Absorption Spectra

A white
light from sun or bulb is
passed through
an
absorbing sample ( gas / solution ) -

It
molecules absorb radiations
Atoms or in sample
of certain
wavelength
4 reach to
state
higher energy
H
The
missing wavelength
in the transmitted
light
absorbed the matter
corresponds to radiation by
continues
leave dark
space
in the
bright
spectrum .

while transmitted Photographic

→- Place
-

light :-. .
-

pnjmi
-
-
-

sample
-
-
-
 this.sc?IYorbed
sample
→ the
by

emission
↳
negative of
spectrum
in
atomic spectator line
How is
spectra ) useful
chemical
analysis ? elements Each element
AIs : line spectra is used
to
identify .

has a unique line

emission spectrum .
As
finger
in the
identity way
same
used to
prints are person ,

used
lines in atomic spectra is to
identify unlearn
establish
atoms .
To
quickly
the
identity of an unknown
 line matched
sample ,
the
spectra of it
exactly
atoms of known element
with line spectra of the a .
 Hydrogen spectrum →
imp
when current is
passed through hydrogen gas in the

discharge
tube at low pressure the
,
molecules of Hydrogen
break into atoms .

Hz 2 H atoms

1
These H atoms absorb from electric spark
energy
-

I
of Halon excited & back to lower
get
e- come

E- M R
energy
level
by emitting
-

excited stale lines

g Are intensity of
two
?
! I 2es same or different
inn>
←
.

around stale (lower energy

)
 H atom which
Batmen studied lines of
- comes

visible
under region
(£ E)
l
J > z
-

n
109677
-

wavenumber
=
um
→ -

levels
Energy .

formula for
Rydberg generalised
lines atom
Energy , frog or >

of emission of H -

ftp. ¥ )
To "
=
109677 -

an
j na > n ,

lines of
Q Draw different spectral H alone
-

.
 n =D

I R -
4=5,3--6,7,8 .
-. .

4--4
IR nz=5, 6,7 - - -

4=3
IR nz= 4,56 . - .
.

region
7=2 In series
T n2= 3,4,5
,
* Lyman
transition will
- - -

which
,

visible
region have max .

wavelength ?
max .
wavelength in If
Lyman Series .

7=1
min
energy
T na -734,
gap
-
- . .

DEAN
.

uv
region y
-

OE ✗
¥ n=2ton#
 btw
*
space energy
level decreases
with increase in

value of
'
n' .

n= 8

n -7
- I
' >
n=6
Born
e- n= 5
I

|
valve
n=4 For
large

:1 1
E
n
of n
,
objet
=3
behaves like

n=2
macroscopic
object

" 5
'

:S
n=1 n=s→
/v-z.tt
n

f
n" this
""
during
transition how
lines
,

emission are
many
?⃝