ACADSORT Thermodynamics-2 Test (JEE Main Pattern) SECTION-A : (Maximum Marks : 80) This section contains TWENTY questions. Each question has FOUR options (1), (2), (3) and (4). ONLY ONE of these four options is correct For each question, darken the bubble corresponding to the correct option in the ORS. For each question, marks will be awarded in one of the following categories: Full Marks: +4, if only the bubble corresponding to the correct option is darkened. ‘Zero Marks: 0, if none of the bubbles is darkened Negative Marks: ~1 in all other cases Mark out the correct one(s) about P-V plot system. 20L 40L (1) The entropy change for the overall process is 0 (zero) (2) AH > AE for overall process (3) Total work, W=q (4) Total work = -620.77J Choose the correct statement : (1) Standard Gibbs free energy is equal to zero for a reversible reaction at equilibrium (2) Gibb's function of the system attains its maximum value when a reversible reaction reaches equilibrium, (3) For H20{s) = H20()), at its melting point and 1 atm pressure, 1 mole of H20(s) has same Gibbs energy as 1 mole of Hz0(é) (4) If AG <0, the process will always be spontaneous.‘The vapour pressure of water is 0.05 at 37°C, What is free energy change for the following process H20(g, 0.05 atm, 310) -> HeO(Z, 0.05 atm, 310 K) (1)310R (2)310RIn 20 @)o (4)-310R ‘Steam undergoes decomposition at high temperature as per the reactio H20(g) 5 He(g) + $208) AH" = 200 kj mol-! aS* = 40 kj mol-, ‘The temperature at which equilibrium constant is unity is : (1) 3000 Kelvin (2) 5000 Kelvin (3) 5333 Kelvin (4) 5 Kelvin ‘The graph that represents the temperature (T) - entropy (S) variation of a Carnot cycle is mr @r| f t a [4 wl fFAreaction has AH = -33 kj and AS = +58 ]/K. This reaction would be : (1) spontaneous below a certain temperature (2) non-spontaneous at all temperature (3) spontaneous above a certain temperature (4) spontaneous at all temperature Which of the following is true for the reaction ? H20(1) = H20(g) at 100°C and 1 atm pressure (1) 4s =0 (2) 4H = TAs (3) 4H=aU (4) aH=0 For a reversible process at equilibrium, the change in entropy may be expressed as: (1) AS = Taree = Sw (2) as=4s = @) 8-5 (4) as=aG Which of the following has highest entropy at 25°C and 1 bar ? (1) Mercury (2) Hydrogen (3) Water (4) Graphite Heat cannot flow itself from a body at lower temperature to a body at higher temperature is a statement of consequence of: (1) 1°" law of thermodynamics (2) 24 law of thermodynamics (3) conservation of momentum (4) conservation of mass For which of the following reaction entropy, change in the system would be positive (in forward direction) (2) Nog + 3H2(q) > 2NH3¢e) (2) 3Mg,,,+2Fet,, >3Mg%, +2Fe,, (3) CHa) + 202%) > CO2 + 2H20@) (4) Czapiate) > C(aiamone)For the reaction at 300 K; (take R = 8 J/K-mole) 2A(g) + B(s) — 20(g) ‘AU® = ~10 kj and AS? = -50J/K. (1) 4G =5 Kj, the reaction is non-spontaneous 25 X, the reaction is spontaneous 6 Ky, the reaction is non-spontaneous (4) AG° = -27.4 kj, the reaction is spontaneous For the gas phase reaction Na+ 3H2 ==> 2NHs the equilibrium constant is 10-5 atm? at 300 K. AG? for the reaction will be (1-28.72) (2)+28.72K) (3)-143K) (4) Zero ‘The entropy change when 2 moles of an ideal monoatomic gas is subjected to change in state from (Latm, 102) to (2 atm, 5é) will be : [In2 = 0.7] (1) 28 cal/K (2)28)/K (3)-14 cal/K (4) 5.6 /K What is the free energy change (AG) when 1.0 mole of water at 100°C and 1 atm pressure is converted into steam at 100°C and 2 atm pressure? [In2 = 0.693] (1) zero cal (2) 540 cal (3) 517 cal (4) 410 cal The entropy of liquid ethanol is 38.4 Cal deg” mol-1 at 27°C, At this temperature the vapour pressure is 76 mm of Hg and enthalpy of vapourisation is 11.38 Kcal mol-+, Assuming the vapour to behave ideally. Calculate the entropy of ethanol vapour at 1 atm pressure at 27°C. (1) 67.5 Cal deg-t molt (2) 71.73 Cal deg! mol"! (3) 92 Cal deg mol (4) 104.5 Cal deg! moltIn given cyclic process for an ideal gas path B ~ C is isentropic. Then select the correct options B t P Gina v—> (in Litre) (1) ASa-+0= AScva (2) ASio9=ASioc (3) AScysic# 0 (A) AScrasne0 If AHvaporsaton of (C2Hs)20(I) is 350 J/g at its boiling point 300K, then molar entropy change for condensation process is (1) 86.33 J/moLK (2) -86.33 J/moLK (3) -1.16 J/molK (4116 The entropy change when two moles of ideal monoatomic gas is heated from 200°C to 300°C reverb ‘and isochorically ? conde 5 573 (2) FRIn (2) 573 (3) 3Rin (3 73) 573) a3) 4 3Rin (3 ‘When steam condenses to water at 90°C, the entropy of the system decreases. What must be true if the second law of thermodynamics is to be satisfied ? (1) Entropy of the universe also decreases. (2) Entropy of the surroundings also decreases. (3) Entropy of the surroundings increases to same extent to which entropy of the system decreases. (4) Increase in entropy in the surroundings is greater than decrease in entropy of the system.SECTION-B : (Maximum Marks: 20) ‘This section contains TEN Questions. Attempt any five Questions. First five Questions Attempt will be considered for marking, ‘The answer to each question is a NUMERICAL VALUE, For each question, enter the correct numerical value (If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places; e.g, 6.25, 7.00, -0.33, - 30, 30.27, -127.30, if answer is 11.36777... then both 11.36 and 11.37 will be correct). Answer to each question will be evaluated according to the following marking scheme: Full Marks: +4, if ONLY the correct numerical value is entered as answer. Zero Marks: 0 in all other cases, Find magnitude of difference in standard Gibb’s energy of formation of H20(g) & Hz0(1) at 300K in kJ/mol if Vapour pressure of H20 at 300 K is 30 torr. [Use : 1 bar = 75 cm Hg] [Give your answer as nearest integer] When the formation of one mole HBr(g) takes place reversibly from gaseous Hz and lig, Brz at 300K and 1 atm increase in entropy of the surrounding is 170 J/K. What is change in entropy /X) of the system if reaction 2HBr(g) ~ Ha(g) + Bro(¢) is carried out reversibly at 300K in rigid container. [Given : R =8.3 J/mol-K] Identify the number of processes with AG = 0 :- (a) He0(,, 0°C, 1atm) > H20(g,0°C, 1 atm) (b) H20(, 100°C, 1 atm) + H20(g, 100°C, 1 atm) (©) H20(1, 27°C, 0.04 atm) + H20(g, 27°C, 0.04 atm) (a) H20(5, -10°C, 0.01 atm) -> H20(g, -10°C, 0.01 atm) Vapour pressure of water at 27°C = 0.04 atm (e) H20(1, 0°C, 1atm) + H20(5,0°C, 1 atm) (8 Hz0(,, 100°C, 1atm) > Hz0(g, 100°C, 1 atm) (g) H20(1, 100°C, 1atm) -> H20(g, 100°C, 0.1 atm) (h) H20(1, 0°C, 1atm) > H20(s, 0°C, 5 atm) 270° C= 0.04 atm Vapour pressure of ice at -10°C = 0.01 atm ‘At 0°C, water and ice are at equilibrium at 1 atm pressure, The value of AHnusion for ice is (in kJ/mole). (Given AShecang of water at 1 atm & 273 K is ~20 JK mol) Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer. Find (AS)univere (in Joule/mole-K) for a chemical reaction at 300 K given ‘AH® (300 K) = 75 kJ / mol ; AS° (300 K) = 300 J/K-mol Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.A thermostat was maintained at 370K. For one hour 4.2 kJ of heat leaked out through thermostat insulation into a room where initial temperature of air was 300K. So, ifthe entropy change of the air in room is 2x JK-1in hour. Then value of 'x' is Calculate AG (in bar-L) when a definite mass of a monoatomic ideal gas at 1 bar & 272C is expanded adiabatically against vacuum from 10 L to 20 L (In2 = 0.7) ‘At 0° C, water and ice are at equilibrium at 1 atm pressure. The value of AHsion for ice is (in kJ/mole). (Given ASiecang of water at 1 atm & 273 K is -20 JK mol) Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer. Find AG(J/mol) for the reaction at 300 kPa & 27°C when all gases are in stoichiometric ratio of moles. N202(g) > 2NO2(g)_[In2.= 0.7] Given : AGi(N20«) = 100 kJ/mol AGi(NO2) = 50 kJ/mol R=8J/mol-K Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer. Find AG(J/mol) for the reaction at 300kPa & 27°C when all gases are in stoichiometric ratio of moles. N20« (g) > 2NO2(g) [In2 = 0.7] Given: AGr(N204) = 100 kJ/mol AGi(NO2) = 50 kJ/mol R=8]/mol-K Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.