ACADSORT Hydrogen and its compounds (JE Main Pattern) SECTION-A : (Maximum Marks : 80) This section contains TWENTY questions. Each question has FOUR options (1), (2), (3) and (4). ONLY ONE of these four options is correct For each question, darken the bubble corresponding to the correct option in the ORS. For each question, marks will be awarded in one of the following categories Full Marks: +4, ifonly the bubble corresponding to the correct option is darkened. Zero Marks: 0, ifnone of the bubbles is darkened. Negative Marks : ~1 in all other cases When the same amount of zinc is treated separately with excess of sulphuric acid and excess of sodium hydroxide, the ratio of volumes of hydrogen evolved is :- (iat 2) 1:2 (3)2:1 4) 9:4 Ortho and Para hydrogen differ :- (1) Inthe number of protons 2) In the molecular mass (3) In the nature of spins of protons 4) In the nature of spins of electrons In Bosch's process which gas is utilised for the production of hydrogen :~ (1) Producer gas (2) Water gas (3) Coal gas (4) Natural gas Water softening by Clark's process uses := (1) Calcium bicarbonate 2) Sodium bicarbonate (3) Potash alum (4) Calcium hydroxide Which of the following produces hydrolith with dihydrogen :- (Mg 2) Al @)cu (4) CaHeavy water (D20) is :- (1) A product of oxygen and hydrogen (2) Ordinary water containing dissolved salts of heavy metals (3) Water of mineral springs (4) Water produced by repeated distillation and condensation ‘The ionization energy order for H, H’, H- is. (1) H< Ht H> He (3) He H> He Ortho-hydrogen and para-hydrogen resembles in which of the following property :- (1) Thermal conductivity (2) Magnetic properties (3) Chemical properties (4) Heat capacity onic hydrides are formed by :- (1) Transition metals (2) Elements of very high electro positivity (3) Elements of very low electro positivity (4) Metalloids Acidified solution of KeCr207 on treatment with H202 yields + (1) CrOs + He0 + 02 (2) CraO2 + H20 + 02 (3) CrOs + H20 + KeS0s (4) HzCra07 + H20 + 02 H202 restores the colour of old lead paintings, blackened by the action of H2S gas by - (1) Converting Pb02 to Pb (2) By oxidising PbS to PbSOs (3) Converting PbCOs to Pb (4) Oxidising PbSOs to PbSOs Consider the following statements : 1, Atomic hydrogen is obtained by passing hydrogen through an electric are. Il, Hydrogen gas will not reduce heated aluminium oxide. IIL Finely divided palladium absorbs large volume of hydrogen gas. Which of the above statements is/are correct :~ (1) Lalone (2) alone (3) Mand It @) nnAtabsolute zero = (1) Only para hydrogen exists (2) Only ortho hydrogen exists (3) Both para and ortho hydrogen exist (4) None ‘The reaction, H2S + H202— S+ 2H20 manifests: (1) Acidic nature of H202 (2) Alkaline nature of H202 (3) Oxidising nature of H202 (4) Reducing nature of H202 Heavy water has found application in atomic reactor as :- (1) Coolant (2) Moderator (3) Both coolant and moderator (4) Neither coolant nor moderator Hydrogen peroxide works as :- (2) An oxidant only (2) Areductant only (3) Anacid only (4) An oxidant, a reductant, and an acid When zeolite (hydrated sodium aluminium silicate) is treated with hard water, the sodium ions are exchanged (1) Ht ions (2) Ca? ions (3) tons (4) OFT ions (1) Ca®* and Nat (2) Mg and K- (3) Ca®* and Mg? (4) Zn? and Ba®> ‘The formula of heavy water is :- (1) 2088 (2) D20 To (4) ro”Polyphosphates are used as water softening agent because they :- (1) Form soluble complexes with anionic species (2) Precipitate anionic species (3) Form soluble complexes with cationic species (4) Precipitate cationic species. SECTION-B : (Maximum Marks: 20) This section contains TEN Questions, Attempt any five Questions. First five Questions Attempt will be considered for marking. ‘The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value (If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places; e.g, 6.25, 7.00, -0.33, 30, 30.27, -127.30, if answer is 11,36777... then both 11.36 and 11.37 will be correct). Answer to each question will be evaluated according to the following marking scheme: Full Marks : +4, if ONLY the correct numerical value is entered as answer. ‘Zero Marks : 0 in all other cases Find out the sum of protons, electrons and neutrons in the heaviest isotope of hydrogen . Find out the number of following orders which are correct against the mentioned properties : () H2 (ii) Cala + H20 > (i CO+n, Ray enT (iv) Electrolysis of fused NaH (v) Electrolysis of acidic water (vi) Cu + HeSO«(dil,) > MgaNo + xH20 — 3Mg (OH)2 + 2NHs PCIs + yH20 ~> Oxyacid + SHCI CaHo + zH20 — Ca (OH)2 + 2Ho (x=2) y determine,How many moles of water are required for complete hydrolysis of one mole of calcium phosphide? How many of the following are saline hydrides? NaH, Mglfz, Calla, VHose, FeaH, NHH3 When Ba0z reacts with HzSOs, products (A) and (B) are formed oxidation states of most EN element in (A) and (B) are x and y determine, |x| + ly|. How many aqueous solution of compounds cause hardness in water? NaCl, CaCk, CaSOs, Mg(HCOs)2, CaCOa, Mg(NO3)z How many of the following elements will evolve Hz gas with NaOH? Mg, Zn, Be, K, Al, Fe