Cu trc spinel

Cng thc chung: AB2O4 trong A l kim loi ha tr 2, B l kim loi ha tr 3. Mi mng cha 8 phn t. Mi oxit tn ti 1 l trng bt din v 2 l trng t din, trong kch thc l trng t din nh hn Tn ti 2 dng cu trc: spinel thng thng (nornal spinel) v spinel ngc (inverse spinel).

Cu trc spinel
Cu trc spinel thng thng:
B (KL ha tr III) chim l trng bt din v ch c th chim s l trng bt din. A chim l trng t din, c th chim 1/8 s l trng t din Cu trc c kch thc A, B gn nhau s c nng lng mng tinh th ln nht. VD: MgAl2O4

Cu trc spinel

Cu trc mng AB2O4, A 2+: mu xanh l cy, chim 1/8 tng s l trng t din, B3+ mu xanh dng chim tng s l trng bt din, Oxy mu ( biu din mt trc ca 1 c s)

Cu trc spinel
Cu trc FCC. M2+: mng fcc (4 ion/ nh) + 1/8 ion ti 8 v tr nh+ *3 ion ti FCC = 8 ion/ c s M3+ : 4 ion ti 4 trong 8 v tr octan =4*4 = 16 ion/ c s O2- : 4 ion ti im gc ca v tr octan = 4*8= 32ion/ c s. Trong 1 c bn, cng thc ca hp cht spinel l [M2+]8[M3+]16O32 hoc (M2+8/3M3+16/3)[M2+16/3M3+32/3]O32