1. A volume of 20.00 mL of a solution of KCl was diluted to 250.

00 mL in a volumetric flask, and the latter

solution was labelled “solution A”. A volume of 15.00 mL of solution A was then pipetted into a 250.00 mL
volumetric flask and diluted to the mark, and this was labelled “solution B”. A volume of 10.00 mL of solution B
was then diluted to 100.00 mL in a volumetric flask, and this was labelled “solution C”. If the molar
concentration of KCl in solution C was 2.5243 x 10-4 M, calculate and indicate the following on your diagram of
the dilutions:

1. The moles of KCl in solutions C, B, A, and the original 20.00 mL solution respectively.
[Ans (mols): C = 2.5243 x 10-5; B = 6.3108 x 10-4; A = 0.010518; original = 0.010518]

1. The molar concentration of solutions B, A, and the original 20.00 mL solution respectively.
[Ans (M): B = 2.5243 x 10-3; A = 0.042072; original = 0.52590]

1. The % (m/v) KCl concentration [KCl = 74.555 g mol–1] of the original 20.00 mL solution].
[Ans: 3.921%]
1. The pKCl of the original 20.00 mL solution.
[Ans: 0.279]
1. The pK of the original 20.00 mL solution.
[Ans: 0.279]
1. A mass of 12.0351 g of an impure sample containing Na2CO3 was dissolved in water and diluted to 250.00 mL. This
solution was labelled “solution A”. A volume of 20.00 mL of solution A was then pipetted into a 200.00 mL volumetric flask,
diluted to the mark, and labelled “solution B”. A volume of 25.00 mL of solution B was diluted to the mark in a 100.00 mL
volumetric flask, which was labelled “solution C”. A volume of 25.00 mL of solution C was pipetted into an Erlenmeyer flask,
indicator was added and the solution was titrated against a 0.01044 M solution of HCl, using 22.25 mL of the latter solution
to reach an end point. Calculate:

1. The % (m/m) concentration of Na2CO3 [Na2CO3 = 105.99 g mol–1] in the impure solid sample.
[Ans: 40.91%]

1. The % (m/v) Na2CO3 in solution B.

[Ans: 0.1970%]