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    BHARGAV LAKHINENI
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    Kinetic theory of gases describes gases as large numbers of small particles in constant, random motion. There are three degrees of freedom for gas particles: 1) Translational, relating to their motion in space; 2) Rotational, relating to their rotation; 3) Vibrational, relating to changes in the arrangement of atoms. The average kinetic energy of gas particles depends on temperature, with higher temperatures corresponding to higher average kinetic energies. Gas particle speeds vary, with most particles moving at around the root mean square speed and fewer particles having either very low or very high speeds.

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    Kinetic theory of gases describes gases as large numbers of small particles in constant, random motion. There are three degrees of freedom for gas particles: 1) Translational, relating to their motion in space; 2) Rotational, relating to their rotation; 3) Vibrational, relating to changes in the arrangement of atoms. The average kinetic energy of gas particles depends on temperature, with higher temperatures corresponding to higher average kinetic energies. Gas particle speeds vary, with most particles moving at around the root mean square speed and fewer particles having either very low or very high speeds.

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    6 views7 pages

    KTG PDF

    Uploaded by

    BHARGAV LAKHINENI
    Kinetic theory of gases describes gases as large numbers of small particles in constant, random motion. There are three degrees of freedom for gas particles: 1) Translational, relating to their motion in space; 2) Rotational, relating to their rotation; 3) Vibrational, relating to changes in the arrangement of atoms. The average kinetic energy of gas particles depends on temperature, with higher temperatures corresponding to higher average kinetic energies. Gas particle speeds vary, with most particles moving at around the root mean square speed and fewer particles having either very low or very high speeds.

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    of 7

    KINETIC THEORY OF GASES

    *Degree of freedom : -

    modes
    Totoro of independent
    ( ways ] in which a system can possess

    energy .

    D Translation degrees of freedom


    KE
    ,
    = Imai ImVyYIMÉ,

    Rotational degrees of freedom

    KER £IWÑ=
    , IzIWyY- II WE

    3) Vibrational degrees of freedom


    arrangement of atoms

    ExG=Er9=fR8=£¥
    55/3 = 1.66
    Mono 3 He , He
    3-z.rs Igp
    Dia 5 1+2,02 .NL ER ER Is = 1^4

    H2O
    Toi 6 3R 4th
    ¥ = 1.33

    spot> =
    II¥;-
    Acc Kit .

    's
    G. → ¥- =
    Inr do
    Internet Guam
    E- NG, do

    ✗Gid=Enrd¢
    Cv=£④
    *
    Cp = GHB =
    ER -112=[12+1] R
    cp=①
    *
    8=¥=¥YÉ-=s¥
    8=s-
    * KE fr) internal energy per mole =
    ERT
    * KE fr) 11 11
    per molecule =
    tzkt
    Various speeds of Gas molecules : -

    * Root mean squid speed :-

    Urns =✓ñ÷vi
    from pressure equation p=§fVrmT
    Ñms= rms=¥
    3P
    "
    g-
    pv=nRT
    px=M☒RT rms=✓¥ass
    "

    P÷①=¥E xrms=F
    m=xg ±m=t
    '¥,
    varig
    g- ¥=T÷=F÷÷¥+
    =

    1¥
    F-
    OK,
    Vrms=O w¥
    Holte Zen
    Abs
    ¥z=f÷ (F- cont)
    Most probable speed
    Zmlse 4mV
    Acc
    . •

    KT G . . .
    - -

    Zmls 3m/ se
    Gmlse

    Vmp=✓¥
    vmp=✓¥"= f-
    77dm

    Vmp=⑤Vr① Vmb= 08118ms

    3) Average Speed

    Yay =
    Ytk+-,n
    Acc KT G .

    van
    :F¥
    xa-i-j.IE _j¥÷
    Vavg=✓- = Yay = 0^92Yrm,
    Vrms > Vax > Vmb

    ymg,,.g,y
    Nrm , = 1 Ams
    '

    Yay = 0 -
    92 ✗rms

    Mean free path : -


    ✗= 7+×_+-µ--Hn_
    ✗
    =ÉEñ
    Diameter of the molecule
    d: -

    n: -
    ng of
    molecular per unit Volare
    n=
    ✗ = "
    f- a-d-p
    ?⃝
    * Rel bet pressure and KE

    P=§eVrmT KE=£m×rmT

    F- 3- ✗ tgfllrms
    "rmT
    F- 3- If
    ✗ f-
    1¥
    ' " rmir
    F- g- { ✗

    P=Zz✗I① •
    I -

    pTT=2z '

    P=E

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