Alkali Metals

Class-1&2
 4ladt
↑ Ask so
Potassi, R
Alkali Metals
Alkalinte ->
solutions↑
↓
4x > 7.

↑
m + 10 -
most
-

↳ catches fire.
↓
Nazother metals
in
kept kerosene

I
->

Rabi sanga friendship....

Li Atomic size 4
Na I.E. t
k
Rb
Electropositivity 44
25 V

Fr - Radioactive
d guid
G5 1A
 DENSITY
-It prosity....
: <bck < Nacy-
expected order
:.>Rb>> Nas is order
expected
⑬ 3pd
↓ d
-
3p2522p
I
3d oss' tal
3
smty:..
empty
↓
Volume 4 -
St.

:.S>Rb> Na> >

eight ovocle.

:.
of alkali metal low.

Alkali metals reactive

very
:.

↳ stored in kerosene I

:.
exosome
floats
wrapped in paraffic way...A
IONIZATION ENERGY

↳
Na Size M
I.E. It
k
I
Rb
CS
V
Electron losing
tendency M
o o o o ufQuanta
Ifoutfo
.....! -e-10se

↓
↳Lotodecc
effect
I
↳esium
*

S
(S

shows maximum photo

- electric
- effect
might
Also with

highest 2. A
Energy....
lowest
 -
·
-

Tenergy loss.....

HATION ENERGY

·I energy
-

released
during
water add" to
hydration.
molecules
surface of

M.
&

H
20 -> .
20
so so
-
-

--

I
-> AH= ve
-
*
-> Exothemic

unit
of solid structure lattice

For
solubility,
segoration Lattice
energy
exergy
was -
----
---- -
>
S

:.
Degree of hydration see

conductivity
a

:.
Degree of hydration: -

t
>
↳> Nat k4> Rb+ est *

:.
conductivity:-
155>Rbt> K+ > Nat > Y *

:. Atomic Rad,In 5ro-hydrated Radi

&t> Nat> kt>RbT> est

 CONDUCTION
FLAME D-> d't electron
lost. *

↳- crimson Red ⑨ (IS

was Golden yellow a way

-
↳
violet ⑨6

Eb Red Violet

-- Blue violet A
 CHEMICAL PROPERTIES

Based on Reactivity
1. Air-Or. N2, moisture

Ais
--

↳
W I

02 N2 220

~ ↓
?."
.........
m N2 -
+

m+40-moxt." i2*
A
. Y Nz +
-4zN catches
CO2 Fre
Na
k No won V
->

Rb with is M200 3
13
I
-

Tarnist
M+02 ->
M20 ..

M. 3
(Normal I. - - - -

oxides].
↳
↳
M202- peroxide
mo? superoxide
↳ or-"2 (0.N.)

noteloew.
:

-> W920, N9202 -> Total 5

202, 10... oxides.
 witide eN3-eagagwa
Nitrate ->Nos

withte -NO2-

sulphide-2-
sulphate -
soy-

suphitoes......? I
All
:
elements
G51A toxic
->
compound
..
except, n-covalent
compound.I

small size
↓
↓ slection 105
28-
tendency
d
Fajaruse.
covalent
.
bond.
 Hydrogen 2.
2.
Halogeo
(x2) F2, Un B82:Is....
(H2] ->

↓
m x 2- Mx
Hz ->

I
+

m +
mH

↓
↓ Ionic
>
a. It F2 -F

Bidet, to from ll
155
↳> Nas > Rb> 1s ↳I

assis
exec
:my

Co..* aublee
.. F-sic
water insoluble

Insolubility
is due to...
a.
of IF
b) 1E> HE
9 19: HE
d) None.
3.
Liquid MM3

s-block alments
I
Both IA21A.
go
m+ 49. N3
- Blue colost
↳
except Be
2mg...A

Alkali metal

Mrzo
+e.
x NH3 YN13.

[m(NUsbaY ↳eiousby]
:.m
+
4qN- (MINH)-)++[e[NA3sy]
-

te +

-
Free Ammoniated
Blue C0108
*
roa
fleet
↑ solvated e-

Paramagnetic, I
Reducing Agent
 long standing,
on

2010ess
Fades
Disappears
->
Blue -

↑
Nat NH- NaN42 +

+2

4
of 19. NH3,
On con"

Blue-Bronze->colobless

⑨B

a metal
+lig. NH3

- -
-
so Con 5014
Dacute
-
-

↓
Blue colostess

· Dilute metal -
m+4q. NH3 *
 I self oxidising e-losing tendeocy
:.
Reducing, property of Gui metals: -

↳Rb> k> Na>Y-

wrong.....
:. > > Rb> k> Na..
Right order
↳ Lowest Reduction Potential in ECC/lest 0.p.

↳ now reduction
self
↳
high self oxid"s
COMPOUNDS OF G5-IA Elements
D
L de L ↓
carbonates/ suptates Nitrates
Hydroxides
Bicarbonates

solubility
stability
Basic. Nature
I order, stral

starts the lasts

↓ from
<On Rbox> KOH >
Naon>40H
 a cas
02.N2....
↑ ~ is
↳ithium -
scaverges-site
smallest element metal
of 65,

complex form
V

:-unstable
compounds
1204->420, +H20

2. 4210s -> i20 + w2

Na2003

3
Rb2W3
-> Doesnot dissonate
k> WO3
132 W3

-
Caw> caO+W2

4N03 O O +024-2
gases
-
3.

NaNOs NaNO2+024 -I
gas

3
... .. Akali metal nitrate -

gas
↳ "- 2 gases. A
 Name test - Golden yellow.
↑
Sodivon-soft in Nature

I
15225226 s
↳
Paramagnetic
..
Nat-dimagnetic....

ORES OF
NA

Li - L I
B08aX Chile Glauberts
NazB407. IOH2O Sait salt microcosmic
...

Pete s salt
f
↓ 192SO4.
NAND 3
10420
I
NaNHy HDOy.
4420

:. salt ->
kNO3
Peter
↑
...
manufacture of Na-Electrometallurgy
i tent
↳
way.
~ -..

Down’s Process

quz

winegage ing of a te
Anode: Graphite
-

cathode: -Iron inde 8

cy
Electrolyte:-Fused all-callz + KF

↓
reduce Nall
met
of
from 8150-600°
&"Eva+Hall-metallic
zog.
2. No doesn't
evaporate
metallic isn't
2.

3. Na2O2
dog formed.
doesn't corrode
metal

Rat
wall -> Nat +4
d
↓

cathode Awode
↓ ↓
Na
Uz
:Things to note:

↑Na-99.8-1 pure.
Is obtained.

in Wall used.
Impune can be *