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R
R
0.4 อ
=1.4 L
Ans
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Problem 2
Given that 3.50 moles of NH3 occupy 5.20 L at 47 °C, calculate the pressure of the gas (in atm) using
(a) the ideal gas equation and (b) the van der Waals equation.
Hint: To calculate the pressure of NH3 using the ideal gas equation, we proceed as
in Example 3.1. What corrections are made to the pressure and volume terms in the van der Waals equation?
(a) We have the following data: V = 5.20 L (b) a =P.
1 #
ri
T = (47 + 273.15) K = 320.15 K
n = 3.50 mol b= 0.0371
4mol
R = 0.0821 L atm/K mol
#(a) P =
P+ (#5014
R (b) / 5205 - 8.0371 = 13.50 ) ( 0.0821/
13
n 23,500 ( 32019
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