Document From Sumi Pandey

QUIZ-CLASS-XII (LKITN224A01-X01-C01-C02-LKPNN224A01-B01-B02) (09.04.
2023)
Syllabus
Physics: Fluid (Pressure, Archimedes principle and floatation)

Chemistry: Chemical Equilibrium
Maths: Circle
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QUIZ-CLASS-XII (LKITN224A01-X01-C01-C02-LKPNN224A01-B01-B02) (09.04.2023)
QUIZ
PHYSICS, CHEMISTRY & MATHEMATICS
DATE: 09.04.2023
Time Allotted: 3 Hours Maximum Marks: 186
A. General Instructions
1. Attempt ALL the questions.
2. This question paper contains Three Sections.
BATCH: CLASS – XII
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.

4. Each Section is further divided into Three Parts: Part-A, B & C
5. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in any
form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with blue / black ball point pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts

(i) Part-A (01 – 08) contains 8 multiple choice questions which have only one correct
answer. Each question carries +3 marks for correct answer and –1 mark for wrong answer.
Part-A (09 – 11) contains 3 multiple choice questions which have one or more than one correct
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
Part-A (12 – 13) contains 2 multiple choice questions based on a paragraph which have only one correct
(ii) Part-B (1) contains 1 matrix match type question which has statements given in 2 columns. Statements in the
first column have to be matched with statements in the second column. There may be one or more than one
correct choices. The question carries +8 marks for all correct answers; however for each correct row +2 marks
will be awarded. There is no negative marking.
(iii) Part-C (1 – 4) contains 4 Numerical based questions with single digit integer as answer, ranging from 0 to 9
(both inclusive). Each question carries +3 marks for correct answer and –1 mark for wrong answer.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
SECTION – 1 (PHYSICS)
PART - A [+3, –1]
(Objective. Only one correct option)
1. A barometer kept in a stationary elevator reads 76 cm. If the elevator starts accelerating up the
reading will be
(A) Zero (B) Equal to 76 cm (C) More than 76 cm (D) Less than 76 cm
2. A closed rectangular tank is completely filled with water and is accelerated horizontally with an
acceleration a towards right. Pressure is (i) maximum at, and (ii) minimum at
(A) (i)-B, (ii)-D (B) (i)-C, (ii)-D (C) (i)-B, (ii)-C (D) (i)-B, (ii)-A
3. A barometer tube reads 76 cm of mercury. If the tube is gradually inclined at an angle of 60o
with vertical, keeping the open end immersed in the mercury reservoir, the length of the
mercury column will be
(A) 152 cm (B) 76 cm (C) 38 cm (D) 38 3 cm
4. Three liquids of densities d, 2d and 3d are mixed in equal volumes. Then the density of the
mixture is
(A) d (B) 2d (C) 3d (D) 5d
5. Radius of an air bubble at the bottom of the lake is r and it becomes 2r when the air bubbles
rises to the top surface of the lake. If P cm of water be the atmospheric pressure, then the
depth of the lake is (Neglect surface tension)
(A) 2p (B) 8p (C) 4p (D) 7p
6. Two solids A and B float in water. It is observed that A floats with half its volume immersed and
B floats with 2/3 of its volume immersed. Compare the densities of A and B
(A) 4 : 3 (B) 2 : 3 (C) 3 : 4 (D) 1 : 3
7. A hollow sphere of volume V is floating on water surface with half immersed in it. What should
be the minimum volume of water poured inside the sphere so that the sphere now sinks into the
water
(A) V/2 (B) V/3 (C) V/4 (D) V
8. An ice block contains a glass ball when the ice melts within the water containing vessel, the
level of water
(A) Rises (B) Falls
(C) Unchanged (D) First rises and then falls
PART - A [+4, –1]

(Objective. One or more than one correct option(s))
9. The weight of an empty balloon on a spring balance is w1 . The balloon is filled with air of
weight w. The weight of the filled balloon becomes w 2 . Neglecting the thickness of balloon
and ignoring the difference in densities of air inside and outside the balloon then
(A) w 2 = w 1 + w (B) w 2 = w 1 (C) w 2 < w 1 + w (D) w 2 > w 1
10. The vessel shown in figure has two sections of areas of cross-section
A1
A1 & A2. A liquid of density ρ fills both the sections up to a height h in
each. Neglect the atmospheric pressure. h
(A) the pressure at the base of the vessel is 2ρgh. x
(B) the force exerted by liquid on the base of vessel is 2ρghA2. A2
(C) the force exerted by liquid on the base of vessel is ρgh(A1 + A2). h
(ρ)
(D) the walls of the vessel at the level x exert a downward force
ρgh(A2 - A1) on the liquid.
11. If a sample of metal weighs 210 gm in air, 180 gm in water, 120 gm in a liquid
(A) relative density (RD) of metal is 3 (B) RD of metal is 7
(C) RD of liquid is 3 (D) RD of liquid is 1/3
PART - A [+3, –1]

(Comprehension. Objective. Only one correct option)
Comprehension:
2
A block of wood floats in water with   rd of its volume submerged. In oil the block floats with
3
 9  3 3
 10  th of its volume submerged. Density of water = 10 kg/m .
 
12. The density of wood is

(A) 470 kg/m3 (B) 667 kg/m3 (C) 710 kg/m3 (D) none of these
13. The density of oil is

(A) 740 kg/m3 (B) 847 kg/m3 (C) 928 kg/m3 (D) none of these
PART – B [+8, 0]
(Matrix Matching)
1. Shown below is a cylinder of radius R floating in vessel containing liquids A and B. Neglecting
atmospheric pressure match the quantities mentioned in Column-I with corresponding
expression in Column-II.
Column I Column II
(A) Net force exerted by liquid A of density ρ on the cylinder. (p) 9ρgRh2
(B) Net force exerted by liquid B of density 2ρ on the cylinder. (q) πρgR2h
Net force exerted by liquids A and B on the left half of the
(C) (r) 4 πρgR 2h
curved part of cylinder.
(D) Net force exerted by liquid A and B on the cylinder. (s) 3πρgR2h
PART - C [+3, –1]

(Numerical / Integer type)
1. A rod of length 6 m has specific gravity 25/36. One end of the rod is
tied to a 5m long rope, which in turn is tied to the floor of a pool 10
m deep as shown. Find the length of the part of rod (in meter),
which is out of water. 10 m
5m
2. A liquid is kept in a cylindrical vessel which is being rotated about its axis. The liquid rises along
the sides due to rotation. If the radius of vessel is 0.05 m and speed of revolution is 2
revolutions per second, then find difference in levels of the liquid at the centre & sides (in cm).
[Given: g = 10ms-2 & π2 = 10].
g
3. The acceleration of the liquid in the vertical U tube is .
β 3b
Find the value of β : θ
b
4b
4. Two spheres of volume 250 cm3 each are connected by a

light string and the combination is immersed floating in
Rel. density
vertical position in liquid as shown. The tension in the string
0.8
1
is N. Find the value of K. [Taking g = 10 m/s2]
K
Rel. density
1.2
SECTION – 2 (CHEMISTRY)
PART - A [+3, –1]
1. In which of the following reaction, the value of K P will be equal to K C ?

(A) N2(g) + O2(g) 2NO (g) (B) PCl5 (g) PCl3 (g) + Cl2(g)
(C) 2NH3 (g) N2(g) + 3H2(g) (D) 2SO2 (g) + O2(g) 2SO3 (g)
2. The equilibrium constant K C for the decomposition of PCl5 is 0.625 mole / lit at 300ºC. Then
the value of K P is
(A) 29.36 atm (B) 0.0625 atm (C) 6.25 atm (D) 0.00625 atm
3. If in the reaction N2O4(g) 2NO2(g), α is the part of N2O4 which dissociates then the
number of moles at equilibrium will be
(A) 3 (B) 1 (C) (1– α)2 (D) (1 + α)
1
4. At 444º C, the equilibrium constant K for the reaction 2AB(g) A2(g) + B2(g) is . The
64
degree of dissociation of AB will be
(A) 10% (B) 20 % (C) 30% (D) 50%
5. An unknown compound A dissociates at 500ºC to give products as follows -

A(g) B(g) + C(g) + D(g)
Vapour density of the equilibrium mixture is 50 when it dissociates to the extent to 10%. What
will be the molecular weight of Compound A?
(A) 120 (B) 130 (C) 134 (D) 140
6. ‘a’ moles of PCl5 undergo thermal dissociation as –

PCl5 PCl3 + Cl2, the mole fraction of PCl3 at equilibrium is 0.5. The total pressure is 2.0
atmosphere. The partial pressure of Cl2 at equilibrium is
(A) 2.5 (B) 1.0 (C) 0.5 (D) None
7. In A + B + Heat C, then reaction is favoured at

(A) High temperature and high pressure (B) High temperature and low pressure
(C) Low temperature and high pressure (D) Low pressure and low temperature
8. When 120 g acetic acid is reacted with 138 g ethyl alcohol, the amount of alcohol consumed is
30% of its initial concentration. The number of moles of acetic acid at equilibrium are
(A) 1.1 (B) 2.1 (C) 1.7 (D) 0.9
PART - A [+4, –1]

9. For the reaction, H2 (g) + I2 (g) 2HI (g), the equilibrium constant Kp changes with
(A) total pressure (B) catalyst
(C) the amounts of H2 and I2 present (D) temperature
10. Kc for reaction N2O4 2NO2 is 1.14 M. If ∆rG is Gibb's energy of the reaction when
concentration of two gases are 0.5 M each at constant temperature 291 K. Which statement is
true?
∆n g
(A) ∆rG = –19.67 L-atm (B) Qp = Qc (RT)
(C) For the reaction N2O4 2NO2 ; Kp > Kc (D) ∆rG = –10.2 L-atm
11. For the reaction 2HCl(g) H2(g) + Cl2(g) the equilibrium constant is 1.0 × 10–5. What is the
equilibrium concentration of HCl if the equilibrium concentration of H2 and Cl2 are 1.2 × 10–8 M and
1.2 × 10–9 M respectively?
(A) 1.2 × 10–3 M (B) 12 × 10–7 M (C) 12 × 10–4 M (D) 1.2 × 10–6 M
PART - A [+3, –1]

Comprehension:
The rate of chemical reaction at a particular temperature is proportional to be product of the molar
concentration term raised to the power equal to the number of molecules of the [B]b, where k is the rate
constant of the reaction.
EQUILIBRIUM CONSTANT (k)
For a general reaction aA + bB ⇔ cC + dD, forward rate rf = kf [A]a [B]b, backward rate rb = kb [C]c [D]d
c d
concentrations of reactants & products at equilibrium are related by

Kf
= KC =
[C] [ D] , where all
a b
Kb [ A ] [ B]
the concentrations are expressed in mole/liter.
e.g. PCl5 ⇌ PCl3(g) + Cl2(g)
KC =
[ PCl3 ] [ Cl2 ]
[ PCl5 ]
In the expression of equilibrium constant those components are kept whose concentration charges with
time.
If equilibrium is established by taking all the components in the reaction then to predict the direction of
reactions we calculate the reaction quotient (Q).
c d
The values of expression Q =

[C] [ D]
a b
[ A ] [ B]
at any time during reaction is called reaction quotient
if Q > Kc reaction proceed in backward direction until equilibrium in reached
if Q < Kc reaction will proceed in forward direction until equilibrium in established
if Q = Kc Reaction is at equilibrium
12. A(g) + B(g) ⇌ 2C(g)

Initial concentration of ‘A’ is twice the initial concentration of ‘B’. At equilibrium concentration of
“A” and “C” are same then equilibrium constant for the reaction is
4 4 16
(A) (B) (C) (D) 4
3 9 9
13. When C2H5OH and CH3COOH are mixed in equivalent proportion equilibrium is reached when
2/3 of acid and alcohol are used. How much ester will be present when 2 moles of acid were to
react with 2 moles of alcohol?
(A) 1.33 (B) 1 (C) 2.33 (D) 2
PART – B [+8, 0]
(Matrix Matching)
1. Match the following (multiple):
Left column : Represents an equilibrium saturation through a chemical equation and below
each equation a stimulus is given which may or may not disturb the equilibrium saturation.
Right column : Represents the responses immediately after the disturbance is created.
With Rf : Rate of forward reaction
Rb : Rate of backward reaction
Q : Reaction quotient
K : Equilibrium constant
Column 1 Column II
(A) H2(g) + I2(g) ⇌ 2HI(g) (p) Rf increases
Pressure is increased
(B) 1 3 (q) Rb increases
N + H ⇌ NH3(g)
2 2( g ) 2 2 ( g )
Volume is halved
(C) PCl3(g) + Cl2(g) ⇌ PCl5(g) (r) Rf = Rb
PCl5 is added
(D) 2SO3(g) ⇌ 2SO2(g) + O2(g) (s) Q ≠K
Inert gas added at constant volume.
PART - C [+3, –1]

1. When 5.1 g of solid NH4HS is introduced into a two litre evacuated flask at 27oC, 20% of the
solid decomposes into gaseous ammonia and hydrogen sulphide. The Kp for the reaction at 27o
C is x × 10 −2. The value of x is
2. Consider the reaction AB2(g) ABg + B(g). If the initial pressure of AB2 is 100 torr and
equilibrium pressure is 120 torr, the equilibrium constant Kp in terms of torr is
3. A mixture of N2 and H2 in the ratio of 1 : 3 reach equilibrium with NH3 when 50% of the mixture
has reacted. If the total pressure is P, the partial pressure of NH3 in equilibrium mixture was
P/x, then the value of x is
4. For the reaction NH2COONH4(s) ⇌ 2NH3(g) + CO2(g), equilibrium pressure was found to be 3
atm at 1000 K, hence Kp is
SECTION – 3 (MATHEMATICS)
PART - A [+3, –1]
1. A straight line is drawn through the center of circle x 2 + y 2 = 2ax parallel to the straight line
x + 2 y = 0 and intersecting the circle at A and B. Then the area of ∆ AOB is
a2 a2 a2 a2
(A) (B) (C) (D)
5 7 3 2
2. If the number of common tangent of the circles x2 +y2+2x +6y+1=0 and x2 +y2-6x +k=0 is three,
then the value of k
(A) 2 (B) 4 (C) 6 (D) 5
3. The circle described on the line joining the point (0, 1), (a, b) as diameter cuts the x-axis at
points whose abscissas are roots of the equation
(A) x 2 + ax + b = 0 (B) x 2 − ax + b = 0
2 2
(C) x + ax − b = 0 (D) x − ax − b = 0
2 2 2
4. The straight line y = mx + c cuts the circle x + y = a at real point if
(A) a 2 (1 + m 2 ) ≤ c (B) a 2 (1 − m 2 ) ≤ c
(C) a 2 (1 + m 2 ) ≥ c (D) a 2 (1 − m 2 ) ≥ c
5. The center of the circle passing through the point (0, 0), (1, 0) and touching the circle
x 2 + y 2 = 9 is
3 1 1 3
(A)  ,  (B)  , 
2 2 2 2
1 1 1 
(C)  ,  (D)  , − 2 
2 2 2 
6. If circles are drawn on the sides of the triangle formed by the lines
x = 0, y = 0 and x + y = 2 as diameter, then the radical centre of three circle is
(A) (0, 0) (B) (1, 1)
(C) ( 2, 1) (D) none of these
7. The coordinates of middle point of the chord 2 x − 5 y + 18 = 0 cut off by the circle
x 2 + y 2 − 6 x + 2 y − 54 = 0 is
(A) (1, 4) (B) (-4, 2)
(C) (4, 1) (D) (6, 6)
8. The equation of circle touching the line 2 x + 3 y + 1 = 0 at the point (1, -1) and passing through
2
the focus of the parabola y = 4 x is
2 2
(A) 3x + 3 y − 8 x + 3 y + 5 = 0 (B) 3x 2 + 3 y 2 + 8 x − 3 y + 5 = 0
2
(C) x + y 2 − 3x + y + 6 = 0 (D) none of these
PART - A [+4, –1]

9. C1 : x 2 + y 2 = 16 intersects another circle C2 of radius 5 in such a manner that the

If the circle
3
common chord is of maximum length and has a slope equal to , the coordinates of the center
4
of C2 can be
 9 12   9 12  9 12   9 12 
(A)  ,  (B) − ,  (C)  , −  (D) − , − 
5 5   5 5 5 5  5 5
2 2 2
10. An isosceles triangle ABC is inscribed in a circle x + y = a with the vertex A at (a, 0) and
the base angle B and C each equal to 75o, then coordinates of an end point of the base are
 3a a   3a a  a 3a   3a a
(A)  ,  (B)  − ,  (C)  ,  (D)  − , − 
 2 2  2 2 2 2   2 2
2 2 2
11. A chord AB of circle x + y = a touches the circle x 2 + y 2 − 2ax = 0 locus of the point of
intersection of tangents at A and B is
2 2
(A) x 2 + y 2 = ( x − a ) (B) x 2 + y 2 = ( y − a ) (C) x 2 = a ( a − 2 y ) (D) y2 = a ( a − 2x )
PART - A [+3, –1]

Comprehension:
Consider the circles C1 of radius ‘a’ and C2 of radius b, b > a, both lying in the first quadrant and
touching the co-ordinates axes.
b
12. If C1 and C2 touch each other then is
a
(A) 2 + 2 (B) 3 (C) 1 + 2 (D) 3 + 2 2
a
13. If C1 and C2 are orthogonal then is
b
1
(A) 2 − 2 (B) (C) 2 + 3 (D) 2 − 3
3
PART – B [+8, 0]
(Matrix Matching)
1. Match the following
Column-I Column-II
(A) The number of
common tangents to the circle (P) 1
x 2 + y 2 = 4 & x 2 + y 2 − 8x + 12 = 0 is
(B) If the two circles (Q) 3
2 2 2 2
2x + 2y − 3x + 6y + k = 0 & x + y − 4x + 10y + 16 = 0
cut orthogonally then the values k is
(C) If the line 2x − y + k = 0 is a diameter of the circle (R) 9
x 2 + y 2 + 6x − 6y + 5 = 0, then k is equal to
(D) The circles x2 + y2 + 2ax + 1 = 0 and x2 + y2 + 2by + 1 = 0 (S) 4
a 2b 2
touch each other then 2 is
a + b2
PART - C [+3, –1]

1. If the length of the intercept made by the circle whose diameter is the line joining the end points
ℓ
(–4, 3) and (12, –1) on y-axis is ℓ , then =
13
2. The number of common tangents to the circles x2 + y2 − x = 0, x2 + y2 + x = 0 is
3. The lines 3x − 4y + 4 = 0 and 6x − 8y − 7 = 0 are tangents to the same circle whose radius
is r, then 4r is equal to
a
4. The length of chord cut off by y=2x +1 from the circle x 2 + y 2 = 2 is . Then, a is
5
*****
ANSWERS [Quiz: Class – XII] (09.04.2023)
SECTION – 1 (PHYSICS)
PART – A
1. D 2. A 3. A 4. B
5. D 6. C 7. A 8. B
9. BC 10. ABD 11. BC 12. B
13. A
PART – B
1. (A) – (Q); (B) – (R); (C) – (P); (D) – (S)
PART - C
1. 1 2. 2 3. 2 4. 2
SECTION – 2 (CHEMISTRY)
PART – A
1. A 2. A 3. D 4. B
5. A 6. B 7. A 8. A
9. D 10. ABC 11. BD 12. D
13. A
PART – B
1. (A) – (PQR); (B) – (PQS); (C) – (QS); (D) – (PQR)
PART - C
1. 6 2. 5 3. 3 4. 4
SECTION – 3 (MATHEMATICS)
PART – A
1. A 2. D 3. B 4. C
5. D 6. A 7. A 8. A
9. BC 10. BD 11. AD 12. C
13. D
PART – B
1. (A) – (Q); (B) – (S); (C) – (R); (D) – (P)
PART – C
1. 4 2. 3 3. 3 4. 6

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QUIZ-CLASS-XII (LKITN224A01-X01-C01-C02-LKPNN224A01-B01-B02) (09.04.

Physics: Fluid (Pressure, Archimedes principle and floatation)

Time Allotted: 3 Hours Maximum Marks: 186

3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

PART - A [+4, –1]

PART - A [+3, –1]

12. The density of wood is

13. The density of oil is

PART - C [+3, –1]

4. Two spheres of volume 250 cm3 each are connected by a

1. In which of the following reaction, the value of K P will be equal to K C ?

5. An unknown compound A dissociates at 500ºC to give products as follows -

6. ‘a’ moles of PCl5 undergo thermal dissociation as –

7. In A + B + Heat C, then reaction is favoured at

PART - A [+4, –1]

PART - A [+3, –1]

concentrations of reactants & products at equilibrium are related by

The values of expression Q =

12. A(g) + B(g) ⇌ 2C(g)

PART - C [+3, –1]

PART - A [+4, –1]

9. C1 : x 2 + y 2 = 16 intersects another circle C2 of radius 5 in such a manner that the

PART - A [+3, –1]

PART - C [+3, –1]

2. The number of common tangents to the circles x2 + y2 − x = 0, x2 + y2 + x = 0 is

ANSWERS [Quiz: Class – XII] (09.04.2023)

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Batch :__ Date of Examination :_