PHIU AN TON HA CHT

XNG KHNG CH CC LOI

S CAS: 8006-61-9 S UN: 1203

PHN I. THNG TIN SN PHM V DOANH NGHIP

Tn thng gi: Xng khng ch Tn thng mi: Xng RON 92, RON 95 Tn khc (khng l tn khoa hc): Gasoiline Tn nh cung cp hoc nhp khu TNG CNG TY XNG DU VIT NAM PETROLIMEX S 1 - Khm Thin - ng a - H ni Tn nh sn xut v a ch: Mc ch s dng: lm nhin liu cho cc loi ng c t trong. Lin h trong trng hp khn cp: Tng cng ty Xng du Vit Nam S 1-Khm Thin-ng a- H Ni Tel. 04 38512 603 Fax. 04 38512 902

PHN II. THNG TIN V THNH PHN NGUY HIM

Tn thnh phn nguy him 1. Benzen 2. Hydrocacbon thm S CAS 71-43-2 Cng thc ha hc C6H6 Hm lng
(% theo th tch, max)

2,5 40

PHN III. NHN DNG NGUY HIM

1. Mc xp loi nguy him: NFPA. Health :3, Flammable:3, Reactivity:0 2. Cnh bo nguy him: - Xng khng ch cc loi l sn phm d chy n khi tip xc vi ngn la trn iu kin nhit bnh thng. - Xng khng ch cc loi c th gy kch thch h thn kinh hoc bng da trong trng hp tip xc trc tip lu di v thng xuyn. - Lu khi tip xc, bo qun, s dng: Xng khng ch cc loi l sn phm d bay hi nhit thng, c tn tr th lng trong cc thit b cha ng chuyn dng, tuyt i trnh xa cc ngun nhit, ngun in, ngun la trn v tm vi ca tr em. Bo qun mt hng xng khng ch ni thong kh, s dng phng tin bo h lao ng ph hp khi tip xc vi xng khng ch. Trong qu trnh vn chuyn c th xy ra hin tng tnh in trong xng khng ch v vy trc khi bm np, x hng t cc phng tin vn chuyn phi s dng cc thit b chuyn dng nh nam chm tnh in, tip t... phng nga s c chy n do hin tng tnh in.
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3. Cc ng tip xc v triu chng: ng mt: C th gy kch thch v cc tn thng cho mt. ng th: Hi xng gy kch thch ng h hp. Ht th hi xng vi nng cao s gy nn tc ngc, bun nn, kh th, lon nhp tim, au u. Trnh ht th trc tip vi hi xng. ng da: Tip xc lin tc v thng xuyn s gy kch thch v vim da ng tiu ha: gy bun nn, tc ngc, au u, kh th, c cm gic say, l ln, hoa mt, sung huyt phi, mt cm gic. Cp tnh: tip xc vi n-pentan vi nng di 5.000ppm trong vng 10 pht s khng c du hiu ng c nhng vi nng trn 5.000ppm s gy kch thch mi v c hng, au u, chong vng, mt mi, kh th. Nu nng rt cao s gy bun nn, mt thng bng, c cm gic lun ngi thy mi xng v kh th.

PHN IV. BIN PHP S CU KHI GP TAI NN

1. Trng hp tai nn tip xc theo ng mt: a nn nhn ra ni an ton, thong mt. Dng nc sch ra mt trong vng 15 pht sau a nn nhn i gp bc s. 2. Trng hp tai nn tip xc trn da: S dng nc v x phng ra sch vng da b nhim xng du. Trng hp vng da b d ng hoc b tn thng nng phi a nn nhn i gp bc s. 3. Trng hp tai nn tip xc theo ng h hp: a nn nhn ra ni an ton, thong mt. Trng hp nn nhn b ngt th phi s dng cc bin php tr th, h hp nhn to v a i cp cu kp thi. 4. Trng hp tai nn theo ng tiu ha: Tuyt i khng c khuyn khch, tr gip nn nhn nn ma v c th gy bin chng phi. C th dng than hot tnh (1g/kg cn trng lng c th) v a i cp cu kp thi.

PHN V. BIN PHP CHA CHY

1. Xp loi v tnh chy: Xng khng ch cc loi cc k d chy. im chp chy - 430C. Gii hn n di (LEL): 1,2% . Gii hn n trn (UEL): 7,6% 2. Sn phm to ra khi chy: Xng khng ch cc loi khi b chy to ra cc kh COx, SOx, NOx, Hydrocacbon. 3. Cc tc nhn gy chy n: Tia la, tnh in, nhit cao, va p, ma st sinh tia la. 4. Cc cht dp chy thch hp v hng dn bin php cha chy, bin php kt
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hp khc: - Cht dp chy: S dng cc bnh v thit b cha chy chuyn dng, CO2, ct, chn thm nc, phun nc lm mt thit b cha ng v cc thit b khc lin k. - Bin php cha chy: Thc hin khn cp cc bin php ban u dp tt m chy. + Ct ngun in lin quan ti m chy. + u tin cu ngi b nn, tm cch ngn chn, cch ly ngun r r xng du, di chuyn cc thng cha xng du khc hoc cc trang thit b khc lin k vi m chy nu c th. + S dng bnh cha chy, ct, chn thm nc cha chy i vi cc m chy nh. + Khng s dng nc cha chy, ch s dng nc lm mt thit b cha ng v cc thit b khc lin k. + Gi in thoi thng bo cho lc lng cnh st phng chy cha chy chuyn nghip h tr ng cu. 5. Phng tin, trang phc bo h cn thit khi cha chy: - Phng tin cha chy: Thit b cha chy c nh, xe t cha chy, xe y bt 25kg, bnh kh CO2,bnh bt 6-10kg, ct, x chu, chn chin... - Trang phc bo h: qun o chng chy, m bo v c knh che mt, gng tay, ng ... 6. Cc lu c bit v chy, n: Hi xng du rt d chy n, nng hn khng kh v di chuyn xa khi ngun r r. Nu gp ngun la c th gy chy ngc n ngun pht tn.

PHN VI. BIN PHP X L KHI GP S C TRN , R R

1. Khi trn , r r mc nh: - Tm mi cch ngn chn ngun xng du trn , r r. Lm thng thong khu vc xy ra s c. - Phong ta khu vc xy ra s c trn , r r. Ct c ngi trng coi v cnh bo cho mi ngi cng bit khu vc . - Ngn cm mi ngun la v tia la khi xy ra s c trn , r r. - S dng ct, gi lau, cc vt liu thm du chuyn dng lm sch khu vc xng du r r cng nhanh cng tt, sau thu gom vo thng cha chuyn dng tiu hy ng cch. - Khng c cho xng du chy lan vo h thng knh rch
2. Khi trn , r r ln din rng:

- Tm mi cch ct in, ngng cc hot ng xut nhp, bm chuyn xng du

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- C lp khu vc xng du trn , r r. Chun b cc phng n phng chy v cha chy. - Ln phng n bo v khu vc s c, ngn nga xng du loang rng v thc hin cc phng n thu hi xng du trn. - Thng bo cho cc c quan chc nng ti khu vc xy ra s c cng t chc h tr ng cu.

PHN VII. S DNG V BO QUN

1. Bin php, iu kin cn p dng khi s dng, thao tc: - M thng cha t t gii phng p sut hi bn trong thng cha ng. - Ch xut nhp, bm rt xng du vo cc thit b cha ng xng du chuyn dng. Phi s dng h thng nam chm tnh in, hoc tip t khi xut nhp xng du vo cc phng tin vn chuyn xng du. - Trong sut qu trnh xut nhp xng du vo phng tin vn chuyn, tuyt i nghim cm: n my ng c xe, kim tra ngun in, bo dng v v sinh phng tin. - Cm la, cm ht thuc l, khng s dng cc thit b in xch tay, thit b vin thng khng m bo an ton phng n trong khu vc tn cha, bm rt xng du. - Khng xng du trn , r r, ri vi. - Khng dng xng khng ch cc loi lau chi v sinh, khng ht xng bng ming. - S dng cc phng tin bo h c nhn khi tip xc vi xng du. Ra tay v v sinh sch s sau khi lm vic. 2. Bin php, iu kin cn p dng khi bo qun - Bo qun xng du trong cc thit b chuyn dng, cc thng cha phi y kn, ni kh ro, thong mt. - Bo qun thng cha xng du trnh cc va p mnh, trnh xa cc ngun nhit, tia la v cc cht oxy ha mnh. - Lp t h thng bo chy t ng. - Tun th cc yu cu v m bo an ton ca Nh nc v phng chng chy n, bo v mi trng, phng chng trn du trong qu trnh bo qun, tn cha, vn hnh, khai thc cc cng trnh xng du. - Phi trang b y cc thit b cha chy theo quy nh ca Nh nc trong qu trnh vn chuyn, tn cha, xut nhp xng du.

PHN VIII. KIM SOT TIP XC V PHNG TIN BO H C NHN

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1. Cc bin php hn ch tip xc cn thit: - Thc hin thng gi t nhin hoc s dng thit b phng n thng gi cng bc khu vc bo qun, xut nhp xng du. - Lp t cc trang thit b chng st, chng tnh in, h thng in an ton phng n theo ng cc quy nh ca Nh nc ti cc khu vc bo qun, xut nhp, vn chuyn xng du. 2. Cc phng tin bo h c nhn khi lm vic: - Bo v mt: Khng yu cu phi c thit b bo v mt c bit. Trong trng hp cn thit c th eo knh bo h. - Bo v thn th: Mc qun o bo h lao ng. - Bo v da: eo gng tay khi lm vic. 3. Phng tin bo h trong trng hp x l s c: - Ngi lm cng tc ng cu s c trn du, cu ha phi c trang b cc trang phng tin v thit b chuyn dng khi tip cn v gii quyt s c . 4. Cc bin php v sinh: - Ra tay bng x phng v v sinh c nhn sau khi tip xc vi xng du.

PHN IX. C TNH HA L

Trng thi vt l: lng Mu sc: sch, trong, mu vng hoc xanh ty thuc vo tng loi xng khng ch Mi: mi c trng ca xng p sut hi ( 37,8oC), kPa: 43 - 75 T trng hi (Khng kh = 1): 3 - 4 ha tan trong nc: khng ph hp PH: khng ph hp Khi lng ring (kg/m3): 0,75 Nhit si (0C): 30-210oC im nng chy (0C): khng ph hp im chp chy (0C): - 40 oC Nhit t chy: 246 - 280oC Gii hn nng chy, n trn (% hn hp vi khng kh): 7.6 Gii hn nng chy, n di (% hn hp vi khng kh): 1.2 T l ho hi (kg/l): 0.70 Cc tnh cht khc: tham kho TCVN 6776:2005

PHN X. TNH N NH V KH NNG PHN NG

1. Tnh n nh - n nh trong cc iu kin s dng v lu tr nhit v p sut thng. - Trnh tt c cc ngun nhit, ngun la trn, tnh in v cc tc nhn xy ha mnh 2. Kh nng phn ng: - C kh nng ha tan cc dung mi khc nhau. - Khng xy ra phn ng trng hp.
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Sn phm to ra sau qu trnh chy: COx, SOx NOx, Hydrocacbon.

PHN XI. THNG TIN V C TNH

- Ng c cp tnh qua ng ming i vi ngi: LDLO 50mg/kg - Gy kch thch nh trn da th nng 20mg trong 24 gi. - Gy c ch ADN trn chut nu cho ung vi liu lng 20mg/kg.

PHN XII. BIN PHP V QUY NH V TIU HY HA CHT

Vic tiu hy phi tun theo quy trnh v tiu chun chung v tiu hy ha cht theo ng quy nh ca php lut v bo v mi trng, m bo an ton cho ngi v mi trng.

PHN XIII. QUY NH V VN CHUYN

- S UN: 1203 - Ngh nh s 13/2003/N-CP ca Chnh ph ngy 19/02/2003 quy nh danh mc hng ha nguy him v vic vn ti hng ha nguy him bng ng b. - Ngh nh s 29/2005/N-CP ca Chnh ph ngy 10/03/2005 quy nh danh mc hng ha nguy him v vic vn ti hng ha nguy him trn ng thy ni a. - USA, DOT Shipping Description: Gasoline, 3, UN 1203, II - IMO/IMDG Shipping Description: Gasoline, 3, UN 1203, II - IATA/ICAO: Motor spirit, UN 1203, flammable liquids, class 3, packing group II.

PHN XIV. THNG TIN V LUT PHP

1. Tnh trng khai bo, ng k cc quc gia khu vc trn th gii: Lin hp quc, EC, Cc t chc quc t M, Anh, Hn Quc... v sn xut, kinh doanh, vn ti sn phm du m c quy nh php l v khai bo MSDS. 2. Phn loi nguy him theo quc gia khai bo, ng k: - EU category of danger: Extremely flammable, carcinogenic category, Risk phrases: R12, R45, R65, R38, R67, R51/53. Safety phrases: S2, S53, S45, S23, S24, S29, S43, S62, S61. - WHMIS classification: Class B, division 2: flammable liquids Class D, division 2, subdivision A: very toxic material carcinogenicity. Class D, division 2, subdivision B: toxic material skin or eye irritation.

PHN XV. THNG TIN KHC

1. Ngy thng bin son phiu: Ngy thng nm 2009

2. Tn t chc, c nhn son tho: Tng cng ty xng du Vit Nam (Petrolimex)
LU NGI C:

- Nhng thng tin trong phiu an ton ho cht ny c bin son da trn cc kin thc hp l v mi nht v ho cht nguy him v phi c s dng thc hin cc bin php ngn nga ri ro, tai nn. - Ho cht nguy him trong phiu ny c th c nhng tnh cht nguy him khc tu theo hon cnh s dng v tip xc. - Petrolimex s khng chu bt c trch nhim no vi nhng trng hp s dng khng ng vi cc hng dn trong phiu cnh bo an ton ny.