Republic of the Philippines

BATANGAS STATE UNIVERSITY

The National Engineering University
Alangilan Campus
Golden Country Homes, Alangilan, Batangas City, Batangas, Philippines 4200
Tel Nos.: (+63 43) 425-0139 loc. 2121 / 2221
E-mail Address: ceafa@g.batstate-u.edu.ph | Website Address: http://www.batstate-u.edu.ph

CHEMICAL ENGINEERING DEPARTMENT

QUIZ PART 2 (Analytical Chemistry)
ChE 426:ChE Applications with Comprehensive Examination

Name: Section: Date: Score:

GENERAL DIRECTIONS: Strictly no ERASURES in the answer sheet. Shade the letter of your
choice in the answer sheet provided. Choose E if your answer is not in the given set of choices. You may
use the questionnaire as scratch. Good luck!

1. A 100-mL sample is analyzed for hardness, requiring 23.63 mL of 0.0109 M EDTA. Report the
sample's hardness as mg CaCO3/L.
a. 103
b. 0.103
c. 258
d. 0.258

2. The Zn (65.4 g/mol) in a 0.7457-g sample of foot powder was titrated with 22.57 mL of 0.01639 M
EDTA. Calculate the percent Zn in this sample.
a. 3.24
b. 3.54
c. 2.87
d. 2.21

3. A 0.4071 g CaCO3 was weighed to make a 500-mL solution and from this, 50.00-mL aliquot was
obtained and titrated with 42.63 mL EDTA to reach the endpoint. Calculate the concentration of the
EDTA in this problem.
a. 6.391 x10-3 M
b. 9.541 x 10-3 M
c. 4.827 x10-3 M
d. 5.020 x10-3 M

4. What is the molar solubility of plumbous chloride?

a. 0.049
b. 0.016
c. 0.004
d. 0.003
 Republic of the Philippines
BATANGAS STATE UNIVERSITY
The National Engineering University
Alangilan Campus
Golden Country Homes, Alangilan, Batangas City, Batangas, Philippines 4200
Tel Nos.: (+63 43) 425-0139 loc. 2121 / 2221
E-mail Address: ceafa@g.batstate-u.edu.ph | Website Address: http://www.batstate-u.edu.ph

5. Which of the following factors causes a decrease in solubility?

a. common ion effect
b. weak acid formation
c. weak base formation
d. complex ion formation

6. Iodide in a 0.6712-g sample is determined by Volhard titration. After adding 50.00 mL of 0.05619 M
AgNO3, the remaining Ag+ is back-titrated with 0.05322 M KSCN, requiring 35.14 mL to reach the
end point. Report the percentage of iodide (126.9 g/mol) in the sample.
a. 17.76
b. 28.17
c. 35.52
d. 82.31

7. A titrant that can serve its own indicator in redox titrations.

a. KMnO4
b. K2CR2O7
c. Na2S2O4
d. Ce(NO3)4

8. In redox reactions involving Cr2O2-7, what is the equivalent weight of K2Cr2O7? In acidic medium,
Cr2O2-7 is converted to Cr3+.
a. EW = MW/1
b. EW = MW/2
c. EW = MW/3
d. EW = MW/6

9. Oxalic acid is present in many plants and vegetables. If 24.0 mL of 0.0100 M KMnO4 solution is
needed to titrate 1.00 g of a sample of oxalic acid to the equivalence point, what is the percent by
mass of H2C2O4 (90.04 g/mol) in the sample?
a. 2.2
b. 5.4
c. 10.8
d. 18.0

10. Calculate the standard potential for the reaction below.

a. 0.90 V
b. -0.90 V
 Republic of the Philippines
BATANGAS STATE UNIVERSITY
The National Engineering University
Alangilan Campus
Golden Country Homes, Alangilan, Batangas City, Batangas, Philippines 4200
Tel Nos.: (+63 43) 425-0139 loc. 2121 / 2221
E-mail Address: ceafa@g.batstate-u.edu.ph | Website Address: http://www.batstate-u.edu.ph

c. 0.64 V
d. -0.64 V