC l 38mV. Tnh hng
s bn to phc [Cu(NH3)4]2+ ( [Cu(NH3)4]2+ ).
/s: [Cu(NH3)4]2+ = 1,02.1012
Bi 54: (T392-393) Cho dung dch X gm Na2S 0,01M , KI 0,06M , Na2SO4 0,05M
a, Tnh pH ca dung dch X
b, Thm dn Pb(NO3)2 vo dung dch X n nng 0,09M th thu c kt ta A v dung dch B. Xc nh thnh phn
ca kt ta A.
c, Axit ha chm dung dch A n pH=0 . Thm FeCl3 n nng 0,1M . Tnh th ca in cc Platin nhng vo dung
dch thu c so vi in cc calomen bo ha (Hg2Cl2/2Hg, 2Cl-)
Cho pka1(H2S) = 7 , pka2(H2S) = 12,9 ; pka(HSO4-) = 2; pT(PbS) = 26 , pT(PbSO4) = 7,8 , pT(PbI2) = 7,6 ; E0(Fe3+/Fe2+) =
0,77V , E0(S/H2S) = 0,14V , E0(I2/2I-) = 0,54V , Ecal bo ha = 0,244V
p n: a, pH = 11,95 ; b, PbS 0,01 mol , PbI2 0,03 mol , PbSO4 005 mol. c, E = 0,499V

Bi 57: (T408-409) Cho cn bng sau 25oC: 2Cr2+ + Cd2+ 2Cr3+ + Cd

Bit E0(Cr3+/Cr2+) = -0,41V , E0(Cd2+/Cd) = -0,4V
a, iu kin tiu chun (25oC) phn ng xy ra theo chiu no?
b, Trn 25ml dung dch Cr(NO3)3 0,4M vi 50ml dung dch Cr(NO3)2 0,02M , 25ml dung dch Cd(NO3)2 0,04M v bt
Cd .Hi phn ng s din ra theo chiu no?
/s: a, Chiu thun ; b, chiu nghch
Bi 65: (T447) Cho E0(Hg22+/Hg) = 0,8V , E0(Hg2+/Hg22+)= 0,91V , T(HgS) = 4.10-53
a, Tnh hng s cn bng ca phn ng Hg22+ Hg + Hg2+ ; K1
b, C hin tng g xy ra khi choNa2S vo Hg2(NO3)2 ? Gii thch.
/s: a, K1 = 1,36.10-2

b, to thnh HgS v Hg kt ta c mu en.

Bi 66: (T458) Nhng Ag vo dung dch HI th c gii phng kh H2 khng ? Bit P(H2) = 1atm , T(AgI) = 8.10-17 v
E0(Ag+/Ag) = 0,8V
/s: C gii phng H2
Bi 67: (T464) Cho phn ng : Fe2+ + Ag+ Fe3+ + Ag
Bit: E0(Ag+/Ag) = 0,8V , E0(Fe3+/Fe2+)=0,77V
a, Xc nh chiu phn ng ca phn ng trn 250C v tnh hs cn bng
b, Xc nh chiu ca phn ng xy ra trong dung dch Fe3+ 0,1M ; Fe2+ 0,01M v Ag+ 0,01M khi cho bt bc kim loi vo
dung dch.
/s: a, Xy ra theo chiu thun K=3,16 ;

b, Xy ra theo nghch

Bi 71: (T469) Tnh E0(MnO4-/Mn2+) v E0(Fe3+/Fe2+) t E0(MnO4-/MnO2) = 1,70V ,E0(MnO2/Mn2+) = 1,23V ; E0(Fe3+/Fe)
= -0,037V , E0(Fe2+/Fe) = -0,44V.
/s: E0(MnO4-/Mn2+) = 1,51V v E0(Fe3+/Fe2+) = 0,77V
Bi 72: (T470) Xt qu trnh chun 10ml dung dch Fe2+ 0,1M bng V(ml) dung dch MnO4- 0,01M trong mi trng
c pH=0 khng i . Gi E l th ca in cc gm thanh Platin nhng vo dung dch chun . Tnh gi tr ca E khi
V1 = 15ml v V2 = 40ml
/s: E1 = 0,798V ; E2= 1,51V
Bi 73: (T478) loi tr NO3- trong nc c th kh n thnh NO2- bng cch cho i qua li cha bt Cd.
a, Vit phng trnh phn ng ca 2 cp NO3-/HNO2 v HNO2/NO trong mi trng acid. Chng minh rng HNO2 b phn
hy trong mi trng pH t 0 6
b, pH = 7 ; C(NO3-) = 10-2M . Hi NO3- c b kh hon ton trong iu kin ny khng .? Tnh nng ca NO3- cn
trong nc khi cn bng .
c, Tnh E0(NO3-/NO2-) pH = 14 v 250C .
Bit E0(NO3-/HNO2) =0,94V;E0(HNO2/NO) =0,98V;E0(Cd2+/Cd) = -0,4V;ka(HNO2)=5.10-4;T(Cd(OH)2)=1.2.10-14

/s:
a,3HNO2 NO3- + NO + H+ + H2O ; pH=06 th E0(HNO2/NO) > E0(NO3-/HNO2) nn HNO2 vn b phn hy .
b, P/ Cd + NO3- + H2O Cd2+ + NO2- + 2OH- ; K = 1,325.1014 [NO3-] = 7,55.10-33 M.NO3- b kh hon ton
c, E0(NO3-/HNO2) = 0,017V.
Bi 76: (T496/542)
a,Cho E0(AgBr/Ag) = 0,0713V ; E0(Ag+ / Ag) = 0,7996V . Tnh T(AgBr)
b, Cho E0(HIO/I2) = 1,45V ; E0(I2/2I-) = 0,54V ; E0(IO3-/I2) = 1,20V. Tnh hng s cn bng ca phn ng:
3HIO HIO3 + 2HI ; K
/s: a, T = 4,8.10-13 ; b, K = 2,018.10-10
Bi 79: (T537) Mt dung dch cha CuSO4 0,1M , NaCl 0,2M ; Cu d v CuCl2 d
a, D on chiu hng phn ng : Cu + Cu2+ + 2Cl- 2CuCl ; K
b, Tnh K v nng cc ion trong dung dch ti thi im cn bng .
Bit pT(CuCl) = 7 ; E0(Cu2+/Cu) = 0,15V , E0(Cu+/Cu) = 0,52V
/s: a, Xy ra theo chiu thun ; b, K = 107,73 , [Cu2+] = 1,67.10-3M , [Cl-] = 3,34.10-3M
Bi 81: (T553-554) Cc ion Co2+ v Co3+ u c kh nng to phc hexamine vi NH3 Vi cc hng s bn ln lt l
lg1=5 , lg2 = 34. Chng minh rng Co3+ khng bn trong nc v bn trong dung dch NH3 ([NH3]=1M). Bit nc
E0(Co3+/Co2+) = 1,82V ; E0(O2/H2O) = 1,23V
/s: Trong nc E0(Co3+/Co2+) > E0(O2/H2O) ; Trong mi trng NH3 E(Co3+/Co2+) = 1,09 < E0(O2/H2O)
Bi 82: (T558) D on kh nng tan ca CuS trong dung dch HCl c mt H2O2 v ca HgS trong HNO3. Cho
E0(H2O2/H2O) = 1,77V , E0(S/H2S) = 0,14V, E0(NO3-/NO) = 0,96V; pT(CuS) = 35,2 , pT(HgS) = 51,8 ; pka1(H2S) = 7 ,
pka2(H2S) = 12,92.
/s: CuS tan tt , HgS kh tan .
Bi 95: (T662) Cho E0(Zn(CN)42-/Zn) = -1,26V ; E0(Ag(CN)2-/Ag) = -0,31V ; E0(Au(CN)2-/Au) = -0,6V ; hng s to phc
(Au(CN)2-) = 4.1028.
a, Lm bay hi 500ml dung dch cha Ag(CN)2- 3.10-3 M v Au(CN)2- 10-2 M cho n th tch dung dch ban u ri x
l vi 65mg Zn . Hy tnh nng ca cc ion Au(CN) 2- v Ag(CN)2- sau khi phn ng kt thc.
b, Cn thit lp nng CN- trong dung dch Au(CN)2- l bao nhiu 99% vng tn ti di dng phc Au(CN)2- .
/s: a, [Ag(CN)2]- = 8,7.10-17M , [Au(CN)2-] = 0,019M ; b, [CN-] = 5.10-14M
Bi 99: (T720-727)
a, Cho E0(Cu2+/Cu) = 0,337V , E0(Cu(NH3)42+/Cu) = -0,07V .Tnh (Cu(NH3)42+)
b, Cho E0(2IO4-/I2(r)) = 1,31V , E0(2IO3-/I2(r)) = 1,19V , E0(2HIO/I2(r)) = 1,45V , E0(I2/2I-) = 0,54V . Tnh E0(IO4-/IO3-) ,
E0(IO3-/HIO)

/s:

a, (Cu(NH3)42+) = 1013,57 ; b, E0(IO4-/IO3-) = 1,61V , E0(IO3-/HIO) = 1,125V

Bi 106: (T135) Cho E0(TcO4-/TcO42-) = 0,7V , E0(TcO42-/TcO2) = 0,8V , E0(TcO2/Tc) = 0,3V . Tnh E0( TcO4-/TcO2) v xt
xem TcO42- c kh nn t phn hy thnh cc cht ln cn l TcO4- v TcO2 khng?
/s: E0( TcO4-/TcO2) = 0,77V v c kh nng t phn hy .
Bi 108: (T142) Tin hnh cn chnh xc 0,2940g K2Cr2O7 tinh khit ri ha tan thnh 100ml dung dch A , ly 10ml dung
dch A thm vo 10,00ml dung dch KI 0,15M c acid ha v thm Na 2CO3 trong bnh chun . bnh chun
trong bng ti 10 pht , sau tin hnh chun bng dung dch Na2S2O3 s dng h tinh bt lm ch th th cn
10,50ml .Ha tan 1,000g mu Cu(NO3)2 vo nc , pha long thnh 100,00ml , ly 10ml dung dch acid ha bng acid
HCl , them KI d , trong bng ti 10 pht sau chun bng dung dch Na 2S2O3 s dng h tinh bt lm ch th cn
15,4ml .Xc nh hm lng Cu(NO3)2 trong mu. Cho E0(Cr2O72-/2Cr3+) = 1,36V , E0(I3-/3I-) = 0,5355V , E0(S4O62-/S2O32-)
= 0,08V , E0(Cu2+/Cu) = 0,337V , E0(Cu+/Cu) = 0,521V ; T(CuI) = 5,1.10-12
/s: 97,03%
Bi 115: (T248) Hy cho bit hin tng khi dn H2S (0,1M) qua dung dch A gm HgCl2 0,01M , ZnCl2 0,01M , FeCl3
0,01M , HCl 0,01M cho n bo ha. Cho pT(FeS) = 17,2 , pT(ZnS) = 21,6 , pT(HgS) = 51,8 ; pk a1(H2S) = 7,02 ,
pka2(H2S) = 12,9 ; E0(Fe3+/Fe2+) = 0,771V ; E0(S/H2S) = 0,17V
/s: Mt mu vng ca Fe3+ do Fe3+ b kh thnh Fe2+ ; c kt ta HgS mu en ln mu vng ca S, mu trng ca ZnS
Bi 117: (T71) Cho phn ng: CrO2- + NO3- CrO4- + NO
E0(CrO42-/Cr(OH)3,OH-) = -0,13V , E0(NO3-,H+/NO) = -0,96V ; lg*(Cr(OH)2+) = -3,8 ; pT(Cr(OH)3) = 29,8 ; Kn = 10-14
V

Cr(OH)3 H+ + CrO2- + H2O ; K = 10-14

Xc nh chiu hng phn ng trn.

/s: phn ng xy ra theo chiu thun.
Bi 118: (T253-254)
a, Chng minh rng : Vng kim loi (Au) b oxy khng kh oxy ha trong dung dch Xianua. Bit E 0(Au+/Au) = 1,70V ,
E0(O2,4H+/2H2O) = 1,23V ; hng s khng bn ca Au(CN)2- bng 7,04.10-40.
b, Chng minh rng : ng kim loi (Cu) kh c nc acid c O2 ha tan ( P(O2) = 0,21atm ). Bit E0(Cu2+/Cu) =
0,34V , E0(O2,4H+/2H2O) = 1,23V , E0(Cu+/Cu) = 0,52V
/s: a, E0(Au(CN)2-/Au) = -0,61V < E(O2/H2O) = 0,81V
Bi 120: (T283)
a, Tnh th ca in cc Platin nhng trong dung dch A cha hn hp FeCl 3 0,2M v FeCl2 10-4M pH=0 so vi in cc
Calomen bo ha (Ecal bo ha = 0,2476V). Bit E0(Fe3+/Fe2+) = 0,771V
b, 1 lt dung dch A trn, nu cha thm KI 0,4M th khi phn ng trng thi cn bng nng cc ion Fe 3+ , Fe2+ , I- ,
I3- l bao nhiu? . Bit E0(I3-/3I-) = 0,536V
/s: a, 0,718V ; b, [I-] = 0,1M , [Fe2+] = 0,2M , [Fe3+] = 2,1.10-4M , [I3-] = 0,1M .
Bi 123: (T327-352-359)

a, Cho mt lng d AgCl (d) vo 100ml nc (Dung dch B) sau thm 1mmol S 2O32- vo B, tnh tan ca AgCl
bit lg[Ag(S2O3)23-] = 12,8.
b, Xt chiu phn ng: 2Cu2+ + 4I- 2CuI(r) + I2(r) trong dung dch c Cu2+ 1M v I- 0,1M. Bit E0(I2/2I-) = 0,54V ;
E0(Cu2+/Cu+) = 0,15V v pT(CuI) = 12
c, Xt chiu hng phn ng: AsO43- + 2H+ + 2I- AsO33- + I2 + H2O trong dung dch cha AsO42- 0,015M , AsO32- 0,15M
, I2 0,015M v I- 0,15M , H+ 1M
/s: a, S= 4,9.10-3M

; b, Xy ra theo chiu thun.

; c, Xy ra theo chiu thun.

Bi 129: (T161) Cho phn ng: 2MnO4- + 10X + 16H+ 2Mn2+ + 5X2 + 8H2O ( X: l Halogen )
a, Trong phng th nghim , ngi ta thng iu ch Cl2 bng cch cho KMnO4 tc dng vi HCl c . Nu thay bng
dung dch HCl 10-4M th c th iu ch c Cl2 khng? V sao?
b, Mt dung dch A cha Cl- 0,01M v Br- 0,02M c oxy ha bng KMnO4 .Tnh pH ca dung dch A sao cho Ch oxy
ha hon ton Br- m khng oxy ha Cl- .
Cho E0(MnO4-/Mn2+) = 1,51V , E0(Cl2/2Cl-) = 1,359V , E0(Br2/2Br-) = 1,10V. Coi nng cc cht cn li bng 1M v p
sut kh cng bng 1atm.
/n: a, Khi HCl 10-4M th khng sinh kh Cl2 do E(MnO4-/Mn2+) < E(Cl2/2Cl-)
b, 0,350 < pH < 3,284
Bi 131: (T267) xc nh hng s to phc ca phc [Zn(CN) 4]2- ngi ta lm nh sau: Thm 99,9ml dung dch KCN
1M vo 0,1ml ZnCl2 0,1M thu c 100ml dung dch cha phc [Zn(CN)4]2- (dung dch A). Nhng vo A hai in
cc : in cc km tinh khit v in cc so snh l in cc Calomen bo ha c th khng i l 0,247V . Ni hai in
cc vi mt in k , gi tr hiu in th o c l 1,6883V .Hy xc nh hng s to phc [Zn(CN) 4]2- . Bit
E0(Zn2+/Zn) = -0,7628V
/s: [Zn(CN)4]2- = 1018,92 .
Bi 137: (T371) Trn 100ml dung dch AgNO3 0,05M vi 100ml dung dch NaCl 0,1M thu c dung dch A. Thm vo
dung dch A 100ml dung dch Na2S2O3 0,2M th kt ta AgCl tan ht v chuyn thnh phc [Ag(S2O3)2]3- v th in cc
o c l 0,2V. Tnh [Ag(S2O3)2]3- .Bit E0(Ag+/Ag) = 0,8V v T(AgCl) = 2,5.10-10.
/s: [Ag(S2O3)2]3- = 2,22.1011