States of matter (Real Gas) JEE Main Pattem Solutions Section-A Ans. (2) Ease of liquification « critical temperature Ans. (1) At high pressure and low temperature gas molecules comes closer and attraction operates. Ans, (4) We can obserb it by certain approximation in Vander Waals gas equation, Ans. (4) At very low temperature gas deviates from ideal behaviour. Ans. (2) a & Intermolecular force attraction & B.P. Ans, (2) ; Putin Vander Waal gas equation. Ans. (2) 2Z= P,=—4,. Put the given Values and get atm. 2b Ans. (1) Formula obtained from kinetic gas obtained Ans. (3) Z> 1 at Boyles temperature in higher pressure reason, Ans. (4) Vm = 4 x VNo Ans. (1) Pi= Pots + | Pa SE vy *( an?) re (v-nb) = nRT When an increase => Pi increase => Poss decrease. Ans. (3) ‘As Xe has longest radius w.r.t, rest gases.States of matter (Real Gas) JEE Main Pattem 13. Ans.(1) 8a Tee ° D7Rb Ans. (1) BRT M Urns = Tes Zao = 1623.3 ~ 1620 K Ans. (3) 8a Ve = 3b, Pe= = 27Rb a ze'T Ans. (2) Pc=75 atm, Ve=? tex Pee RT, 3 75xV, 8 0.0821x300 3. 24.63 ay 702 Ans. (4) At Boyle's temperature Z = 1 hence. = 28 _ 640K = 367°C 0.25States of matter (Real Gas) JEE Main Pattem Section -B Ans. (0.667) PV g= PM aRT RT = PV ___MPV___MP__ MP “(W/M)RT WRT (W/V)RT dRT MP ‘aRT 18% 10%328.4x1.01%10'Pa__135x10°Kg__135%10" © 135kg/m*x8314x800K dmxidmxidm — 10%m° _5989.5234x10? ~~ 897912 = 0.00667 x 10? = 0.667 » d= 135 g/dm? 0.667 Ans, (160) ‘The temperature at which gas behaves ideally is called Boyle's temperature Ta=540K Zer- 24540 = 160k 27 27 Ans, (58.82) 3x200 -™ ——3%200_ ig a3 19-24 ey - x314x13.6xN, 3 *10 beav 4 = 4x 5 n0ONs =4x $53.14 15.83 x 104 6022 « 108 = 588 em Ans. (0.489) Molarity = 6 mol/ P=72atm T=300KStates of matter (Real Gas) JEE Main Pattem ‘At 1s we have to calculate Vm a : [3] (Vm-b) =RT PV3 +aV, ~ab Vo PVS +aVie—ab= V2(RT+Pb) By putting the values of given terms We get, [N = 5.60 L] Ans, (1.622) 008x400 4.0 20-04 (20) 2 001 196 632 - 0.01 = 1.622 Asd=168/L . for 1 mol gas v=? 1.6g-1L 1 32x 10=20L. 6 1 32g- 8 T6 Ans. (0) PM aT PM _500x16/0.246%10" pRT _0,0821200 x=0 zStates of matter (Real Gas) JEE Main Pattem 8. AN 150 = 3454 ~ 38.48 7 9 1000.08 25 = 0.12 L= 120 ml