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Pgas =KµX gas

↳ Henry's constant or
Henry 's law
constant
Significance
.

of Ky :

Pgas
=
KH ✗ -

gas Ky =

Pgas_ atm


gas
let Pgas of gas A & B is same .

Chu
%÷ga
(Ku ) ☐
P8ga
& =

, ,

let
Xgaea >
gasps
✗ Gas A- is more
soluble
then
( Ku )a < (Ka )

given pressure higher
the
At a , solubility
lower is the value of Kµ
of a

gas ,
.

Higher
the
temp low solubility of gas liq in .

I
value of KH
Higher .

I let Ku value of gas A = 1.3 atm 4 KH value


of
gas
13 = 1-7 atm .
which
gas
is
easily
soluble in water ?
Ansf Gas A

§ How can determine the value of Ku ?


you

AES Pgas Km
Xgae
: -
= -
straight
line
egn :
y = mute - ④
9 y= Pga , ; a-

gas

Pgas -1%1 __m=Kµ ; c=o

✗ →
gas

Applications of Henry 's law :

④ In order to increase the solubility of CO2 gas


in soft drinks & soda water, the bottles are

sealed under
high pressure .

used by sea
Bends In
oxygen cylinder
also filled with Na In
divers are .

inside the pressure increases


deep
sea ,
.
Solubility of Oa Nz also
,
increases .

back to the
When diver come
ground
decreases solubility
from sea
pressure ,

of 02 & Ng decreases .
Nz forms bubble in

the blood cells which &


causes
pain cause

pain in joints . This is called bends .

How to avoid bends to minimise bends ;


also diluted with
oxygen
cylinder is tee
gas .

It happens when brain


Ciii] Anoxia :
body or

I loses its
oxygen supply .

injuries affect breathing


→ sudden
Higher
,

altitudes
like
choking .
tissues
→ It
may affect body .

toxic with rotten like smell


§ Has ,
a
gas egg
is used for the qualitative analysis .
If the

water
solubility of Hzs in at STP is

calculate law constant


0.195m ,
Henry 's .

go.IO/given:-Pgas--1atmmolalilj(m)--
kn ✗
AIS Pgas

|
= .

0-195 moles

!¥;÷µ , tkgofwater.nl/ys
=

Has in
,
✗ ) 0.195

g.FI?+s-g-.s-s---fj-!#q-n(tgoy--,ogo0-=55---
=
=

Has
not
Xmas = 0-0035 -

Eqn 1- atm =
Kµ ✗ 0.0035

285.771 atm
K,,
o.to#--
=

§ The partial press .

of ethane over a son

3g
-

containing 6-56×10
of ethane is 1- bar.

If the son contains 5. oo ✗


152g ethane then

be
what shall the
partial press of gas ?
.

AE to given temp
m ✗ at a .

m=Kp .
- ①
>
Cersei 6.56×10
:
m
,
=
Kp ,
m
,
=

go Pit
.
bar

case #
Kpz Fg Pa ?
:
my =
; my = 5×1
;
=
Is ¥
-
-

,
ta =

m÷×P ,

Pa =

{¥_g ,

1- bar = 0.76-2 bar

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