Geometrical Isomerism and Conformations JEE Main Solutions SECTION-A CH: CHs Noa Hy cHs Ans. (1) 1 ° H Kite (@)i HC Cl (ce) Ch Br (a) H co cl Ww H Cl Br H Me liMe = For Glin monocyclic compounds there should be two different groups present on at leasts| two different sp?-carbons of ring. = n=3 & unsymmetrical = G=2=8 Ans. (4) cis coon cone Colts aM Scac RS c2cC HN oN Css ‘CH Sc=cH um Sa > for cis-trans nomenclature at least one group is same on both carbons of C=C @) Ans. (1) In (1) both groups are at equatorial position, So, least repulsion, Hence, more stable. Ans. (1)Geometrical Isomerism and Conformations JEE Main New mann projection ¢y4,-¢H,-CH-Et About Co-Ca is Ha X&Yis X—Me Benzaldoxime Ans. (2) We sC. we @ (3) c 2 Hoch >” Cre —cHts Ans, (2) HL clo ‘Trans-2-haxenal :- CK > WA" CHs-Cl2-CH? trans Ans. (1) Cl around cycloalkaneGeometrical Isomerism and Conformations JEE Main 12. 13. Ans. (4) cis-trans both forms are possible as ring size is large. Ans. (1) ‘As same groups are present at terminal So, site I will not show Gl. Ans. (2) Ph-CH=CH Cac n=2 Ans. (4) a cL-cHs~ ge CHC Br ‘Same group opposite side, so trans. Ans. (3) According to CIP rules, high priority group same side, so Z-form. Ans. (4) will show GJ, around cycloalkane. Ans. (3) H will show G.l. around cycloalkane. Ans. (2) When number of double bonds are even with different ends formula is 2° where nis the number of double bond, so 2* = 16 Ans. (4) 12,3 are position isomers and 4 is G.L.as same connectivity of atom but different orientationGeometrical Isomerism and Conformations JEE Main SECTION-B Ans. (6) (@) ! H shows GI o unsymmetrical symmetrical n = 3 (odd) ‘ 2e14 2 =GL=6Geometrical Isomerism and Conformations JEE Main 5. Ans. (3) Bulky group is stable at equatorial position. So, most bulky group must be at equatorial. So, ring flipping equilibrium constant is greater than 1 for (i), (ii) and (v) Ans. (2) Ans. (5) Allup > 1 1.COOH up 1 1Phup—>1 COOH, Phup 1 2COOH up 1 Ans. (3) Ds D Cie CCH, W 1 anti-form D wo ay GI=2= qziGeometrical Isomerism and Conformations JEE Main 10. Ans. (3) 2 Nts i) 2 een OO cece f p) CHe-CHs HaC-CHX__-Br! ; 2 ee wo HO=CH~ (q) OH,