20 08 2023 JR Iit Star Co Scmodel A Wta 16 Jee Adv 2019 p1 QP Final

JR.
IIT_*CO-SC(MODEL-A) Date: 20-08-2023

Time: 3HRS Max. Marks: 186
Name of the Student: ___________________ H.T. NO:
20-08-2023_ JR.IIT. * CO-SC(MODEL-A)_JEE-ADV_ _WAT-16_SYLLABUS

PRESENT WEEK(80%):
Equation of Straight Line: General form, Slope Form, Intercept Form, Two Point Form,
Normal form, Parametric Form, Angle between two lines, Intersection of two lines, Position
of Two Points w.r.t a line, Length of perpendicular distance of a point from a line, Distance
MATHS between parallel lines, Reflection of a point w.r.t a line
PREVIOUS WEEK(20%):
2-D GEOMETRY: Introduction of Co-ordinate Geometry, Distance Formula, Section formula,
Finding various Centres with given vertices of a triangle (avoid using concepts of POT), Area of
Triangle, Collinearity of Points, Locus(Simple problems), Translation and Rotation of axes
PRESENT WEEK(80%):
Impulse, 2D collision & Variable mass systems
PHYSICS PREVIOUS WEEK(20%):
Conservation of linear Momentum & 1 D collisions (Exclude: variable mass, impulse and 2D
collision)
PRESENT WEEK(80%):
Electrolytic cell - Electrolysis of different solutions, Faraday's laws - Calculations,
conductance, specific, equivalent and molar conductivity, Kohlrausch’s law; Batteries:
CHEMISTRY Primary and Secondary, fuel cells; Corrosion (Exclude: transport number)
PREVIOUS WEEK(20%): ELECTRO CHEMISTRY:
Electrochemical work, Nernst equation; Electrochemical series, Galvanic Cells, Nernst Equation,
emf of galvanic cells; Concentration cells
TG ~ @bohring_bot
Narayana IIT Academy 20-08-2023_ JR.IIT. * CO-SC(MODEL-A)_JEE-ADV_ _WAT-16_SYLLABUS
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
MATHS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 5 – 12) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Total 18 62
PHYSICS
Sec – II (Q.N : 23 – 30) +4 -1 8 32
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62
CHEMISTRY
Sec – II (Q.N : 41 – 48) +4 -1 8 32
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62
JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 2

MATHS Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1 A point P is taken outside ABC where B 1, 3  , A(0, 0) and C(2, 0) , but inside the
 
acute angle BAC, such that APC = and BPA = . Slope of the line BP is
6 12
1 1
(A) 3 (B)  3 (C) (D)
3 3
2 The vertices of a triangle are A(m, n), B(12, 19) and C(23, 20), where m and n are
integers. If its area is 70 and the slope of the median through A is –5, then the last
digit of (m + n) is
(A) 3 (B) 5 (C)7 (D) 8
3 Let A(–1, 1), B(3, 4) and C(2, 0) be given three points. A line y = mx, m > 0,
intersects lines AC and BC at point P and Q respectively. Let A1 and A2 be the areas
of ABC and PQC respectively, such that A1 = 3A2, then the value of m is equal
to :
4
(A) 2 (B) 3 (C) (D) 1
15
4 Number of statement(s) among following statements which is/are always TRUE is
(S1) If value of common ratio is greater than 1, then G.P. is increasing
(S2) Equation of line parallel to 2x + 3y – 5 = 0 and passes through (–1, 1) is 2x +
3y = 1
(S3) x co-ordinate of circumcentre of triangle with vertices (–2, –3), (–1, 0), (7, –6)
TG ~ @bohring_bot
is 3
JR.IIT_*CO-SC Page. No. 3

(S4) Equation of line perpendicular to y = 4 – x and having x intercept 5 is x – y = 5
(A) 1 (B) 2 (C)3 (D) 4
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
answer, out of which ONE OR MORE is/ are correct.
5 A line L1 passes through a point P in first quadrant on y = x at a distance 2 from

1 
origin and point Q(even prime, 0). Another line L2 passes through  , 0 
2 
perpendicular to L1, then
(A) Slope of L1 is –1
1
(B) Initial ordinate of L2 is –
2
25
(C) Area of triangle formed by L1, L2 and x = 0 is square units.
16
25
(D) Area of triangle formed by L1, L2 and x = 0 is square units.
8
6 A particle starts from origin and moves at a constant speed of 4 units/s towards
positive
x-axis. The particle changes its direction by angle ‘’ (clockwise or anticlockwise at
random) with respect to its previous direction after every 2 seconds, then

(A) For = , particle can pass through the point (2019, 0)
2
(B) For  = , particle will trace a line segment


(C) For = , particle may lie on the line y  3x  0
3

(D) For = , after 2019 seconds, particle may lie on the line x  3y  8  0
6

7 Which of the following is/are CORRECT

(A) If the distinct points A(x, y + z), B(y, z + x) and C(z, x + y) are such that
AB = BC, then x, y, z are in A.P.
(B) If a line through the variable point A(k + 1, 2k) meets the lines 7x + y – 16 = 0,
5x – y – 8 = 0, x – 5y + 8 = 0 at B, C and D respectively, then AC, AB and AD are
in H.P.
(C) The length of the perpendiculars from the points (m2, 2m), (mn, m + n) and
sin 2 
(n2, 2n) to the line x cos + y sin  = p, where p = – , form a G.P.
cos 
(D) If the lines ax + 12y + 1 = 0, bx + 13y + 1 = 0 and cx + 14y + 1 = 0 are
concurrent then a, b, c are in G.P
x y
8 Line   1 cuts the co-ordinate axes at A(a, 0) and B(0, b) and the line
a b
x y
  1 at A'(a ', 0) and B'(0,  b') . If the points A, B, A ', B' are concyclic and
a ' b'
distinct then the orthocentre of the triangle ABA' is
 aa'   bb' 
(A) (0, 0) (B) (0, b') (C)  0, (D)  0,
 b   a 
9 Consider a triangle ABC with vertex A (2, –4). The internal bisectors of the angles
B and C are x + y = 2 and x – 3y = 6 respectively. Let the two bisectors meet at I.
(A) If (a, b) is incentre of the triangle ABC then (a + b) has the value equal to 2
(B) If (a, b) is incentre of the triangle ABC then (a + b) has the value equal to 3
(C) If (x1, y1) and (x2, y2) are the co-ordinates of the point B and C respectively, then
the value of (x1x2 + y1y2) is equal to 3
(D) If (x1, y1) and (x2, y2) are the co-ordinates of the point B and C respectively, then
the value of (x1x2 + y1y2) is equal to 8

10 Consider the points O(0, 0) A(0, 1) B(1, 1) be the xy – plane. Suppose the points
C(x, 1) and D(1, y) are chosen such that 0 < x < 1 and such that O, C, D are
collinear. Let sum of the area of the triangles OAC and BCD be denoted by “S” then
which of the following is/are correct?
1 1
(A) Minimum value of S is irrational lying in  , 
3 2
2 
(B) Minimum value of S, is irrational lying in  , 1
3 
2 
(C)The value of x, for minimum value of S lies in  , 1
3 
1 1
(D) The value of x, for minimum values of S lies is  , 
3 2
11 A rod of length 10 cm slides between two lines, x-axis & y =  3x . If locus of mid
point of rod lies on the curve ‘S’, then which of the following are INCORRECT?
(A) x-intercept of S is 10
(B) y-intercept of S is 10 3
3
(C) y-intercept of S is 10
7
(D) x-intercept of S is 10 3
12 If  = 0 represent the equation of straight line perpendicular to 5x + 2y – 17 = 0 and
passing through (1, 1), then

3
(A) x-intercept of line  = 0 is 
2
3
(B) y-intercept of line  = 0 is 
5
9
(C) Area of triangle formed by line  = 0 with co-ordinate axes is square units
20
9
(D) Area of triangle formed by line  = 0 with co-ordinate axes is square units
10

SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
13. In ABC if A(0, 0), internal angle bisector through vertex B is x + 2y – 5 = 0 and
perpendicular bisector of the side AC is 3x – y – 10 = 0 then the absolute value of slope
of line BC is
 3 
14. Let A  , a  ; a> 0, be a fixed point in the xy-plane. The image of A in y-axis be B
 a 
and the image of B in x-axis be C. If D(3 cos, a sin ) is a point in the fourth quadrant
such that the maximum area of ACD is 12 square units, then a is equal to __________.
15. A ray of light passing through the point P(2, 3) reflects on the x-axis at point A and the
reflected ray passes through the point Q(5, 4). Let R be the point that divides the line
segment AQ internally into the ratio 2 : 1. R is nearer to Q. Let the co-ordinates of the
foot of the perpendicular M from R on the internal bisector of the angle PAQ be (, ).
Then, the value of 7 + 3 is equal to ____________.
16. Consider two lines L1 x – y = 0 and L2 x + y = 0 and a moving point P(x, y). Let
d(P, Li), i = 1, 2 represents the distance of the point ‘P’ from Li. If point ‘P’ moves in
2
certain region ‘R’ in such a way  d(P, Li )  [2, 4] .
i 1
then the area of region ‘R’ is _________

17. Let the medians of a triangle meet at (5, 4) and two of its vertices are (1, 2) & (–2, 0)
then absolute difference of abscissa and ordinate of third vertex is ________
x y
18. One diagonal of a square is the portion of the line   1 intercepted between the
97 79
axes p1, p2 are the lengths of the perpendiculars from the vertices of the other diagonal
p1  p 2
on the axis y then 
5
PHYSICS Max.Marks:62
SECTION – I
19. A freight car is moving on a smooth horizontal track with no external force acting in
horizontal direction. Rain is falling with a velocity u ms 1 at an angle  with the vertical.
Rain drops are collected in the car at the rate of  kgs 1 . If initial mass of the car is
m0 and velocity v0 then
Velocity of the car as a function of time is


Rain
 t  m0 v0  t  m0 v0
A) v  u cos    B) v  u cos   
 m0  t   m0   t   m0   m0   t 
 t  m0 v0  t  m0 v0
C) v  u sin    D) v  u sin   
 m0  t   m0   t   m0   m0   t 

20. Ends of three light identical rods each of length l are connected to a light pivot that
enables them to rotate in any direction. At the other ends of the rods, three particles A,
B and C of masses m, 2m and 3m respectively are affixed. Initially, the rods are coplanar,
angle between any two adjacent rod is 1200 and the particles are at rest. Now the particle
C is given a velocity u perpendicular to the rod connected to it and in the plane of the
rods as shown in the figure. Ignore gravitational interaction between the particles. What
are moduli of acceleration vectors of the particles A, B and C immediately after the
particle C is given velocity u?
u2 3u 2 3u 2 u2 12u 2 6u 2 4u 2 6u 2 3u 2 2u 2
A) All equal to B) , and C) , and D) , and
11l 11l 22l 11l 11l 11l 11l 11l 11l 11l
21. Two identical discs of mass M are lying on a smooth horizontal surface. A small ball of
mass M strikes one of the discs, while moving along a line, making an angle   370 with
the line joining the centres of the two discs. Velocity of the ball just before collision is
1
v  10 ms 1 . Coefficient of restitution for collision between the ball and disc A is and
2
the coefficient of restitution for collision between A and B is 1. Speed of disc B after
collision is
TG ~ @bohring_bot
A) 6 ms 1 B) 3 ms 1 C) 4 ms 1 D( None
JR.IIT_*CO-SC Page. No. 9

22. A wagon of mass M can move without friction along horizontal rails. A simple
pendulum consisting of a bob of mass m is suspended from the ceiling by a string of
length l . At the initial moment, the wagon and pendulum are at rest and the string is
deflected through an angle  from the vertical. The system is released from this
position. The velocity of wagon, when the string forms an angle       with vertical
is v . The velocity of wagon (v) is
2 2
2mMgl   cos   cos   cos   2m 2 gl   cos   cos   cos  
A) v    B) v   
M m  M  m sin 2   M m  M  m sin 2  
2mMgl   cos   cos   cos   2m 2 gl   cos   cos   cos 2 

C) v    D) v   
M m  M  m sin   M m  M  m sin 2  
SECTION – II
23. Two particles A and B of masses M and 2M respectively are connected by an ideal
spring. The spring is compressed so that the potential energy stored in it is V0 . The
system is placed on a horizontal frictionless table and is given a velocity ukˆ as shown
and simultaneously the spring is released. In the subsequent motion the line from B to A
always points along the iˆ unit vector. The initial total mechanical energy is E.

M
ukˆ x
A
iˆ
ukˆ
z
kˆ
Initial
potential
energy=V0 B ukˆ
2M
Initial
velocitry
3
A) In terms of the given quantities E  V0  Mu 2
2
B) Potential energy stored in the spring when A and B have kinetic energy K A and K B is
PE  E  K A  K B
C) At some instant of time B is at point P and has a component of velocity in the x-

direction of u xiˆ . At that instant of time, in terms of the given quantities, the velocity
 
vector VA of A is VA  2u x iˆ  ukˆ
D) In subsequent motion, A and B undergo circular motion about centre of mass
24. An iron ball (A) of mass m can slide without friction on a fixed horizontal rod, which is
led through a diametric hole across the ball. There is another ball (B) of the same mass
m attached to the first ball by a thin thread of length L . Initially the balls are at rest, the
thread is horizontally stretched to its total length and coincides with the rod, as is shown
in the figure. Then the ball B is released with zero initial velocity. At the time, when the
thread is vertical
A) The force exerted by rod on ball A is 4mg.

B) Tension in the string is 5mg.
C) Speed of ball B is 2gL .

L
D) Radius of curvature of path of ball B at that moment is .
4
25. A particle projected at an angle  with the horizontal from the centre of the floor of a
cylindrical room of radius r returns to the point of projection after three elastic
collisions, first with the wall and then ceiling, again with wall. If the particle remains in
air for time T. The speed of projection
3r 4r gr gr
A) B) C) 2 D)  2
T cos  T cos  sin  sin 2
26. A particle strikes a smooth horizontal surface (surface is at rest) at an angle   0 and it
rebounds at an angle  as shown
A) If collision is perfectly inelastic, then particle will stop immediately after the
collision and  will not be defined
B) If collision is perfectly inelastic, then particle will not stop after the collision
C)    , if collision is perfectly elastic
D)   900 , if collision is perfectly inelastic

27. A ball of mass m is projected from a point P on the ground, as shown in the figure. It
was supposed to have a horizontal range R. However, it hits a fixed vertical wall
elastically at a distance l from P. Which of the following options are correct
corresponding to motion of ball till it reaches ground for first time?
R
A) The ball will return to the point P directly if l 
2
R
B) The ball will fall between point P and the wall if l 
2
R
C) The ball will fall between point P and the wall if l 
2
R
D) If l  , the ball spends more time in air after collision than before it
2
28. A large heavy sphere and a small light sphere are dropped onto a flat surface from a
height h . The radii of both spheres is much smaller than height h . The large sphere
collides with the surface with velocity v0 and immediately thereafter with the small
sphere. The spheres are dropped so that all motion is vertical before the second collision
and the small sphere hits the larger sphere at an angle  from its upper most point, as
shown in figure. If all collisions are perfectly elastic and there is no surface friction
between the spheres. Then,

A) The angle made by velocity vector of small sphere with the vertical just after the
second collision in the frame of large sphere is 
B) The angle made by velocity vector of small sphere with the vertical just after the
second collision in the frame of large sphere is 2
C) The vertical velocity of smaller sphere just after the collision with respect to ground
is v0 cos   v0
D) The vertical velocity of smaller sphere just after the collision with respect to ground
is 2v0 cos 2  v0
29. Two blocks, A and B of masses m1 and m2 respectively, are placed on a frictionless
horizontal floor. They are connected by a light cord, as shown. Block A is imparted a
velocity u towards right. During the very short time interaction when the thread is
gaining tension, it gets slightly extended and after acquiring a maximum extension, it
again goes back to relaxed state. The short period when the thread is getting stretched is
called deformation period and the period in which the thread returns to its relaxed state
is called ‘restitution period’. Let us define a number  as
Impulse of tension during restitution period
 then,
Impulse of tension during deformation period
1  m1m2  2
A) Energy absorbed by the thread during its deformation period is  u
2  m1  m2 
1  m1m2  2
B) Energy absorbed by the thread during its deformation period is  u
4  m1  m2 
m1 1   
C) Final velocity of B is u
m1  m2
m2 1   
D) Final velocity of B is u
m2  m2

30. Two point masses are connected by a light inextensible string are lying on a frictionless
surface as shown in figure. An impulse of magnitude 10kg-m/s is given to 5kg block
1
A) Velocity of 10kg block immediately after impulse is given m/s
3
B) Velocity of 10 kg block immediately after impulse is given 2 m/s
28
C) Speed of 5kg block immediately after impulse is given m/s
9
28
D) Speed of 5kg block immediately after impulse is given m/s
9
SECTION – III
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
31. Two smooth spheres are moving towards each other. Both have same radius but their
masses are 2kg and 4kg. If the velocities are 4m/s and 2m/s, respectively, and
coefficient of restitution is e=1/3. Their lines of motion are parallel to each other but
have separation equal to the radius of sphere. Maximum potential energy of
deformation (in joules) is_______J.
32. Two elastic balls of masses m1 and m2 are placed on top of each other (with a small gap
between them) and then dropped onto the ground. What is the ratio m2 / m1 , for which the
upper ball ultimately receives the largest possible fraction of the total energy in the
collision between m1 and m2 ? (Neglect air resistance and assume all collisions to be
elastic).

33. A cylinder of mass M and radius R moves with speed V through a region of space that
contains particles of mass m that are at rest. There are n of these particles per unit
volume. The cylinder moves in a direction perpendicular to its axis. Assume m  M ,
and assume that the particles do not interact with each other. If particles collide
elastically with the cylinder, the force required to move it with constant speed V
is pnmRV 2 . Find p. (Neglect collision on plane surface of cylinder)
34. A brick is thrown from ground level, at an angle  with respect to the (horizontal)
ground. Assume that the long face of the brick remains parallel to the ground at all
times, and that there is no deformation in the ground or the brick when the brick hits the
ground. If the coefficient of friction between the brick and the ground is   0.75 . What
should  be so that the brick travels the maximum total horizontal distance before
finally coming to rest? Assume that the brick doesn’t bounce. Report  in degrees.
35. A piston of mass M with a ball of mass m rests inside a fixed long vertical tube due to
frictional forces acting between the periphery of the piston and the inner surface of the
tube. The ball is raised to height h above the piston and then released. All the collisions
of the ball with the piston are perfectly elastic. Net frictional force on the piston has a
constant value F that is more than the total weight of the ball and the piston. How far
will the piston eventually move down in the tube
(in metres)? Acceleration due to gravity is g and air resistance is negligible.
[Given m=2kg, M=3kg, h=8m, F=60N, g  10ms 2 ]

36. A sphere A is of mass m and another sphere B of identical size but of mass 2m, move
towards each other with velocity iˆ  2 ˆj and iˆ  3 ˆj respectively. They collide when their
1
line of centres is parallel to iˆ  ˆj . Taking e  , the velocities of A and B after impact
2
1 1
are

 
 x1iˆ  y1 ˆj and

 
 x2iˆ  y2 ˆj respectively. Find     x1  x2  y1  y2 .

CHEMISTRY Max.Marks:62
SECTION – I
37. Given the following molar conductivities at 25°C; HCl, 426 1 cm 2 mol 1 ; NaCl,
126  1 cm 2 mol 1 ; NaC (sodium crotonate), 83 1 cm 2 mol 1 . What is the ionization
constant of crotonic acid? If the conductivity of a 0.001 M crotonic acid solution is

3.83  105 1 cm 1 ?
A) 105 B) 1.11 105 C) 1.11 104 D) 0.01

38. The specific conductance of a saturated solution of silver bromide is  Scm 1 . The
limiting ionic conductivity of Ag  and Br  ions are x and y (S cm2 mol–1), respectively.
The solubility of silver bromide in gL1 is : (molar mass of AgBr = 188)
1000  1000 188 x  y 1000
A) B) 188 C) D) 
xy xy xy  188
39. The conductivity of 0.1 N NaOH solution is 0.022 S cm1 . When equal volume of 0.1 N
HCl solution is added, the conductivity of resultant solution is decrease to 0.0055 S
cm 1 . The equivalent conductivity in S cm 2 equivalent 1 of NaCl solution is
A) 0.0055 B) 0.11 C) 110 D) 0.055

40. A current of 1.70 ampere is passed through 300 mL of 0.160 M solution of ZnSO4 for
230 sec with a current efficiency of 90%. Find the molarity of Zn 2 after the deposition
of Zn. Assume the volume of the solution remains constant during electrolysis
A) 0.154 M B) 0.244 M
C) 0.349 M D) 0.444 M

SECTION – II
41. Equal quantity of charge is passed through three electrolytic cells containing aqueous
solutions of FeSO4 , Fe2  SO4 3 and Fe  NO3 3 . Regarding the electrolytic process which
of the following is/are correct, assuming at cathode only iron ion is reduced.
A) The amount of iron deposited in three cases is equal.
B) The amount of iron deposited in Fe2  SO4 3 and Fe  NO3 3 is equal
C) Same gas is evolved at anode in all three electrolytic processes.

D) Amount of iron deposited in Fe2  SO4 3 is double to that of the iron deposited in case
of Fe  NO3 3 .
42. Which of the following statements is (are) correct w.r.t electro chemical series based
on SRP (from highest to lowest) ?
A) The reactivity of metals decreases in going down the electrochemical series
B) A metal can displace any other metal placed above it in the electrochemical series
from its salt solution.
C) The oxidizing power of the substances decrease from the top to the bottom in the
electrochemical series.
D) A redox reaction is feasible when the substance having higher reduction potential
gets reduced and the one having lower reduction potential gets oxidized.
43. In a galvanic cell, the salt bridge
A) does not participate chemically in the cell reaction.
B) stops the diffusion of ions from one electrode to another.
C) is necessary for the working of galvanic cell
D) ensures mixing of the two electrolytic solutions

44. Two litre solution of a buffer mixture containing 1.0 M – NaH 2 PO4 and 1.0 M –
Na 2 HPO4 is
placed in two compartments (one litre in each) of an electrolytic cell. The platinum
electrodes are inserted in each compartment and 1.25 A current is passed for 965 min.
Assuming electrolysis of only water at each compartment, what will be pH in each
compartment after passage of above charge? ( pK a for H 2 PO 4  = 2.15, log 7 = 0.85)
A) Anode: 3.00 B) Cathode: 3.00
C) Anode: 1.30 D) Cathode: 1.30
45. Ionic conductance at infinite dilution of Al3 and SO 24 ions are 60 and 80  1 cm 2 eq 1 ,
respectively. The correct detail(s) regarding Al2  SO 4 3 is/are
A) the molar conductance is 140  1 cm 2 mol1

B) the equivalent conductance is 140  1 cm 2 eq 1
C) the molar conductance is 840  1 cm 2 mol 1
D) the molar conductance is 23.33 1 cm 2 mol 1
46. Select the correct relations
 E   E 
A) S     nF B) S     nF
 T p  T p
 E   S   E  H  nEF
C)      D)   
 T  p  T   T p T
47. 1 litre of 1 M CuSO 4 (aq) is electrolysed by passing 0.01 faraday charge using inert
electrode. Which is/are correct about above process?
A) Intensity of blue colour changes during electrolysis
B) No change in colour intensity, if Cu-electrode is used
C)  H   108 M after electrolysis
D) During electrolysis the libereated O2 requires 28ml of CH 4 at 1 atm and 273 k for
complete reaction.

48. During electrolysis O2 gas is evolved at anode in

A) Aqueous AgNO3 with Pt-electrode
B) Aqueous NaCl (Very dilute) with Pt-electrode
C) Aqueous Na 2SO4 with Pt-electrode
D) Aqueous CuCl2 with Pt-electrode
SECTION – III
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
49. Calculate log Kc at 25°C for the disproportionation of 3 moles of aqueous HNO2 to
yield NO and NO3 ions. The E o for reduction of HNO2 to NO is 0.99 V and E o for
 RT 
reduction of NO3 to HNO2 is 0.94 V. Given 2.303   = 0.06
 F 
50. Per disulphuric acid  H 2 S 2O8  can be prepared by electrolytic oxidation of H 2 SO4 as
2 H 2 SO4  H 2 S 2O8  2 H   2e oxygen and hydrogen are by-products. In such an
electrolysis 9.72 litre of H 2 and 2.35 litre of O2 were generated at STP. What is the
weight of H 2 S2O8 formed?
51. The resistance of a solution A is 50  and that of solution B is 100  , both solutions
being taken in the same conductivity cell. If equal volumes of solution A and B are
mixed, what will be the resistance of the mixture using the same cell? Assume that there
is no increase in the degree of dissociation of A and B on mixing.
52. For the cell,
Pt Hg    Hg 2Cl2  s  KCl 1M  H  ,Q  0.1M  ,QH 2  0.001M  Pt
Ecell  0.12V at 298 K, hence, pH of cathodic compartment is
RT 
[Given: E 0Calomel, RP  0.28V, E Q|QH
0
2
 0.699V , 2.303   = 0.059]
 F 

53. A saturated solution in AgA  K sp  3  1014  and AgB  K sp  1  1014  has conductivity of
375  1010 Scm 1 . Limiting molar conductivity of Ag  and A are 60 Scm 2 mol 1 and
80Scm 2 mol 1 respectively. If the limiting molar conductivity of B is Y (in Scm 2 mol 1 ).
Y
Find out the value of ?
54
54. The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was
determined by using a conductivity cell consisting of platinized Pt electrodes. The
distance between the electrodes is 120 cm with an area of cross section of 1 cm2. The
conductance of this solution was found to be 5×10–7 S. The pH of the solution is 4. The
value of limiting molar conductivity (Λ°m) of this weak monobasic acid in aqueous
solution is Z × 102 S cm2 mol–1. The value of Z is

20 08 2023 JR Iit Star Co Scmodel A Wta 16 Jee Adv 2019 p1 QP Final

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JR.

IIT_*CO-SC(MODEL-A) Date: 20-08-2023

Name of the Student: ___________________ H.T. NO:

20-08-2023_ JR.IIT. * CO-SC(MODEL-A)_JEE-ADV_ _WAT-16_SYLLABUS

TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 2

(A) 3 (B) 5 (C)7 (D) 8

4 Number of statement(s) among following statements which is/are always TRUE is

(S1) If value of common ratio is greater than 1, then G.P. is increasing

(S2) Equation of line parallel to 2x + 3y – 5 = 0 and passes through (–1, 1) is 2x +

JR.IIT_*CO-SC Page. No. 3

(S4) Equation of line perpendicular to y = 4 – x and having x intercept 5 is x – y = 5

(A) 1 (B) 2 (C)3 (D) 4

5 A line L1 passes through a point P in first quadrant on y = x at a distance 2 from

(B) For  = , particle will trace a line segment

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 4

7 Which of the following is/are CORRECT

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 5

12 If  = 0 represent the equation of straight line perpendicular to 5x + 2y – 17 = 0 and

passing through (1, 1), then

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 6

perpendicular bisector of the side AC is 3x – y – 10 = 0 then the absolute value of slope

Then, the value of 7 + 3 is equal to ____________.

then the area of region ‘R’ is _________

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 7

then absolute difference of abscissa and ordinate of third vertex is ________

Velocity of the car as a function of time is

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 8

JR.IIT_*CO-SC Page. No. 9

is v . The velocity of wagon (v) is

2mMgl   cos   cos   cos   2m 2 gl   cos   cos   cos 2 

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 10

C) At some instant of time B is at point P and has a component of velocity in the x-

A) The force exerted by rod on ball A is 4mg.

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 11

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 12

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 13

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 14

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 15

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 16

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 17

constant of crotonic acid? If the conductivity of a 0.001 M crotonic acid solution is

A) 105 B) 1.11 105 C) 1.11 104 D) 0.01

A) 0.0055 B) 0.11 C) 110 D) 0.055

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 18

C) Same gas is evolved at anode in all three electrolytic processes.

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 19

A) the molar conductance is 140  1 cm 2 mol1

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 20

48. During electrolysis O2 gas is evolved at anode in

2 H 2 SO4  H 2 S 2O8  2 H   2e oxygen and hydrogen are by-products. In such an

Ecell  0.12V at 298 K, hence, pH of cathodic compartment is

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 21

JR.IIT_*CO-SC TG ~ @bohring_bot Page. No. 22

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