Hydrogen and its compounds JEE Main Pattern SOLUTIONS SECTION-A Ans. (1) Zn + H2SOs —> ZnSOs + He Zn + 2NaOH > NazZnO2 + He Ans. (3) Ortho and para hydrogen differ in the nature of spins of protons Ans. (2) cHHo ttm. co +H, wate gas CO+H,+H,9 ——>CO, +2H, us Wittrges steam Ans. (4) In this method calculated amount of lime is added to hard water Ans. (4) Caltz is hydrolith Ans. (4) Heavy water (D20) is water produced by repeated distillation and condensation Ans. (3) Ionization energy is not defined for H*, As there is zero electron in H’. Ans. (3) Chemical properties of ortho and para hydrogen are same ‘Ans. (2) Ionic hydrides are stoichiometric compounds of dihydrogen formed with most of the s-block elements which are highly electropositive in character. Ans. (3) KoCr207 + HeSOs + 4H202 > 2CrOs + KzSOs + SH20 Ans. (2) PDS(s) + 4H202 (aq) + PbSO4(s) + 4420(4)Hydrogen and its compounds JEE Main Pattern 12. Ans. (3) 1. Toproduce atomic hydrogen, molecular hydrogen is passed through an electricare struck between tungsten electrodes at 3773-4273 K. Aluminium oxide cannot be reduced by hydrogen even under very hot conditions because Alis more reactive than hydrogen. Finely divided palladium absorbs large volume of hydrogen gas due to its large surface area- Ans, (1) Only para hydrogen exists at absolute zero Ans. (3) Here S® converts into S® by Ha0zi.e, sed by HaO2 Ans. (3) Heavy water is extensively used as moderator in nuclear reactors and coolant Ans, (4) Hydrogen peroxide can work as an oxidant, a reductant and an acid Ans. (2) NaAlSiOs(s) + M®*(aq.) + M(AISiO.)2(s) + 2Na* (aq.) (M=Mg, Ca) Ans. (3) Hydrogen carbonate, chloride, and sulphate of Mg?* and Ca?* are responsible for hardness of water Ans, (2) Heavy water is a form of water that contains only deuterium rather than the common hydrogen Ans. (3) MM" +Na,P,0%, — [Na.MP,O,,]° +2Na’ M->Mgi andca SECTION-B Ans. (4) 1H? proton > 1 electron 1 neutron —> 2Hydrogen and its compounds JEE Main Pattern Ans. (3) Boiling point/K Hz > 20.39 D2 23.67 T 25.00 Ans. (1) S* (s)+4H,0,(aq.) > SOF (s)+4H,0(() Ans. (5) () Na+ 10> NaOH + Hz (il) Cale + 2120 Ca(OH): + He Gil) Cy + H204q) = COw + Hele) CO ee) + Hate) + He0) zaps, > COrte) + 2Ha%e) (iv) NaH == Nat +H Cathode -> Na* + e--> Na Anode Hh —> Her H+H — Hot Electrolysis of acidic water Cathode : Ha Anode : 02 Ans. (1) MgsNo + 6120 > 3Mg(OH)2 + 2NH PCIs + 41120 HsPO« + SHCL Calle + 2H20 > Ca(OH)2 + 21k Ans. (6) CasP2 + 6H20 > 3Ca(OH)2 + 2PH2 Ans, (2) MgH? and Belz are not saline hydrides Ans. (3) Ba0r.8H20(s) + HzSOs(aq,) ~» BaSOa(s) + H202(aq,) + 8H20(!) matswoe HO eyHydrogen and its compounds JEE Main Pattern 9. Ans. (4) Hydrogen carbonate, chloride and sulphate of Mg? and Ca are responsible for hardness of water Ans. (3) ‘Zn + 2NaOH > NazZnO2 + Ha Be + 2NaOH > NazBeO2 + Ha Al + 2NaQH + H20 > NaAl02 + Hz