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  • Tugas Pourbaix - Muhammad Chair Hanif

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    This document contains calculations of equilibrium constants (K) and standard electrode potentials (E°) for several iron redox couples in aqueous solution as a function of pH. The calculations show: 1) The pH at which ferrous iron (Fe2+) and ferric iron (Fe3+) are in equilibrium is 10.53. 2) The pH at which ferrous iron (Fe2+) and iron hydroxide (FeOH2+) are in equilibrium is 2.43. 3) The pH at which ferrous iron (Fe2+) and iron hydroxide (Fe(OH)2+) are in equilibrium is 4.69.

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    Tugas Pourbaix_Muhammad Chair Hanif

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    This document contains calculations of equilibrium constants (K) and standard electrode potentials (E°) for several iron redox couples in aqueous solution as a function of pH. The calculations show: 1) The pH at which ferrous iron (Fe2+) and ferric iron (Fe3+) are in equilibrium is 10.53. 2) The pH at which ferrous iron (Fe2+) and iron hydroxide (FeOH2+) are in equilibrium is 2.43. 3) The pH at which ferrous iron (Fe2+) and iron hydroxide (Fe(OH)2+) are in equilibrium is 4.69.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    5 views3 pages

    Tugas Pourbaix - Muhammad Chair Hanif

    Uploaded by

    MChair Hanif
    This document contains calculations of equilibrium constants (K) and standard electrode potentials (E°) for several iron redox couples in aqueous solution as a function of pH. The calculations show: 1) The pH at which ferrous iron (Fe2+) and ferric iron (Fe3+) are in equilibrium is 10.53. 2) The pH at which ferrous iron (Fe2+) and iron hydroxide (FeOH2+) are in equilibrium is 2.43. 3) The pH at which ferrous iron (Fe2+) and iron hydroxide (Fe(OH)2+) are in equilibrium is 4.69.

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    © All Rights Reserved
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    of 3

    NAMA : MUHAMMAD CHIAR HANIF

    NPM : 3334210086

    TUGAS KOROSI DAN PROTEKSI + PRAKTIKUM [B]

    [𝐻𝐹𝑒𝑂2− ]
    𝑙𝑜𝑔 [𝐹𝑒 2+ ]
    = −31,58 + 3𝑝𝐻

    [𝐻𝐹𝑒𝑂2− ] [𝐻 + ]3
    (𝑙𝑜𝑔 [𝐹𝑒 2+ ]
    + 𝑙𝑜𝑔 [𝐻 2) = −31,58
    2 𝑂]

    log(1) − 3𝑝𝐻 = −31,58


    3𝑝𝐻 = 31,58
    𝑝𝐻 = 10,53

    [𝐹𝑒𝑂𝐻 2+ ]
    log [𝐹𝑒 3+ ]
    = −2,43 + 𝑝𝐻

    [𝐹𝑒𝑂𝐻 2+ ] [𝐻 + ]
    (log [𝐹𝑒 3+ ]
    + 𝑙𝑜𝑔 [𝐻 ) = −2,43
    2 𝑂]

    log(1) − 𝑝𝐻 = −2,43
    𝑝𝐻 = 2,43

    +
    [𝐹𝑒(𝑂𝐻)2 ]
    𝑙𝑜𝑔 [𝐹𝑒𝑂𝐻 2+ ]
    = −4,69 + 𝑝𝐻
    +
    [𝐹𝑒(𝑂𝐻)2 ] [𝐻 + ]
    𝑙𝑜𝑔 [𝐹𝑒𝑂𝐻 2+ ]
    + 𝑙𝑜𝑔 [𝐻 = −4,69
    2 𝑂]

    log(1) − 𝑝𝐻 = −4,69
    𝑝𝐻 = 4,69

    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − 𝑛𝐹
    log 𝐾

    0,0591 [𝐹𝑒 3+ ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒 3+ ]


    𝐸 = 0,771 + 1
    log [𝐹𝑒 2+ ]
    − ( 1 𝑥 96500
    ) log [𝐹𝑒 2+ ]

    𝐸 = 0,771

    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − log 𝐾
    𝑛𝐹
    0,0591 [𝐹𝑒𝑂𝐻 2+ ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒𝑂𝐻 2+ ]
    𝐸 = 0,914 + 1
    log [𝐹𝑒 2+ ]
    −( 1 𝑥 96500
    ) (log [𝐹𝑒 2+ ]
    + log[𝐻 + ])

    𝐸 = 0,914 − 0,0591pH

    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − 𝑛𝐹
    log 𝐾
    2+ 2+
    0,0591 [𝐹𝑒(𝑂𝐻)2 ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒(𝑂𝐻) ]
    𝐸 = 1,191 + 1
    log [𝐹𝑒 2+ ]
    −( 1 𝑥 96500
    ) (log [𝐹𝑒 2+2] + 𝑙𝑜𝑔[𝐻 + ]2 )

    𝐸 = 1,191 − 0,1182 pH

    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − 𝑛𝐹
    log 𝐾
    2+ 2+
    0,0591 [𝐹𝑒(𝑂𝐻) ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒(𝑂𝐻) ]
    𝐸 = −0,675 + log [𝐻𝐹𝑒𝑂22−] −( ) (log [𝐻𝐹𝑒𝑂 2−] − log[𝐻 + ])
    1 1 𝑥 96500 2

    𝐸 = −0,675 + 0,0591 pH

    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − 𝑛𝐹
    log 𝐾

    0,0591 [𝐹𝑒𝑂4 2− ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒𝑂4 2− ]


    𝐸 = 1,001 + 4
    log −
    [𝐻𝐹𝑒𝑂2 ]
    − ( 4 𝑥 96500
    ) (log [𝐻𝐹𝑒𝑂2 − ]
    + log[𝐻 + ]5 )

    𝐸 = 1,001 − 0,0739 pH

    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − 𝑛𝐹
    log 𝐾

    0,0591 [𝐹𝑒𝑂4 2− ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒𝑂4 2− ]


    𝐸 = 1,700 + log [𝐹𝑒 3+ ]
    −( ) (log [𝐹𝑒 3+ ]
    + log[𝐻 + ]8 )
    3 3 𝑥 96500

    𝐸 = 1,700 − 0,1576 pH

    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − 𝑛𝐹
    log 𝐾

    0,0591 [𝐹𝑒𝑂4 2− ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒𝑂4 2− ]


    𝐸 = 1,652 + 3
    log [𝐹𝑒𝑂𝐻 2+ ]
    −( 3 𝑥 96500
    ) (log [𝐹𝑒𝑂𝐻 2+ ]
    + log[𝐻 + ]7 )

    𝐸 = 1,652 − 0,1379 𝑝𝐻
    2,303 𝑅𝑇
    𝐸 = 𝐸𝑜 − 𝑛𝐹
    log 𝐾

    0,0591 [𝐹𝑒𝑂4 2− ] 8,314 𝑥 298 𝑥 2,303 [𝐹𝑒𝑂4 2− ]


    𝐸 = 1,599 + log 2+ − ( ) (log 2+ + log[𝐻 + ]6 )
    3 [𝐹𝑒(𝑂𝐻)2 ] 3 𝑥 96500 [𝐹𝑒(𝑂𝐻)2 ]

    𝐸 = 1,599 − 0,1182 𝑝𝐻

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