Redox Reaction JEE Main Patter SOLUTION SECTION-A Ans. (2) MnOe ; x+4(-2)=-1 or x= +7 (Max possible for Mn); CrO2Clz; x + 2(-2) + 2(-1) =0 or x = +6 (Max possible for Cr). Ans. (1) Fluorine exhibits only 0 and ~1 oxidation state. Ans. (3) MnOr +e» MnO? MnOs +4H* + 3e-—> MnO2 + 2H20 MnO« +5H*+4e--»3Mn,03 + 3420 MnOe + 8H* +Se-—> Mn? + 4H20 or +3 Mn,0, <= — jxvinog) —2—> (Mno aaa MnO, Ans, (4) H202 acts as reducing agent when it releases electrons (itself gets oxidised and reduces others) ice. in (B) & (D). Ans. (4) S undergoes increase in oxidation number from +2 to +2.5, while I undergoes decrease in oxidation number from 0 to ~1. Ans. (4) In (3) option, Cl goes from +5 to +7 and ~1, while in (1) option, Cl goes from 0 to +1 and -1 Ans, (2) Reduction 4 BIO, + Mn*—+Bi" + Mno- ‘Oxidation (i) 2e + 6H* + BiOy —> Bi + 3H20 (ii) 4H120 + Mn?» > MnO + BH’ + 5e (i) <5 + (il) x 2, we get 14 Ht + 5 BIOs” + SMn?*—> SBI + 2MnO«- +7 H20 Hence, (2) is the correct balanced reaction,Redox Reaction JEE Main Patter 8 Ans. (1) MnOe + C0s2+ H* —Mn?* + CO2 + HO vfi=2 :. Balanced equation: 2MnO«- + 5C20.2-+ 16H* —+ 2Mn®* + 1002 + 8H20 ‘Ans. (1) 3lz + 6 OH- —10s + 5I- + 3H20 (balanced reaction) So, ratio is 1:5. Ans. (4) Mn?" > Mn6* ; v.f.=7-6=1 aorsst64 _ So, eq. wt. of KMnO« = M/1 = 158 ‘Ans. (2) 2 46 Naz S03 —>Naz $0, the total change in oxidation number = 4x 2=8 _ molt 280s VE Ans. (2) 2CuSOs + 4K] —> Cuzl2 + le + 2K2S0s. Cue + Le —> Cur, VE=1, Ecuso, ee 159.5 Ans. (2) NH,OH—> N,0 a “1 :. Vf of NH2OH = 1-(-1) =2 Eq wt =M/2 Ans. (4) G0, +14H'+6r—>Gr47H,0+31, noeRedox Reaction JEE Main Patter 15. Ans. (2) MnO«" +5e-+8 Ht —> Mn? +4 H20 = L mole of MnOs- accepts 5 mole of e~ 1/5 mole of MnO«- accepts 1 mole of e- 0.2 mole of MnO«" accepts 1 mole of e~ 0.6 mole of MnO«- accepts 3 mole of e~ Fe?» Fe +e- 1 mole of Fe? will liberate 1 mole of e~ Cro07?- 4 6e- +14 H's 2 Crs +7 HO 1 mole of Cr207# will accept 6 moles of e~ 1 mole of FeC20s—-> Fe® + C02 +3 e~ 1 moles of ferrous oxalate gives 3 moles of e- 0.2 moles of KMnOs = 1/5 moles of KMnOs oxidises 1 mole of Fe® ion, (Tallies with statement A) 0.6 moles of KMnOs = 3/5 moles of KMnOs will oxidise 1 mole of ferrous oxalate (Tallies with statement C) 1 mole of K2Cr207 will oxidise 2 moles of ferrous oxalate, (Tallies with statement D) Hence, (1), (3), (4) are correct while (2) is incorrect. Ans, (2) Normality of a mixture (N) = Normality(Ns) of H2S0s = molarity x basicity = 0,2 x 2=0.4.N N2=0.2x1=0.2N Vi = 100 mL, V2 = 200 mL _oarcioato.2x200 40440 _ 00 _ “700+200 300 300 0.2670 N N Ans. (2) HCI reduces MnOs- to Mn** and itself oxidises to Cle. Ans, (1) Equivalent of K2Cr207 = equivalent of NzHs also equivalent of KMnOs = equivalent of NoHs So, equivalent of K2Cr207 = equivalent of KMnOs 0.1% 6x Vi = 0.35% Ve soV2=2/5Vi Ans, (4) Dilute nitric acid converts chromate into dichromate and H20. 2K2CrOs + 2HNOs —> KeCr2O7 + 2KNOs + H20.Redox Reaction JEE Main Patter 20. qhas (VF = 1 for both) CHClzCOOH + NH3 —> CHCleCOONHs From reaction, m-moles of NH3 = m-moles of dichloroacetic acid = 100 SECTION-B Ans, (33) 70% by weight means 70 g of orthophosphoric acid is present in 100 g solution wy 2000 Taw Voeo w=70¢ rmolmass 5; of replacable H-atom = amass _ 200 “density 154 py 2 230004. exio0| Ans. (0.63) HoC204. 2H20 = 2 + 24 + 64+ 36 = 126 and Equivalent wt. = [25| Lets mole of KeSOs = x Now, KMnOs oxidises only FeSOs (+ Fez(SOs)s has Fe & S in their maximum oxidation state, +3 & +6 respectively) equivalent of FeSO« = equivalent of KMnOs => xsl Necessary equations : KBrOs + KI —> [2+ Br- Tz + Na2S203 —> Na2SsOs + Nal equivalent of fz = equivalent of KBrO3 = 12 «10 equivalent of Na2S203 = equivalent of Iz Mx tx 40-12% 102 so molarity = 3 M.Redox Reaction JEE Main Patter Ans. (10) Mass of organic compound = 1.4.g let it contain x mmole of N atom. organic compound —> NH xmmole 2NH3 + H2SO+ —> (NH4)2 SOs. (Ist) x 60=6 mmole initially taken, HS04 + 2Na0H —> NaSOs + 2H20 (2nd) GX 20=2 mmole reacted Hence mmoles of HzS0« reacted in 2nd equation = 1 => mmoles of H2S0s reacted from 1st equation = 6 - 1 = 5 mmoles => mmoles of NHsin 1st equation = 2 x 5 = 10 mmoles => mmoles of N atom in the organic compound = 10 mmoles => mass of N= 10x 10-3 14=0.14 g > % of N in organic compound = “* x 100 = 10 % Ans, (184) m.cq. of H2S0+ = m.eq. of NaOH sexn.84K10 ee 2x10 2x Vi Vi = 184 mL Ans, (40) Equilivalents of H2C20s.2H20 in 10 mL = Equivalents of NaQH gE) = 0-1 xv Cin tre) V=0.04L= 40 mL, Ans. (600) meq of NazCOs = meq of HaSOs que 25=Nx10 Normality = 0.25 N 0.25 x 400 = =x Vr or Vr= 1000 mL, Volume of H20 mixedRedox Reaction JEE Main Patter 9. Ans. (2) Ca(HCOs)2 + Ca0—-» 2CaCOsb + H20 Moles of calcium bicarbonate 2 = neo required = 2 Note : KCI does not cause any hardness in water. Ans, (20) Moles of CaCl = “1 _asx107 = 107+ = equivalent moles of CaCOs = 10-4 Moles of MgClz = 10-* = equivalent moles of CaCO = 104 . Total moles of CaCOs = 2 x 10-* => Weight of CaCOs = 2«10-* x 100 = 2x10-?g Also, weight of solution = 1000 g ea OCOD, yp 2210 210 10° = 20ppm ‘weight of solution (000 ‘