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Coordination DigiBook
Coordination DigiBook
Compounds
µ
:L n'Thieme
"
Isomerism
field
Crystal Theory
Organometallic Compounds
I -2 Ols
Werner 's Theory
0
I .
Primary Valency :
Ionic
covalent
2
Secondary valency
:
.
TUPAC Nomenclature
• certain rules to be
followed
-
I . The
positive part of compound named
first followed
by negative part .
2 .
of ligand present .
prefix
: bis ,
tris used when
fsolydendate ligands
3 .
4 .
Oxidation state of central atom in roman No 's in
bracket .
for Anion
ligands : Name ends in 0
neutral
ligands
:
Regular Names
H2O =
Aqua
No =
nitrosyl
MHz = ammine
co =
carbonyl
Isomerism
structural stereo
structural Isomerism
is .
Hydrate Isomerism
Differ in coordinated bound H2O .
2 . Ionisation Isomerism
3 .
Linkage Isomerism
Differ in sites of coordination of ambient
ligand
⇐ (MDs model and founds (Ono)) I
4 . Coordination Isomerism
Differ in coordination spheres
@ (Nhs) 6) (counts) and [cocoons) 6) (crank )
Stereoisomerism
1 .
Geometrical Isomerism
°
Tetrahedral complexes do not show
geometrical
isomerism .
•
Square planar complexes with
general formula
M Az Xz MABXY
M Az XY M ( AB)z
MAB Xa MCABCD)
show geometrical isomerism .
• Sn Octahedral complexes -
2 .
Optical Isomerism
when CN = 4
Possible hybridisation
's
dsp
'
=
; sp
In case
of dsp
' -
No optical isomerism
On sp
's -
"
Type I :
( ( )
m AA
,
Bz)
Type I :
(MIAA) ,]
"
1 .
(
Cr ( Nhs)¢ ) ion
"
Ear ) 3dB
Electronic
config of Cr =
n
2 . Hi Cco) u )
oxidation state Ni
of = zero
by charged ligands
-
ve .
d lost
In CFT
degeneracy of orbitals is
-
.
Decides stability of complex .
stable
strong field ligands complexes more
-
-
chelates (Ring forming ligands) are more stable .
Organometallic comped .
atleast metal
Compounds containing one carbon
-
•
bond .
I .
or bonded
organometallic compound
RMGX
Nez (MDG
2 A bonded
organometallic compound
-
.
3 .
o -
it bonded organometallic compound
Ni (co)y
Fe CCDs
Previous yrs Imm