aA + bB → cC + dD

�� �� �� ��
− =− = =
� � � �
Elementary: hệ số chất là bậc của chất

Pressure and concentration:

CONSTANT VOLUME (CONST DENSITY):

Zero order:

First order:

Second order:
1. 2A->Products:

2. A+B->Products:
3.A+2B->Products:

nth-order reaction:

Half-life t1/2:

2�−1 − 1
����1/2 = ��� + (1 − �)���(��0 )
�(� − 1)
 First-order reversible reaction:

VARYING VOLUME BATCH REACTOR:

Calculating �:
aA → rR + sS
x% reactant A and (100 - x)% inerts
a × (100 − x)%
i=
x%

r+s−a
εA =
a+i
A + bB → rR
 Relationship of CA0 and CA:

Batch and flow systems of changing density T const:

Zero-order reaction:

First-order reaction:

Second-order reaction:

ARRHENIUS LAW:
 Linear form:

E: J/mol
R: 8.314 J/mol.K

Batch reactor:

for εA ≠ 0
CSTR:

PFR:
F and �0 :
Molar feed rate: F (mole/time)
Volumetric feed rate: �0 (volume/time)

Nhập liệu 2 dòng khác nhau có dòng 1 chứa CA0’, dòng 2 chứa CB0’
��0 = �0 ��0 = �'�0 = ��0 �'�0
��0 = �0 ��0 = �'�0 = ��0 �'�0
�0 = ��0 + ��0

CA0 và CB0 là initial concentration tham gia phản ứng.

RELATIONSHIP BETWEEN FR, FA, FA0:

aA → rR
Initial ��0
r
Change ��0 × �� → ��0 × ��
a
r
Final ��0 × (1 − �� ) ��0 × ��
a

So:
�� = ��0 × (1 − �� )
r
�� = ��0 × ��
a
Nếu cho cái Batch là epsilon khác 0 thì phải xài công thức varying
volume của Batch (hình như ở chương 2)