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FLETCH

UNIT 6:
STOICHIOMETRY

Lesson 5: Stoichiometric Conversions

Ms. Laura D. De Guzman


SCIENCE 9 – CHEMISTRY Ms. Yomiko Danise P. Elores
Mr. Paolo Herminio C. Regal

La Salle Green Queries and complaints can be directed to the Data Protection Officer via email at dpo@lsgh.edu.ph.
REVIEW OF IMPORTANT CONCEPTS
E
N
G
A
G
E
Today we are going to review a very IMPORTANT SKILL that
you have encountered in the second trimester.

What could it be?

Yes, it’s BALANCING CHEMICAL EQUATIONS.


REVIEW OF IMPORTANT CONCEPTS
E
N
G
One of the following equations is not the same as the others. Which A
G
of these is NOT a balanced chemical equation? E

Zn + 2 HCl → ZnCl2 + H2

2 Al + 6 HCl → 2 AlCl3 + 3 H2

3 Na2CO3 + 2 HCl → 3 NaCl + H2CO3


REVIEW OF IMPORTANT CONCEPTS
E
N
Knowing that the third chemical equation is not balanced, kindly G
A
balance that chemical equation. G
E

Zn + 2 HCl → ZnCl2 + H2

2 Al + 6 HCl → 2 AlCl3 + 3 H2

3 Na2CO3 + 2 HCl → 3 NaCl + H2CO3


REVIEW OF IMPORTANT CONCEPTS
E
N
Na2CO3 + 2HCl → 2 NaCl + H2CO3 G
A
G
E
2 Na 1 X 2
1 C 1
1 X 2 Cl 1 X 2
1 X2 H 2
3 O 3

It’s balanced!
READING ACTIVITY
E
X
P
L
Read silently B. Reaction Stoichiometry: 1. Interpreting O
R
Balanced Equations and 2. Stoichiometric Equivalence on E

pages 103-104 of your JHS Proficiency Worktext in


Chemistry.
STOICHIOMETRIC CONVERSIONS
C6H12O6 → 2 C2H6O + 2 CO2 E
X
What is the coefficient of C2H6O ? 2 P
What is the ratio between the moles of C6H12O6 and the moles of C2H6O? 1:2 L
O
R
4 Fe + 3 O2 → 2 Fe2O3 E

What is the coefficient of Fe? 4


.
How many oxygen atoms are present before or after the reaction? 6
If I have 6 atoms of Fe, how many f.u. of Fe2O3 will be produced? 3

Sb2S3 + 6 HCl → 2 SbCl3 + 3 H2S


What is the coefficient of HCl? 6
What is ratio between the moles of Sb2S3 and the moles of H2S? 1:3
If I have 30 moles of HCl, how many moles of H2S do I have? 15
STOICHIOMETRY
Derived from Ancient Greek words
Study of"element"and
stoicheion the quantitative aspects
metron of chemical formulas and reactions
"measure" E
X
Two Parts of Stoichiometry P
L
COMPOSITION - refers to the atomic make-up of a chemical A
I
• Mole Concept ✔
compound N
• Percent Composition✔
• Empirical and Molecular Formula✔
REACTION - refers to the amount of compounds consumed or produced
during a chemical reaction
• Theoretical Yield ✔
• Excess and Limiting Reagant/Reactant x
• Percent Yield ✔
STOICHIOMETRY
Types Stoichiometric Conversions
(Reaction Stoichiometry) E
X
P
• Mole to Mole L
A
I
N
• Mole to Mass

• Mass to Mole

• Mass to Mass
STOICHIOMETRIC CONVERSIONS
Numerical coefficients represent ratio of moles, particles, volumes of gases but NOT
masses.
E
C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(g) X
P
L
1 mol 5 mol 3 mol 4 A
I
1 molecule 5 3 4 mol N

1L molecules
5L molecules
3L molecules
4L
1g 5g 3g 4g
STOICHIOMETRIC CONVERSIONS: MOLE TO
MOLE
1. Given the following balanced chemical equation:

Na2Cr2O7 + 6 HI + 4 H2SO4 🡪 3 I2 + Na2SO4 + 7 H2O + Cr2(SO4)3 E


X
P
L
a. How many moles of I2 are formed from 2.00 moles of HI? A
I
N
2.00 mol = 1.00 mol I2
HI
b. How many moles of HI will react with 12.0 moles of H2SO4?

12.0 mol H2SO4 = 18.0 mol HI


STOICHIOMETRIC CONVERSIONS: MOLE TO
MOLE
2. The balanced combustion chemical equation of octane, C 8H18, is:
E
2 C8H18 + 25 O2 🡪 16 CO2 + 18 H2O X
P
a. How many moles of octane are needed to completely react with 12.5 L
moles of oxygen gas? A
I
N
12.5 mol O2 = 1.00 mol C8H18

b. How many moles of water will be produced if 15.50 moles of octane


react with excess oxygen gas?
15.50 mol C8H18 = 139.5 mol H2O
STOICHIOMETRIC CONVERSIONS: MOLE TO
MOLE
To summarize…
E
X
P
L
A
I
N
STOICHIOMETRIC CONVERSIONS: MOLE TO
MOLE

Kindly answer EXERCISE 9.6: STOICHIOMETRIC CONVERSION: E


L
MOLE TO MOLE on PAGE 120 #3 of the JHS PROFICIENCY A
B
WORKTEXT IN CHEMISTRY. Kindly take a clear picture of the page in O
portrait orientation and submit on the prescribed google forms link found in R
A
LESSON 5: STOICHIOMETRIC CONVERSIONS > EXERCISE 9.6 in T
your RANGER 360. E

DO NOT FORGET TO INCLUDE YOUR NAME ON THE TOP PART OF THE PAGE.
STOICHIOMETRIC CONVERSIONS: MOLE TO
1.
MASS
In some parts of the world, when a person is convicted of a capital crime and is
sentenced to death, the execution is carried out with a poison gas (HCN). The following
reaction is used to produce the poison gas: E
X
H2SO4 + 2 KCN 🡪 K2SO4 + 2 HCN P
L
a. How many grams of H2SO4 are needed to react with 2.00 moles of KCN? A
I
N
2.00 mol KCN = 98.09 g H2SO4

*calculated molar mass of H2SO4 = 98.09 g/mol


= 98.1 g H2SO4

b. How many grams of K2SO4 will be formed from 5.45 moles of H2SO4?
5.45 mol H2SO4
= 949.7715 g K2SO4
*calculated molar mass of K2SO4 = 174.27 g/mol
= 950. g K2SO4
STOICHIOMETRIC CONVERSIONS: MOLE TO
MASS
H2SO4 + 2 KCN 🡪 K2SO4 + 2 HCN
E
X
c. How many grams of hydrogen cyanide will be formed if 225 mol of potassium sulfate P
L
were formed? A
I
225 mol K2SO4
= 12 163.5 g HCN N

= 12 200 g HCN
*calculated molar mass of HCN = 27.03 g/mol
STOICHIOMETRIC CONVERSIONS: MOLE TO MASS

To summarize…

E
X
P
L
A
I
N
STOICHIOMETRIC CONVERSIONS: MOLE TO
MASS
Kindly answer EXERCISE 9.7 STOICHIOMETRIC CONVERSION:
MOLE TO MASS on PAGE 122 #2 of the JHS PROFICIENCY
WORKTEXT IN CHEMISTRY. Kindly take a clear picture of the page in E
L
portrait orientation and submit on the prescribed google forms link found in A
LESSON 5: STOICHIOMETRIC CONVERSIONS > EXERCISE 9.7 in B
O
your RANGER 360. R
A
T
DO NOT FORGET TO INCLUDE YOUR NAME ON THE TOP PART OF THE PAGE. E

Corrections
Equation: NH4NO3 🡪 N2O + 2 H2O
Letter C: How many grams of N2O will be formed from the decomposition of
EXERCISE 9.6: STOICHIOMETRIC CONVERSIONS:
MOLE TO MOLE

E
L
A
B
O
R
A
T
E
EXERCISE 9.7: STOICHIOMETRIC CONVERSIONS:
MOLE TO MASS

E
L
A
B
O
R
A
T
E
STOICHIOMETRIC CONVERSIONS: MASS TO
MOLE
1. The body metabolizes sucrose or table sugar by burning it with oxygen gas to produce
carbon dioxide, water and energy. The reaction is,
E
C12H22O11 + 12 O2 🡪 12 CO2 + 11 H2O X
P
L
a. If 575 grams of sucrose is burned, how many moles of carbon dioxide will be A
produced? I
N
575 g C12H22O11

= 20.155 4 mol CO2 = 20.2 mol CO2


*calculated
molar mass of C12H22O11 = 342.34 g/mol
b. How many moles of water will be formed if 600.0 g of sucrose is burned?
600.0 g C12H22O11

= 19.279 07 mol H2O = 19.28 mol H2O


STOICHIOMETRIC CONVERSIONS: MASS TO
MOLE
C12H22O11 + 12 O2 🡪 12 CO2 + 11 H2O
E
c. How many moles of oxygen gas will completely react with 410 g of sucrose? X
P
410 g C12H22O11 L
A
I
N
= 14.371 677 mol O2 = 14 mol O2
*calculated molar mass of C12H22O11 = 342.34 g/mol
STOICHIOMETRIC CONVERSIONS
To summarize…
E
X
P
L
A
I
N
STOICHIOMETRIC CONVERSIONS: MASS TO
MOLE

Kindly answer EXERCISE 9.8 STOICHIOMETRIC CONVERSION:


E
MASS TO MOLE on PAGE 124 #2 of the JHS PROFICIENCY L
WORKTEXT IN CHEMISTRY. Kindly take a clear picture of the page in A
B
portrait orientation and submit on the prescribed google forms link found in O
R
LESSON 5: STOICHIOMETRIC CONVERSIONS > EXERCISE 9.8 in A
your RANGER 360. T
E

DO NOT FORGET TO INCLUDE YOUR NAME ON THE TOP PART OF THE PAGE.
STOICHIOMETRIC CONVERSIONS: MASS TO
MASS
1. Trinitrotoluene (C7H5N3O6), an explosive chemical, is commonly known as TNT. This
can be formed by reacting toluene (C7H8) with nitric acid.
E
C7H8 + 3 HNO3 🡪 C7H5N3O6 + 3 H2O X
P
L
a. How many grams of toluene is necessary to manufacture 1x103 g of TNT? A
I
1x103 g C7H5N3O6 N

= 405.679 066 7 g C7 H8 = 400 g C7H8


*calculated molar mass of C7H5N3O6 = 227.15 g/mol
*calculated molar mass of C7H8 = 92.15 g/mol
STOICHIOMETRIC CONVERSIONS: MASS TO
1. 7 5 3 6
MASS
Trinitrotoluene (C H N O ), an explosive chemical, is commonly known as TNT. This
can
be formed by reacting toluene (C7H8) with nitric acid. E
X
C7H8 + 3 HNO3 🡪 C7H5N3O6 + 3 H2O P
b. How many grams of TNT will be formed if 460 g of toluene completely L
A
reacts with nitric acid? I
N
460 g C7H8

*calculated molar mass of C7H8 = 92.15 g/mol

*calculated molar mass of C7H5N3O6 = 227.15 g/mol


STOICHIOMETRIC CONVERSIONS: MASS TO
1.
MASS
Trinitrotoluene (C H N O ), an explosive chemical, is commonly known as TNT. This
7 5 3 6
can
be formed by reacting toluene (C7H8) with nitric acid. E
X
C7H8 + 3 HNO3 🡪 C7H5N3O6 + 3 H2O P
L
c. How many grams of HNO3 will completely react with 765 g of toluene? A
I
765 g C7H8 N

= 1 569.516 g HNO3 = 1 570 g HNO3


*calculated molar mass of C7H8 = 92.15 g/mol
*calculated molar mass of HNO3 = 63.02 g/mol
STOICHIOMETRIC CONVERSIONS
To summarize…
E
X
P
L
A
I
N
STOICHIOMETRIC CONVERSIONS: MASS TO
MASS

Kindly answer EXERCISE 9.9 STOICHIOMETRIC CONVERSION: E


L
MASS TO MASS on PAGE 126 #2 of the JHS PROFICIENCY A
B
WORKTEXT IN CHEMISTRY. Kindly take a clear picture of the page in O
portrait orientation and submit on the prescribed google forms link found in R
A
LESSON 5: STOICHIOMETRIC CONVERSION > EXERCISE 9.9 in T
your RANGER 360. E

DO NOT FORGET TO INCLUDE YOUR NAME ON THE TOP PART OF THE PAGE.
FLETCH

REMINDER
Your participation in this Gizmos
activity will be a part of your class
participation grade.
Go to Ranger under Gizmos
March Madness section.

This is due on April 27, 2023.

Use teacher’s username:


yomikode
La Salle Green Queries and complaints can be directed to the Data Protection Officer via email at dpo@lsgh.edu.ph.
EXERCISE 9.8: STOICHIOMETRIC CONVERSIONS: MASS
TO MOLE

E
L
A
B
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R
A
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E
EXERCISE 9.9: STOICHIOMETRIC CONVERSIONS:
MASS TO MASS

E
L
A
B
O
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A
T
E
STOICHIOMETRIC CONVERSIONS: % YIELD

Percentage Yield (% yield) E


X
P
L
A
I
N

Note: 1. Actual yield is given in the problem and Theoretical


yield is calculated to solve for % yield
2. Actual yield is equal to or less than the theoretical yield
3. Maximum % yield is 100
STOICHIOMETRIC CONVERSIONS: % YIELD

Theoretical E
X

Yield
The maximum (expected) amount of product that can be
P
L
A
obtained by the reaction from the given amount of reactant. I
N

Actual Yield
It is the experimental value.
It must be equal to or less than the theoretical yield.
STOICHIOMETRIC CONVERSIONS: % YIELD

E
ACTUAL YIELD Possible Errors X
P
L
A
I
• Products are lost during separation in the mixture N

• Impurities
• Reaction stops before its completion
• Undesirable side reactions
STOICHIOMETRIC CONVERSIONS: % YIELD
1. Silver chromate, AgCrO4, can be precipitated by mixing aqueous solution of silver
nitrate, AgNO3, and potassium chromate, K2CrO4.
E
2 AgNO3 + K2CrO4 🡪 Ag2CrO4 + 2 KNO3 X
P
Suppose an aqueous solution containing 5.32 g AgNO3 is allowed to react with excess L
K2CrO4 and 4.77 g Ag2CrO4 is obtained, calculate the theoretical yield and percentage A
I
yield of the reaction. N
5.32 g AgNO3

= 5.194 421 945 g AgCrO4 = theoretical yield


*calculated molar mass of AgNO3 = 169.88 g/mol
*calculated molar mass of Ag2CrO4 = 331.74 g/mol

= 91.829 274 76 % = 91.8 % = % yield


STOICHIOMETRIC CONVERSIONS: % YIELD
2. Citric acid (C6H8O7), a component of jams, jellies and fruity soft drinks, is prepared
industrially in the fermentation of sucrose by the mold Aspergillus Niger. The equation
representing this reaction is E
X
C12H22O11 + H2O + 3 O2 🡪 2 C6H8O7 + 4 H2O P
L
What mass of citric acid is actually produced from exactly 1000. g of sucrose, A
C12 H22O11, if the yield is 92.30 %? I
N
1 000. g C12 H22O11

= 1 122.509 786 g C6H8O7 = theoretical yield


*calculated molar mass of C12H22O11 = 342.34 g/mol
*calculated molar mass of C6H8O7 = 192.14 g/mol

= 1 036.076 532 g C6H8O7 = 1 036 g C6H8O7 = actual yield


PERCENTAGE YIELD: SEATWORK
3. Freon-12, CCl2F2, is prepared from CCl4 by the reaction with HF. The other product of
this reaction is HCl. The reaction is E
CCl4 + 2 HF 🡪 CCl2F2 + 2 HCl X
P
Determine the actual yield of CCl2F2 from 32.9 g CCl4, if the % yield is 58.3 %. L
A
32.9 g CCl4 I
N

= 25.862 681 23 g CCl2F2 = theoretical yield


*calculated molar mass of CCl4 = 153.81 g/mol
*calculated molar mass of CCl2F2 = 120.91 g/mol

= 15.077 943 16 g CCl2F2 = 15.1 g CCl2F2 = actual yield


STOICHIOMETRIC CONVERSIONS: % YIELD

Kindly answer EXERCISE 9.10 PERCENT YIELD on PAGE 127 #2 of the E


L
JHS PROFICIENCY WORKTEXT IN CHEMISTRY. Kindly take a clear A
B
picture of the page in portrait orientation and submit on the prescribed google O
forms link found in LESSON 5: STOICHIOMETRIC CONVERSIONS > R
A
EXERCISE 9.9 in your RANGER 360. T
E

DO NOT FORGET TO INCLUDE YOUR NAME ON THE TOP PART OF THE PAGE.
FLETCH

UNIT 6:
STOICHIOMETRY

Lesson 5: Stoichiometric Conversions

Ms. Laura D. De Guzman


SCIENCE 9 – CHEMISTRY Ms. Yomiko Danise P. Elores
Mr. Paolo Herminio C. Regal

La Salle Green Queries and complaints can be directed to the Data Protection Officer via email at dpo@lsgh.edu.ph.
EXERCISE 9.10: STOICHIOMETRIC CONVERSIONS: %
YIELD

E
L
A
B
O
R
A
T
E
STOICHIOMETRIC CONVERSIONS

To recall…

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A
I
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PRACTICE DRILLS: STOICHIOMETRIC
CONVERSIONS
Today you will answer some exercises on stoichiometric conversions for practice and mastery.
1. Given the chemical equation: 2 H2 + O2 → 2 H2O
E
a. How many moles of oxygen are needed to react with 25.0 mol of hydrogen? L
A
25.0 mol H2 = 12.5 mol O2 B
O
R
A
T
b. How many grams of water will be produced from 14.2 mol of oxygen gas? E

14.2 mol O2
= 511.768 g H2O
= 512 g H2O
*calculated molar mass of water = 18.02 g/mol
PRACTICE DRILLS: STOICHIOMETRIC
CONVERSIONS
Today you will answer some exercises on stoichiometric conversions for practice and
mastery.
2. Suppose 6.00 x104 moles of H2 are reacted with sufficient nitrogen. Given the equation,
N2 + 3 H2 → 2 NH3
E
a. How many moles of ammonia would be produced? L
A
6.00 x 104 mol H2
= 40 000 mol NH3 = 40 000 mol NH3 B
O
R
A
b. How many grams of nitrogen gas would be needed? T
E
6.00 x 104 mol H2
= 560 400 g N2
= 560 000 g N2
*calculated molar mass of N2 = 28.02 g/mol
PRACTICE DRILLS: STOICHIOMETRIC
CONVERSIONS
Today you will answer some exercises on stoichiometric conversions for practice and mastery.
3. Carbon disulfide is an important industrial solvent. It is prepared by the reaction of
carbon (called coke) with sulfur dioxide:
5 C(s) + 2 SO2(g) ---> CS2(ℓ) + 4 CO(g) E
L
A
a. How many moles of carbon are needed to react with 500. g SO2? B
O
500. g SO2
= 19.509 911 mol C R
A
= 19.5 mol C T
E
*calculated molar mass of SO2 = 64.07 g/mol
b. How many grams of SO2 are required to make 125.0 g CS2?
125.0 g CS2
= 210.34143 g SO2
= 210.3 g SO2
*calculated molar mass of CS2 = 76.15 g/mol
PRACTICE DRILLS: STOICHIOMETRIC
CONVERSIONS
Today you will answer some exercises on stoichiometric conversions for practice and mastery.
4. Given the following balanced chemical equation:
C5H12(g) + 8 O2(g)→ 5 CO2(g) + 6 H2O(g)
E
a. How many moles of oxygen are needed to react with 5.00 grams pentane? L
A
5.00 g C5H12
= 0.554246917 mol O2 B
O
R
= 0.554 mol O2 A
*calculated molar mass of C5H12 = 72.17 g/mol T
E
b. How many grams of carbon dioxide can be formed if 20.00 g of pentane were to react?
20.00 g C5H12

= 60.98101704 g CO2
= 60.98 g CO2
*calculated molar mass of CO2 = 44.01 g/mol
PRACTICE DRILLS: STOICHIOMETRIC
CONVERSIONS
Today you will answer some exercises on stoichiometric conversions for practice and mastery.
4. Given the following balanced chemical equation:
C5H12(g) + 8 O2(g)→ 5 CO2(g) + 6 H2O(g)
E
c. If the reaction of 20.00 g of pentane produces 50.00 g of carbon dioxide, what would L
A
be the percentage yield of the reaction? B
O
R
A
From letter b, 20.00 g pentane would theoretically produced 60.98101704 g CO2 T
E
From letter c, 50.00g of CO2 is the actual yield.

= 81.99272893 %
= 81.99 %
QUIZ 3.4: STOICHIOMETRIC CONVERSIONS

E
V
A
Prepare for a 15-item quiz on stoichiometric L
U
conversions and percentage yield NEXT MEETING. A
T
E
FLETCH

UNIT 6:
STOICHIOMETRY

Lesson 5: Stoichiometric Conversions

Ms. Laura D. De Guzman


SCIENCE 9 – CHEMISTRY Ms. Yomiko Danise P. Elores
Mr. Paolo Herminio C. Regal

La Salle Green Queries and complaints can be directed to the Data Protection Officer via email at dpo@lsgh.edu.ph.
STOICHIOMETRIC CONVERSIONS

To recall…

E
X
P
L
A
I
N
FLETCH

SCAFFOLDING ACTIVITY 3.2


INSTRUCTIONS: Read, understand and comprehend the scenario below.
A student managed to compute for the moles of isopropanol in the previous
scaffolding activity. The equation was also balanced to be as follows:

2 C₃H₈O + 9 O₂ → 6 CO₂ + 8 H₂O

Note the following information:


0.522 moles of isopropanol (C₃H₈O) will be the given for all computations
Molar mass of O₂ is 32.00 g/mol
Molar mass of CO₂ is 44.01 g/mol
Molar mass of H₂O is 18.02 g/mol
INSTRUCTIONS: Read, understand and comprehend the scenario below.
FLETCH

SCAFFOLDING ACTIVITY 3.2


PART I. REACTION STOICHIOMETRY
Answer each of the following questions. Write only the magnitude
(number), no need to write the unit. Do not forget to apply the rules on
significant figures.
1. What is the mass in grams of oxygen gas needed? (5 points)
SOLUTION USING DIMENSIONAL ANALYSIS:
2. What is the mass in grams of carbon dioxide produced? (5 points)
SOLUTION USING DIMENSIONAL ANALYSIS:
3. What is the mass in grams of water produced? (5 points)
SOLUTION USING DIMENSIONAL ANALYSIS:
INSTRUCTIONS: Read, understand and comprehend the scenario below.
LONG TEST 3.1: STOICHIOMETRIC CONVERSIONS

Prepare for a 30-item long test on significant figures, E


V
mole concept, percent composition, empirical and A
L
molecular formulas, balancing chemical equations, and U
A

stoichiometric conversions and T


E

percentage yield NEXT MEETING.


REMINDERS

SCAFFOLDING ACTIVITY 3.2 (STOICHIOMETRIC CONVERSIONS)


Cycle 6 Meeting 1 - Asynchronous

E
V
EXPERIMENT OF FINAL OUTPUT OF PERFORMANCE TASK
A
Cycle 6 Meeting 1 - Asynchronous L
U
A
T
LONG TEST 3.1 – STOICHIOMETRY E
Cycle 6 Meeting 2
Be ready with your scientific calculator

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