ADHYAY Batch GOC & ISOMERISM LECTURE -2

effect
Inductive

Inductive
*
effect a
is
permanent effect
It
*

decrease with
increase in distances.

both
operates through
It
* of bonds.

Resonancei

of
when one structure a molecule is

incapable of showing properties of

all the molecule.
the

that exist men than

suggest
than
this there

structure which
of
one the same molecule are

interconvertible into each other. These structures

readily structures
or canonical structures
resonating
are called

structures.
or
contributing The
process called
is

actual
Resonance & the structure existas
Resonance
hybid.
 meandecule
show resonance
to

① should be
The molecule
plans & check
to

the
peanal i t
we will check
y for hybridization
which should be either
sparep
arbitals should be
for Resonance than
plane
in same

undergoing
which are Resonance.

conjugation.
There should be (Alternate
② single
resonatinspecies.
double bond
g
wort
 resonance
Different types of
① it-Bonds
of -vecharge
Resonance with -

CH2=CH- Mz

" yep3

In 4PY H
&⑫ ⑪
⑪

* ↓Py

:
92
 If lone pair in purs p-rital
2
s I
-- A
CH2 CH-CH2 S >
CH2-CH=C2
=

↓ ↓ ↓

sp2 sp24/sp2

( c-] I allylaniou)
=
-

plap
Resonance
hybrid
①
· I
-
Benzylanion
Funz
13
E /

G
o

-
2

>
&M2
-
[Ba
I
e
T

(i)~
S
Y
J -

-
gi -
El
Resonance
hybrid E
 0
G
↓

dOy
I m
ortho - -
or tho
-

d↳ -> meta - -> O

meta pp ↑

para
m

⑭
j:
I
Draw
resonating structure
structure I also
⑪ no
of Resonating
↑

17 (Phenoxide ion)
S /

ADVANCED
-
I o Draw
a[I
-
② structures
--- resonating
-

also the
structures
no
of resonating
(B-naphthalate)

i-Bonds
e c
charge
2 with
of
the -

⑰
cation)
↓
CH2=CH-CH2
↓ ↓ Callye
sp2 I sp2 S2
X ⑰ I
CH2 CH-CH2
= CH2-CH= U2

(t--c-2) Resonance
hybrid.
 ·zp
gration
Be
eps I
ep ↓

⑲ 2
[
1 -
7
I
o --
a

for · Resonance
li
of
hybrid.

⑭u
all the
resonating structures
braw
a as

well the
as
hybrid.
⑰ -
②

[
7
1
I (tropoliumion)
 Resonance lone X-Bond?
with
of
pair
3
of
es

0
·O

CHy= 41-NH2 (vinyl amine)

star pleph
↓
sp2
-2 !**
wo

CH2CH-NH
=

CH2-CH NH2 =

Ot

[2-cH-NH2)
....... Resonance
hybrid.
Plop2
CiS it
⑲z ⑲z
*

2 I

-sp I
2

-
- &
sp
S 3 sp2 [:
-

-> L
I I
/ ->
2-

epi/
1 Aniline

↓
↳
12
e Il
S
-
=

(againresonance
< 7

again
wo To Man

②
InPolle& a

pysidine
③
E
④ Resonance it-Bonds
radical with
of Jus
·

radical)
CH2=CH-CH2
↓ ↓ ↓ cally
1p2 sp2 sp2
& S. 10
2-CH=
CH2
CHI= CH-CH2
<-

&2 -
CH2=CH-CH2

[412 =-4 -

(H2]
 Gazein
II ↳s

SBu
I
2
,

/
· 2

jo

re
i ->
·
⑧

ED

ki
Resonance X-Bonds X-Bonds!
with
of
5
-

sp2
2
↓
I x sp3
⑰
2
-
-
*- -
S ↑
Sp2 sp2
↳1.3-Butadiene)

L-
.......---
⑭
0
⑥ Resonance X-Bonds with obitals
of empty pord -

+sp2 +12 ⑦
-
- BH -O
2 -
BM2
↓ ↓
12 vacent
p-ubital
H
H I
I
⑭⑪
⑭T
②
↳
⑦ Resonance
crd-obitals. I
-
lonspair/-ve charge
with
empty p-
f
- -

⑰
0 C
-=
41 -c
=
-

acylcation