Structural Isomerism JEE Main Pattern 1. SOLUTIONS Ans. (1) (CH- CH =CH-CHy CH2-CHe dete CyHe CyHe Acyclic Cyclic DU=1 DU=1 => ring chain isomers. Ans. (2) CH CH-CHe-€-OH & CHs-Clls-CH-C-H C4Hg02 CyHg02 = different functional groups > Functional isomers Ans. (2) (1) CHs- CH~ CH2~CHs & CHis-CH-CHla CH => Both are chain isomers (2) HC=c-CHe-CHs } OR CHs-C=C-CHs = Both can’t show chain isomers (3) CHy-CH,-OH & CH-0-CH, = Both are functional group isomers CHO CHO -OH functional -O- functional group group (4) CHs-CH=CH & CHy-CHy- CHO = Both are functional group isomers oH 3H, C3H,0 -OH functional -CHO functional Group group Ans. (2) 9 i Hs CHHs-CHe-C-CHe-CH2-CHls & CHe-t-€-Cils Cita CeHy20 CeH20 => same bivalent functional group => difference groups on one side of functional group => Both are metamers.Structural Isomerism JEE Main Pattern Ans. (1) C,Hyo0 : Primary alcohols (1) CHy-CHy~CH)-CH,- OH (2) CHs-CH-CH2-OH Hs Ans. (3) @ (CoHls-G-NH-CHs (CHs-G-NH-CelHs CoHyNO CoHyNO => same bivalent functional group => Two different groups on same side of functional group => Metamers ) Calts-€-0-€-Calls (CHs-C-0-C-CsH7 Celio. CoHyoOa same bivalent functional group ‘Two different groups on same side of functional group Metamers Ans. (3) Aldehyde and ketone are different functional group, so functional isomer. Ans. (3) ite ©L-o-- OL <0) TE item Different group/substituent attached to polyvalent functional group :- Metamerism Ans. (4) (CHs-NH-CH2CH2CH2CH ; Cits-NH-CHo-CH-CHs CHs (Both are chain isomer with minimum number of carbon in 2°-amine) Ans. (4) All will show tautomerism through space tautomerism,Structural Isomerism JEE Main Pattern 14. Ans. (3) ) { ) ( SZ Keto enol cyclic vicinal di keto form is unstable are to repulsion. (R) and (S) has active methylene group “pee , 80 0n basis of enolate ion stability. Ans. (2) Ketone and Alcohol are different functional group. Ans. (3) Both are 1, 3-dimethyl cyclohexane (identical) Ans. (3) @ >| | enol form don't exist as ring formed is anti-aromatic. (2) Double bond (sp®) is highly unstable at bridge head. (3) possible (4) No He to show tautomerism, Ans. (2) (1) CH3-O-CH2-CH2-CH2-CH3 (2) CH3-CH2-O-CH2-CH2-CH3 (8) Clis-0-CHt-CH-CHts (4) CHHs-Cll2-0-GH-CHts CHs CHs oH (5) CHis-0-C-CHs (6) CHz-0-CH-CHi-CHls Gb CHa Ans. (1) dX has most stable enolate ion, due to -M effect of 2 o-0 groups.Structural Isomerism JEE Main Pattern 17. Ans. (2) NAA (1, 2) position Ans. (4) ‘Compounds should have same molecular formula to show isomerism. C=C &C-U=C are isomer (chain isomer) Cc Cc SECTION-B Ans. (8) CyHyN: (1) CHy~CHa~ CHy~CHy-NHp (2) CHa-CHa-CH-Cls NH i fe (3) CHo-G-CHt-NHa (4) CHs-C-NHa CH CH3 (5) CHy~CHy~CHy-NH-CH, (6) CH3-CHI-NH-CH CH (7) CHy- CH- NH-CH,- CH (8) CHis-N-CHo-CHs CHs Ans. (5) CsHy,0H = (1) 1° Alcohol := _ CHy~CH2- CH;~CHy~ CHp- OH, CH GH-CHe-Ct-O CHs CHs-CH-CH2-CHs CH2-OHStructural Isomerism JEE Main Pattern Hs CHs-C-CHt-OH CHs oH (2)3° Alcohol:+ — CHs-(-CHa-CHs CHa Ans. (8) @ Ans. (5) Ans. (7) ‘Compound must have alpha H to show tautomerism, Ans. (6) (CHs-CH-CH-COaH, CHs-CH-COaH, CHls-G-0-Cas CHs CoHs-C-O-CHs , H-C-O-CH2-CHz-CHa Ht (-O-CH-CHs 0 CHs slorete ‘Ans, (3) 9 aA wStructural Isomerism JEE Main Pattern Ans. (3) %@ Total 9 hydrogens are replaced.