Electronic Displacement Effect Mains Pattern SOLUTIONS SECTION-A Ans, (2) i 1 Acidic strength a. = Acidic strength a Stability of conjugate base Acidic strength => 3>4>1>2 PH>2>1>4>3 Ans. (4) ° 9 ° % ° O-G-G-B-O e e - Not valid No conjugation = No Resonance Ans. (3) CH CHs 3 > Ans. (1) Noe “oy Due to repulsion of two - CH groups, NO, will go out of plane w.rt benzene ring = SIRElectronic Displacement Effect Mains Pattern 6 Ans. (1) iitte delocalised lone pair (II) OCHs (+M) Basic strength « “+ M>1V>1>11 Ans. (2) Generally RE of Aromatic > Non-aromatic aw < rincorrect NOz Aromatic l \ > \ : correct 2 ( | ss, N’ N’ 1 i H H Aromatic al \< OX. incorrect 3 5 on Aromatic oO-Og mer ‘CH2 Aromatic 8. 8 uy RR Non-polar Polar -ve charge Polar -ve charge on more EN atom on Less EN atom less stable => [>i EN:0>NElectronic Displacement Effect Mains Pattern 9 Ans. (1) la-H a Il. on ae wNS Benaylc c* war order: W> I> >t (ost stable Ans. (2) HH Ha * H AH © “ yp H H 3a-H Jo-H oh oD la-H Resonance Stabilised => order :1V>I>1> IIL Ans. (3) ° o Dey Cc PhoPh A Ph o-bond resonance AromaticC- Resonance stabilised Dancing Resonance _least stable most stable = stability a3 => P.Eorder: I> I> Sir UsB Ilsa e . Aromatic 6 Ans, (3) of 0% AromaticElectronic Displacement Effect Mains Pattern Both ring aromatic Most charge separate Highest dipole moment Jeans eromate earomate Acidic strength a stability of conjugate base # Phenol is less acidic then H2COs, but H2C0s is less acidic then benzoic acid Ans. (4) -M less than (III) Maximum -M @ => Stability of 7 a-M => Acidic strength a stability of C => Acidic strength: II 0 (uy H20 (WV) EtOH oH jae “OH CH3-CH2-O- 1 Least acidic => Acidic strength a stability of conjugate base a => CHs- OH is slightly more acidic than H20_ = rder-1>>Il>1V Ans. (3) “N4 A-butene a4 1,3-butadiene HOH = 30 Kcal/mol HOH = 57 Kcal/mol , as some energy is utilized in form of resonance energy. SIP Least basic NiElectronic Displacement Effect Mains Pattern 20. Ans. (1) Basie strength = Kye Po SECTION-B tg ctict Ans. (5) CHa(3Ha) CH2-CHa(2Ha) A-A-A. Ans. (6) 8 -I group :~ NH ,~ OH, ~ N(CHs)z,~SO3H ,~CHO,~Cl Gi) ii) (vy) (vi) (vii). (vill) Ans. (4) (bdfg) Negatively charged group and alkyl group shows +1 Ans. (7) (a), (©, Cd), (e), G), (, (m) are correct statement about resonance. Ans. (3) @ |] |) 4xe° Antiaromatie (ii) Oe 8ne® AntiaromaticElectronic Displacement Effect Mains Pattern 4 | (wii) ( } 4ne® Antiaromatic Antiaromatic compounds are unstable at room temperature. Ans. (3) o oO ale © ton = caualee RS => All C-0 Bl are equal Ql prt 5-1 — Re Non- equivalent RS => All C-0 BI not equal cy iL & > Equivalent RS, = All co BL equal 0° ) Ho de, H=~ H-0-t-81 = AlLC-0 BL not equal Non-equivalent RS. KR 2 6 squaringacid All C-O BLare equal Ans. (7) (D Naphthalene : CO- TO OO => 3RS. (ID) Anthracene : => 4RS, => Total RS.=4+3=7 Ans. (4) HA + NaOH = NaA+H20 Compounds which are more acidic then H20 are soluble in aqueous NaOH.