Nghin cu tng hp v tnh cht xc tc ca zeolit ZSM-5 c t s Si/Al khc nhau trong phn ng cracking n-hexan

15/07/2008

ti do cc tc gi L Th Hoi Nam, Nguyn nh Tuyn, Nguyn Th Thanh Loan (Vin Ha hc, Vin Khoa hc v Cng ngh Vit Nam) v Trn Tun Nht (i hc Cng nghip TP.HCM) thc hin nhm tng hp zeolit ZSM-5 vi cc t s SiO2/Al2O3 khc nhau c s dng cht to cu trc v tm hiu bn cht, c ch trong phn ng cracking n-hexan trn cht xc tc ZSM-5. tin hnh thc nghim, nhm tc gi s dng cc ha cht sau: Sol Ludox, Al2SO4. 18 H2O, TPA-Br, axit Sunfuric, NaOH. Bng phng php dng cht to cu trc, zeolit ZSM-5 c nghin cu tng hp. Vic s dng cht to cu trc trong qu trnh tng hp lm gim thi gian kt tinh so vi phng php khng s dng cht to cu trc. ti tng hp c zeolit ZSM-5 c hm lng silic cao (Si/Al = 50, 60,75 v 100). Zeolit ZSM-5 tng hp c th hin hot tnh cracking rt mnh v thay i theo t s Si/Al. chuyn ha hirocacbon trn mu H-ZSM-5 tng ln lt t mu Z(50), Z(60), Z(70) v gim xung mu Z(100). Phn ng cracking n-hexan trn H-ZSM-5 cho sn phm cha nhiu olefin. iu ny chng t s can thip ca phn ng chuyn dch hydrua l rt thp v phn ng cracking phn ng ch yu theo c ch ion ccbeni