States of matter (Ideal Gas) (JEE Main Pattern) Solutions Section-A Ans. (3) Given : Initial temperature (11) = 20°C = 293 K and final temperature (T2) = 40°C = 313K. BRT, _3xRx293 2N, 2xN, BRT, _ 3xRx313 2N, -2xN, We know that initial kinetic energy of neon atom (KE1, Similarly, final kinetic energy of neon atom (KE2) = _ 34RX298, 313 313, gp 2xN, "293 293 ‘Thus, the factor by which kinetic energy of neon atom changes = x Ans, (2) ‘As gas are non-reacting, then total moles remain conserved, ni=ne PoVi + PeV2 = PN 1x 100 + 1.5 x 300 = Pr(100 + 300) pr= 550 500 = 1.375 atm Ans. (2) Kinetic energies per molecule will be same because itis proportional to absolute temperature only. 3RT 1 Unis = PE Unis x = M vu fy, _ My, _28 je aNe> molecular attraction Ans. (2) Vy, =10xV2 = 14.141States of matter (Ideal Gas) (JEE Main Pattern) 11. Ans. (4) Given : Temperature of gas (T) = 25°C = 298k BRT 3%0,0821%298 _ 2N, 2x(6.023x10") We know that kinetic energy per molecule of an ideal gas = 6.1 x 10-25} (where R = gas constant equal to 0.0821 L-atm-mol-tk-t and Na= Avogadro's no, equal to 6,023 x 1028), Ans. (2) Nis and HCI & HBr is a reacting gas mixture to produce NHsCl & NHsBr so Dalton’'s law is not applicable. Ans. (4) x, -—2/2 "2 72432/64 ___ 32/64 Ans. (2) ny =n, T1 = 300 K, T2= 500 K, n=? At constant pressure m:T1 = n2T2 nx300 500 5 moles of air escaped = Initial moles - Final moles % of air escaped = x100 = 40% Ans. (1) Given : Final pressure of a gas (P2) = 3P1 (where Ps is initial pressure) We know from the Boyle's law that at constant temperature P1V1 = P2V2 orVe= PPM MV 338 PF 3R, ..{where Vi and V2 are initial and final volumes of the gas)States of matter (Ideal Gas) (JEE Main Pattern) 16. Ans. (3) Given : Weight of the carbon monoxide (CO) = 28 g; pressure of the carbon monoxid atm; volume of carbon monoxides = 3 litres and gas constant (R) = know that molecular weight of the carbon monoxide (CO) = 12 + 16 Therefore no. of moles in 2.8 g of the carbon monoxide. n=___Weight ofcarbon monoxide _28 Molecular weight of carbon monoxide 28 We also know from the ideal gas equation that temperature of the carbon monoxide. PV 0.a21x3 T=2 OSE 300K AR 0,1%0,082! =01 Ans. (3) At constant volumes P « T Pv=enrT -. P= SR M _16x1+28%1 =22 g/mol 7 g/mol 0.98 gL me 90821 x273 Ans, (1) Constant v Px Tat constant volume, p= Ans. (1) Protal= Peas + Py.g =725 torr & Pgs = 725-25 = 700 torr Ps = 750 torr P2 = 700 torr Vi= 127.4 ml V2=? 11=273K = 750%127.4 7 T 273 => V2= 150mlStates of matter (Ideal Gas) (JEE Main Pattern) 21, Ans. (1) pa okt. Mut. at at, R for same gas R Ans, (2) Given : Initial volume (Vs) = 11. = 1000 ml; Initial temperature (11) =27°C = 300 K and final temperature (T2) = -5°C = 268 K. We know from the Charle's law that at constant pressure 1000 5 *268= 893.3 ml (where V2 = New volume of the gas) Ans. (1) Given : Pressure of gas = P and density of gas = p. SECTION-B Ans, (170) Given : rms velocity of the molecules of the gas (brms) = 184.5 m-s-t, BRT [ert u u, nos ve aM ‘We know that average velocity of the molecule of a gas = 0.9213 rns = 0.9213 « 184. Ans, (606) Given : Temperature of oxygen (T) = 303 K We know that molecular weight of oxygen (02) (Mi) = 16 x 2= 32 And molecular weight of sulphur dioxide (S02) (Mz) = 32 + (16 * 2) = 64 we also know that rms. velocity of a gas 32 oy 4, 303264 _ go 6K 1 * Tet” 32 (where Tz = Temperature of sulphur dioxide). Therefore Ans, (532.4) Second member of CaHzn series, _ [BRT _ [BRT =M, aM, T2=5324KStates of matter (Ideal Gas) (JEE Main Pattern) 4. Ans. (16) Mi = 64512 = 2r1 Ans, (3.74) Given : Temperature of an ideal gas = 300 k and number of mole of gas(n) = 1 We know that kinetic energy of an ideal gas = Sart : 3 x 1x 8314 x30 = 3740) =3.74) (where R = universal gas constant equal to 8.314 J-mol-tk-*), Ans. (2) Given : Number of moles (n) = 2; Temperature of gas (T) = 540 K and volume of gas (V) = 44.8 litres. ‘We know from the ideal gas equation that pressure (P) = BRT = 200527540 _ a5tm _.(where R = Gas constant equal to 0.0821 lit-atm/mol/K) Ans, (12.3) ART _05x0.0821x300 760 760. 0.0821%300 1 Ans, (2,46) P= 2.463 atm Ans. (5) Psi = mT: PeVa=mRT2 B38 _n, R300