Experiment - 12

AIM: To identify the functional group present in the given organic compound.
S.N Experiment Observation Inference
1 With 0.2ml of organic compound in 2 ml Brown colour of Br2 Unsaturation
CCl4, bromine water was added drop wise. Remain unchanged is absent
2 A pinch of NaHCO3 was added to 0.2ml of Effervescence occured Carboxylic group is
organic compound present
3 0.2ml of organic compound was added to No Violet colouration Phenolic group
2-3 ml of FeCl3 solution. was obtained is absent

4 A small piece of sodium metal was added No effervescence Alcoholic group

to the liquid organic compound occured is absent
5 2-3ml of 2,4-dinitrophenyl hydrazine was No orange yellow ppt. Carbonyl group
added to 0.2ml of oganic compound was formed is absent
6 1ml of organic compound with 1ml of No silver mirror was Aldehyde group
Tollen's reagent in a test tube was warmed formed is absent
in a water bath.
7. To 1 ml of sodium nitroprusside , a few ml No red colouration Ketonic group
of given organic compound was added, is absent
flollowed by the addition of sodium
hydroxide solution drop wise.
8. 1 ml conc. HCl, a few drops of CHCl3 and2 No offensive smelling Amino group
ml of KOH was added to the organic gas was evolved is absent
compound and warmed.

Result : The given organic compound contain functional group …Carboxylic group

Experiment - 13
AIM:To identify the functional group present in the given organic compound
S.N Experiment Observation Inference
1 With 0.2ml of organic compound in 2 ml Brown colour of Br2 Unsaturation
CCl4, bromine water was added drop wise. Remain unchanged is absent
2 A pinch of NaHCO3 was added to 0.2ml of No effervescence Carboxylic group
organic compound occured is absent
3 0.2ml of organic compound was added to 2- No Violet colouration Phenolic group
3 ml of FeCl3 solution. was obtained is absent
4 A small piece of sodium metal was added to No effervescence Alcoholic group
the liquid organic compound occured is absent
5 2-3ml of 2,4-dinitrophenyl hydrazine was Orange yellow ppt. Carbonyl group
added to 0.2ml of oganic compound was formed is present
6 1ml of organic compound with 1ml of Silver mirror was Aldehyde group
Tollen's reagent in a test tube was warmed formed is present
in a water bath.
7. To 1 ml of sodium nitroprusside , a few ml of No red colouration Ketonic group
given organic compound was added, is absent
flollowed by the addition of sodium
hydroxide solution drop wise.
8. 1 ml conc. HCl, a few drops of CHCl3 and2 No offensive smelling Amino group
ml of KOH was added to the organic gas was evolved is absent
compound and warmed.
Result : The given organic compound contain functional group ……Aldehyde………..
Experiment - 14
AIM:To identify the functional group present in the given organic compound.
S.N Experiment Observation Inference
1 With 0.2ml of organic compound in 2 ml CCl4, Brown colour of Br2 Unsaturation
bromine water was added drop wise. Remain unchanged is absent
2 A pinch of NaHCO3 was added to 0.2ml of No effervescence Carboxylic group
organic compound occured is absent
3 0.2ml of organic compound was added to 2-3 ml No Violet colouration Phenolic group
of FeCl3 solution. was obtained is absent
4 A small piece of sodium metal was added to the No effervescence Alcoholic group
liquid organic compound occured is absent
5 2-3ml of 2,4-dinitrophenyl hydrazine was added No orange yellow Carbonyl group
to 0.2ml of oganic compound ppt. was formed is absent
6 1ml of organic compound with 1ml of Tollen's No silver mirror was Aldehyde group
reagent in a test tube was warmed in a water formed is absent
bath.
7. To 1 ml of sodium nitroprusside , a few ml of No red colouration Ketonic group
given organic compound was added, flollowed is absent
by the addition of sodium hydroxide solution
drop wise.
8. 1 ml conc. HCl, a few drops of CHCl3 and 2 ml Offensive smelling Amino group
of KOH was added to the organic compound gas was evolved is present
and warmed.

Result : The given organic compound contain functional group …Amino group………..

Experiment - 15
AIM :To identify the Glucose,Sucrose and Starch from the given samples-A,B and C
S.N Test A B C
1 Solubility Soluble Soluble Insoluble

2 Few drops of Molisch's reagent was added to Purple ring Purple ring Purple ring
the organic comond and one ml of conc.
H2SO4 was slowly added along the side of test
tube.

3 1-2 ml of Fehling solution was added to the Red ppt Negative Negative
organic compound and kept in boling water
bath.

4 1-2 ml of Benedict's solution was added to the Red ppt Negative Negative
organic compound and kept in boling water
bath.

5 1-2 ml of Tollen’s reagent was added to the A shinning Negative Negative

organic compound and kept in boling water silver mirror
bath. is formed
6 1-2 ml of Iodine solution was added to the Negative Negative Blue colour
organic compound .

Result : A = Glucose , B = Sucrose , C = Starch