Chemical Bonding Solutions SECTION-A Ans, (3) Valence Electrons Group Number Ans. (1) Born Haber cycle is mainly used to determine lattice energy. Ans. (3) % Covalent character « Polarisation 9% C.C. « Charge of cation 1 % CC. — size Size order : Sr?* > Ca?* > Mg?* > Bo?* % C.C.= BeCl, > MgCly > CaCl, > SrCly Ans. (3) Li* (aq), Na" (aq), K* (aq), Rb! (aq), Cs* (aa) (1), hydrated radii.) Ans. (3) Extent of overlapping x Directional nature of orbital Order of strength of overlappin; —?s<2s—2p<2p—2 rs pping s — 2s < 2s — 2p <2p—2p (Non-directional) (More directional) Ans. (4) Si, does not exist because of steric repulsion due to large size of lodine atoms, Ans. (2) Atomic orbitals involved are S, Py, Pys Pa Gy2- Ans. (4) Ie 8 FOL-F see-saw shape POF Ans. (2) \ y NzOs: NTO—N, ° 0 [Co-ordinate and covalent bond]Chemical Bonding 10. Ans. (2) @ HO & a ke sp Bent/V-shape —_Trigonal pyramidal Ans. (2) No NOt NOW BO:25 3 2 BLL. order : NO*> NO > NO* Ans. (4) CO COF COz BO: 3 133 2 BL: CO%" > CO, > CO Ans. (4) Ne N; NS NE BO: 3 25 25 2 BO. « BE. Ans. (3) Strength of H-Bond « EN of atom. Ans. (2) Volatility : Intra molecular H-bonding > Inter molecular H-bonding Ans, (2) HCOOH (dimer due to H-bonding) In solid Argon the atoms are held together by Vander Waal forces,Chemical Bonding 18, 2.6 x 10-2 —_26x 10" _ T6x 10" x14 x 10-9 = 115% IC = 100 Ans. (2) Because Bef? is a linear molecule while H20 has bent shape as following H,0 °° HoH Bent/V-shape Ans. (4) SOF, is polar, equitorial angle # 120° (due to VSEPR) NB; is polar (pyramidal shape) XeFZ shape is sq, pyramidal (polar), bond angle < 90° ICIf shape is bent (polar), bond angle < 109° 28 SECTION-B Ans. (3) d,~ pz is present in : C103, PO}", S05 aa ays lone pair on 1=2 CHCl, CH,Cl, and BF, Cl have distorted shapeChemical Bonding Ans. (4) aa CH fi or CaKy ne StH — c 4— sp? carbon atom. Ans. (0) (a)x=4, y=2 (b) In tetrahedral number of 109° 28’ angles =2=6 > xty-z=442-6=0 Ans. (3) SF, > if m (planar) Le SFs> og (Non-planar) SE, octet (Non-planar) 80,7 AY TE Sp Blane) oO 50; planar il n> ZS 070 Ans, (5)Chemical Bonding 10. Ans. (4) Nag[B,05(OH),]8H,0 on 2 oN Prva HO-R fp Bon NK? oH Maximum 4 identical B-O-B linkage.