Atomic Structure JEE Main Pattem SOLUTIONS SECTION-A New atomic mass =7 +35 = 10.5 Charge in atomic mass = 14 - 10.5 = 3.5 Atomic mass reduced by 25%. Ans.D hh = 663 x10 Js, c= 3x 10° m/sec v=8x 10% sect Gam) = 37.5 x 10° 7.5 0m X= 3.75 x 10° m Ans.D 3° excited state ie.n=4 Velocity of an electron = 2.18 x 10° x2 = 2.18% 108 x! 188 x 10° m/s = 2.188 x 109 km/s Ans. A z By =713.6x5 for H-atom in ath orbit (E,) = “136 x for He* innth orbit => (B,)! = -13.6x (&)! = -13.6 x4 (By)! = 4x (-13.6x 4)Atomic Structure JEE Main Pattem Ans.C B, =-13.6x5 Hyperbolic graph Ans. C For shortest wavelength. (@2 > m4) Ans.A transition will be 3 + 2 =Rx7z? (2-2) = Seber 2 36 wive number Ans. B Last electron of K- Electronic configuration of K* => 1s? 2s? 2p6 3s? 3p® Last electron is in 3p subshell For 3p subshell n=3,e=1, mean be-1,0,+1 m, can be or s 2 2Atomic Structure JEE Main Pattem Ans. D In any atom, values of principal quantum no. = (1 to 20) So, possible shells will be co Ans. C KB istmv? = qxV a de Broglie wavelength = = inv > Fiavm (mg = 4m, charge of a-particle = 2 x charge on electron) Angular momentum = (Y@@ #1) = for s-orbital ¢ = 0 Angular momentum will be zero for s-orbital. Ans. C Values of ¢ o 4s > 3p > 3s Ans. A Volume of nucleus Volume fraction = otal volume ofatom = 10"Atomic Structure JEE Main Pattem 16. Ans. C Bohr's theory is applicable for single electron species. He*? has zero electrons. Ans.B The spectrum of hydrogen has many spectral lines, These lines are formed due to electronic transitions. All the wavelengths in the Lyman series are in the ultraviolet band. If n is the lowest energy level then n = 1 for Lyman series, The number of lines in orbit for Lyman series is n ~ 1. Ans.A Initial state (A) —— final state (B) rot 3 22 (nt — 8) (ror) = 24 (2x 1) Put the value of ry~r2 in equation (1) => 24=(nf—n3) = mon 5 > 1, will satisfy the above equation (2) Ans. C Photon of violet light has maximum energy, maximum frequency and minimum wavelength. On the other hand, photon of red light has minimum energy, minimum frequency and maximum, wavelength, Ans.D d’ configuration. AL {Ab} 4 total spi SECTION-B Ans.9 Here we need only m, = (-3), electrons Crea = 1st 2st iH) f) &Atomic Structure JEE Main Pattem Ans. 6 # Feng = 18? 25? 2p* 35? 3p® 3d° 45? = [Ar]ig 3d° 487 Magnetic moment = 4.89 BM. n@F2) = 4893 =4 inpaired electrons => Fett = [Arh 3d° 4s" [5 unpaired e*] Fet? = [Ar];q 3d° 45° [4unpaired e"] (minimum) Fet? = [Ar]iq 3° 45° [5 unpaired e"] Fet* = [Ar], 3d* 4s° [4 unpaired e-] (maximum) maximum value of 'x' = 4 minimum value of 'x' = 2 sum =6 Ans, 319.20 vy =3.2x 1095 st => KE, 0X 10° 5" => KE, hv-$ KE, = 2KE, => hy, 6 = 2(hv2 - 6) h(2v2 — vs) > = 6.626 x 10-(2 x 2 x 10° — 3.2 x 10") = 6.626 x 10°*(0.8 x 1015) =5.3 x 101 = 5.3 x 107? kj This is the work function for one atom. The work function for one mole of atom is 6.023 X 103 x 5.3 x 10°? kJ/mole = 319, 20 kJ/mole Ans. 16 According to Aufbau principle electronic configuration of Cu is [Ar]4s? 3d? AL }AL J4L J 1b) 1 no, of exchange pairs (for spin up) = at no, of exchange pairs (for spin down) = Total no. of exchange pairs = 10 + 6 = 16 Ans, 0.62 E=eVy Given, Vp = 2 x 10*V 1,6 x 1071 x 2.x 104 = ‘39x11 = 0621A x = 6.21 x10" m Ans, 3.06 ‘The kinetic energy of the electron = 3.06 eV The voltage required (V) to bring the electron to rest. 3.06eV=eVo = Vo=3.06V.Atomic Structure JEE Main Pattem Ans. 2.66 Radio waves travel at the speed of light = Distance = speed x time 3 8x 10x 10 m= 3x 10°" Hyline 42 Hline 52> Hyline prRe(G-F for Hg line (3 > 2) ividing equation (1) by equation (2), we get dy 5x68 3 36x12 dy = 2x 6565A 7 Dy = 4862.96 A (662x107 84)? © 2x9,2x1 0-82 x1,6x 1029 x (5001019)? > 6.03 104 = (yx 10) 03 Ans. 28 Energy of n-photons = = she _ 49-17 ame m= 10 'Bx6.626x10-84xax108 ‘S500 ; one 550x107 0 Gezexaxa0 08 n= 28 10-17