ACADSORT Redox Reaction (EE Main Pattern) SECTION-A : (Maximum Marks : 80) This section contains TWENTY questions. Each question has FOUR options (1), (2), (3) and (4). ONLY ONE of these four options is correct. For each question, darken the bubble corresponding to the correct option in the ORS. For each question, marks will be awarded in one of the following categories: Full Marks: +4, if only the bubble corresponding to the correct option is darkened Zero Marks: 0, if none of the bubbles is darkened. Negative Marks: -1 in all other cases Amongst the following, the pair having both the metals in their highest oxidation state is (1) [Fe(CN)6]*- and [Co(CN}e]>- (2) CrO2Cle and MnOs- (3) TiOz and Mn02 (4) [MnCla]?- and [NiFs]?~ The non-metal that does not exhibit positive oxidation state is : (1) Fluorine (2) Oxygen (3) Chlorine (4) lodine When KMnOs acts as an oxidising agent and ultimately forms MnO4?-, MnO2, Mn203 and Mn?*, then the number of electrons transferred in each case is : ()4.3,15 (2)1,5,3,7 313,45 (4)3,5,7,1 In which of the following reactions H202 acts as a reducing agent? (A) HeO2 + 2H- + 2e°—> 2120 (B) HzO2 - 2e° —> 02 + 2H (©) H202 + 2e°—> 20" (D) Ho02 + 20H” - 2e° —> 02 + 2H20 (A) 8) (2) (©), 0) BOA.O (4) (B), 0) Consider the redox reaction 2S203% + la —> SuOe?- + 2 F-: (1) S203% gets reduced to SOs? (2) S20s* gets oxidised to SsOs? (3) Iz behaves as oxidant (4) Both (2) and (3) Which of the following is/are example(s) of disproportionation reaction (1) Cle + OH- —> ClO-+ Cl + H20 (2) KCl0s —>KCl + 02 (3) KCl0s —+ KC10s + KCL (4) Both (1) and (3)Which of the following equations is a balanced one : (1) SBiOs- + 22H* + Mn?*—-> SBi3* + 7H20 + MnO«- (2) SBiOs- + 1411* + 2Mn?* —> SBI + 7H20 + 2Mn0«- (3) 2BiOs + 4H" + Mn?*—> 2Bi?* + 2H20 + MnO«- (4) 6BiOs- + 12H* + 3Mn?*—> 6Bi*+ + 6H20 + 3MnO« For the redox reaction MnOy + C20,2- + H* —» Mn? + C02 + H20, the correct whole number stoichiometric coefficients of MnO", C204? and H’ are respectively : (1)2,5,16 (2) 16, 5,2 (3) 5, 16,2 (4) 2, 16,5 During the disproportionation of lodine to iodide and iodate ions, the ratio of iodate and iodide ions formed in alkaline medium is: ais (5:1 3:1 1:3 In alkaline medium, KMnOs reacts as follows : (Atomic weights in u: K = 39, Mn = 55, = 16) 2KMnO« + 2KOH -» 2K2MnOs + H20 + [0] Hence, its equivalent weight is : (131.6 (2) 63.2 (3) 126.4 (4) 158 In the reaction : NazS20s + 4Clz + SH20—-> NarSOs + HSOs + HCI, the equivalent weight of Naz Sz 0s will be : (M = molecular weight of NazS203) GQ) M/4 (2) M/8 GB) M/1 (ay M/2 In the reaction, 2CuSOs + 4KI— > 2Cual2 + Ie + 2K2SOs the equivalent weight of CuSO« will be : (1) 79.75 (2) 1595 (3) 329 (4) None of these In the conversion NH20H —-> N20, the equivalent weight of NHzOH will be: (M = molecular weight of NH20H) (M/4 (2) M/2 GB) M/s (@)M/1 ‘The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution is (+4 (+6 (+2 +3 Which of the following statements is incorrect : (41) 0.2 moles of KMnOs will oxidise one mole of ferrous ions to ferric ions in acidic medium, (2) 1.5 moles of KMn0s will oxidise 1 mole of ferrous oxalate to one mole of ferric ion and carbon dioxide in acidic medium in acidic medium. (3) 0.6 moles of KMn0s will oxidise 1 mole of ferrous oxalate to one mole of ferric ion and carbon dioxide in acidic medium. (4) 1 mole of KeCr207 will oxidise 2 moles of ferrous oxalate to ferric ions and carbon dioxide in acidic medium,‘The normality of mixture obtained by mixing 100 ml. of 0.2 M HzSOs and 200 ml. of 0.2 M HClis: (1) 0.0267 (2) 0.2670 (3) 1.0267 (4) 1.1670 Amount of oxalic acid present in a solution can be determined by its titration with KMnO« solution in the presence of H2SOs. The titration gives unsatisfactory result when carried out in the presence of HCI, because HCI: (1) furnishes H- ions in addition to those from oxalic acid. (2) reduces permanganate to Mn?*, (3) oxidises oxalic acid to carbon dioxide and water. (4) gets oxidised by oxalic acid to chlorine. Volume Vi mL of 0.1M KeCraO7 is needed for complete oxidation of 0.678 g NeHs in acidic medium. The volume of 0.3 M KMnOs needed for same oxidation in acidic medium will be : wiv @iv @)113 vi (4) cannot be determined What will happen if the solution of potassium chromate reacts with excess amount of nitric acid: (1) Crrreduces in the oxidation state +3 from Cr0s2 (2) Cr oxidises in the oxidation state +7 from Crow. (3) Cr-¥and Cr207*- will be formed. (4) Cr2072-and H20 will be formed, 100 millimoles of dichloroacetic acid (CHCl2 COOH) can neutralize how many moles of ammonia to form ammonium dichloroacetate : (1) 0.0167 (201 (3) 03 (06 ‘SECTION-B: (Maximum Marks: 20) This section contains TEN Questions. Attempt any five Questions. First five Questions Attempt will be considered for marking ‘The answer to each question is a NUMERICAL VALUE. For each question, enter the correct numerical value (If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places; e.g. 6.25, 7.00, -0.33,, ~30, 30.27, -127.30, if answer is 11.3677... then both 11.36 and 11.37 will be correct). Answer to each question will be evaluated according to the following marking scheme: Full Marks: +4, if ONLY the correct numerical value is entered as answer. Zero Marks: 0 in all other cases. ‘The normality of orthophosphoric acid in a solution which is 70% by weight and has specific gravity 1.54is:‘The mass (in g) of oxalic acid crystals (H2C20s.2H20) required to prepare 50 ml. of a 0.2 N solution is A3 mole mixture of FeSOs and Fez(SOs)s required 100 mL of 2M KMnOs solution in aci medium. Find the mole of FeSOs in the mixture. A solution of NazS20s is standardised iodometrically against 3.34 g of pure KBrO3 (converted to Br-), requiring 40 mL NazS20s solution, What is the molarity of Na2S203 solution? (molar mass of KBrOs = 167 g mol-t) For the estimation of nitrogen, 1.4 g of an organic compound was digested by Kjeldahl method and the evolved ammonia was absorbed in 60 mL of * sulphuric acid, The unreacted acid required 20 mL of sodium hydroxide for complete neutralization, The percentage of nitrogen in the compound is, 10 ml. of sulphuric acid solution (specific gravity = 1.84) contains 98% by weight of pure acid. Calculate the volume (in mL) of 2 N NaOH solution required to just neutralize the acid. ‘An aqueous solution of 6.3 g of oxalic acid dihydrate is made upto 250 mL.. The volume (in mL) of 0.1 N NaOH required to completely neutralise 10 ml. of this solution is: 25 mL. of (N/10) Na2COs solution neutralises 10 ml. of a dilute H2S0s solution. The volume (in mL) of water that must be added to 400 mL. of this H2S0s solution in order to make it exactly N/10is: Number of moles of CaO required to remove hardness from 1000 litre water having 324 ppm of calcium bicarbonate and 74.5 ppm of potassium chloride is : One litre of a sample of hard water contains 11.1 mg of CaCl: & 9.5 mg of MgClz. What is degree of hardness in terms of ppm of CaCO?