CH202 (GR) 1

Tutorial-II 26-03-2024

Name: Roll Number:

1) Determine the Mulliken symbols in BF3 and [PtCl4]2- complex.

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2) Determine the point group of these molecules

a) b) c)

d) e)

f)

3) Find the symmetries of all motions in NH3. Determine which are rotations, translations,
and vibrations. Determine which vibrations are IR and Raman active.
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Answer.

2) Determine the point group of these molecules

a) b) c)

Td D2d C3h

d) e)

Oh D3d

f)

C6h
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3) Find the symmetries of all motions in NH3. Determine which are rotations, translations,
and vibrations. Determine which vibrations are IR and Raman active.

Matrix representation of Cn(z) = Trace of Cn(z) = 2cosθ + 1

Matrix representation of Sn(z) = Trace of Sn(z) = 2cosθ - 1

Matrix representation of E = Trace of E = 3

Matrix representation of i = Trace of i = -3

Matrix representation of σxy = Trace of σxy = -3

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E 2C3 3σv
Trace 3 0 1
No. of unshifted atoms 4 1 2
atom
Гreducible 12 0 2
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