MS NEGATIVE MASS ACCURACY REPORT

A C Q U I S I TI O N I N F O R M A TI O N

System Name: 2695_2998_ISM_QDa72 Acquired By: ryan

Processing Method: QDa Negative Mass Accuracy PM Sample Kit 2 Lot Number: 1245
Project Name: SQT_E_2695_2998_QDa_P_ISM_RC2 Sample Kit 2 Exp. Date: 12/22/2014 12:00:00 AM
Sample Set Id: 4292 Column Serial Number: W1412341AD
Sample Set Name: MS Neg Mass Accuracy SSM Result Set Id: 4303
Sample Set Start Date: 12/22/2014 4:36:06 PM EST

TE S T D E S C R I P TI O N
In the MS Negative Mass Accuracy test, three (3) on column injections of a Sulfadimethoxine solution are made
into a flow of 0.8 mL/min mobile phase - water (0.1 % formic acid) and acetonitrile (0.1 % formic acid).

The qualification passes if the average measured mass of the Sulfadimethoxine ion for the three replicates is
< or = to +/- 0.2 Da (200 mDa) compared to the theoretical [M - H] - m/z.

Sulfadimethoxine Mass Accuracy Results

MS Neg Mass MS Neg Mass MS Neg Mass Accuracy
Accuracy Spec Accuracy (mDa) Pass/Fail
1 QDa < or = 200 mDa 91 PASS

Printed 10:13:23 AM US/Eastern 12/30/2014 Page: 1 of 5

Waters Project Name and Version: SQT_E_2695_2998_QDa_P_ISM Version 1.00
 MS NEGATIVE MASS ACCURACY REPORT

A C Q U I S I TI O N I N F O R M A TI O N

System Name: 2695_2998_ISM_QDa72 Sample Set Id: 4292

Project Name: SQT_E_2695_2998_QDa_P_ISM_RC2 Result Set Id: 4303

MS Negativ e Mass Accuracy Spectra And Chromatograms

Sulfadimethoxine - 2.213
200.00 m/z
250.00 300.00 350.00 400.00 450.00 500.00 550.00
309.16

1.2x106

1.0x106
Sulfadimethoxine - 2.213

8.0x105
Intensity

6.0x105

4.0x105

2.0x105

0.0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00
Minutes
Injection 1

Printed 10:13:23 AM US/Eastern 12/30/2014 Page: 2 of 5

Waters Project Name and Version: SQT_E_2695_2998_QDa_P_ISM Version 1.00
 MS NEGATIVE MASS ACCURACY REPORT

A C Q U I S I TI O N I N F O R M A TI O N

System Name: 2695_2998_ISM_QDa72 Sample Set Id: 4292

Project Name: SQT_E_2695_2998_QDa_P_ISM_RC2 Result Set Id: 4303

MS Negativ e Mass Accuracy Spectra And Chromatograms

Sulfadimethoxine - 2.209
150.00 m/z
200.00 250.00 300.00 350.00 400.00 450.00 500.00 550.00
309.16

1.2x106

1.0x106
Sulfadimethoxine - 2.209

8.0x105
Intensity

6.0x105

4.0x105

2.0x105

0.0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00
Minutes
Injection 2

Printed 10:13:23 AM US/Eastern 12/30/2014 Page: 3 of 5

Waters Project Name and Version: SQT_E_2695_2998_QDa_P_ISM Version 1.00
 MS NEGATIVE MASS ACCURACY REPORT

A C Q U I S I TI O N I N F O R M A TI O N

System Name: 2695_2998_ISM_QDa72 Sample Set Id: 4292

Project Name: SQT_E_2695_2998_QDa_P_ISM_RC2 Result Set Id: 4303

MS Negativ e Mass Accuracy Spectra And Chromatograms

Sulfadimethoxine - 2.198
200.00 m/z
250.00 300.00 350.00 400.00 450.00 500.00 550.00
309.16

1.2x106

1.0x106
Sulfadimethoxine - 2.198

8.0x105
Intensity

6.0x105

4.0x105

2.0x105

0.0
1.00 1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00
Minutes
Injection 3

Printed 10:13:23 AM US/Eastern 12/30/2014 Page: 4 of 5

Waters Project Name and Version: SQT_E_2695_2998_QDa_P_ISM Version 1.00
 MS NEGATIVE MASS ACCURACY REPORT

A C Q U I S I TI O N I N F O R M A TI O N

System Name: 2695_2998_ISM_QDa72 Sample Set Id: 4292

Project Name: SQT_E_2695_2998_QDa_P_ISM_RC2 Result Set Id: 4303

Sulfadimethoxine Mass Accuracy Results

Measured
Inj ection Volume RT Theoretical Mass Mass Accuracy
Inj ection Name Mass Result Id
(ul) (min) (Da) (mDa)
(Da)

1 1 10.00 Sulfadimethoxine 2.21 309.162 309.070 92 4320

2 2 10.00 Sulfadimethoxine 2.21 309.164 309.070 94 4321

3 3 10.00 Sulfadimethoxine 2.20 309.157 309.070 87 4322

Mean 91

Sulfadimethoxine Mass
Accuracy Results
Summary
MS Neg Mass Accuracy (mDa)
1 91

Printed 10:13:23 AM US/Eastern 12/30/2014 Page: 5 of 5

Waters Project Name and Version: SQT_E_2695_2998_QDa_P_ISM Version 1.00