alASSMALe

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FiNAL PUNCH kET-2mo

Dafe
Page
opic compounes coi hae
Non-divechenal hence no steeo
iSomeis ieao
CHEMICAL BONDING:
Highy selulble in
inerqaniS
Seents bu inseluble io ogani
:SYNOPSIS Solvents

) Tonic Bond or Electrovalent bend Donot cencluet elechtik n solhd

stalebu in soluion hey axe
Complete transfeu of elechrens aoed Condluctas.in me Hensta
Hiqh mp BP
Fovouredd by
a) Low 1E ef Cation:
b) High negahve electron qan enthapy Covalent 1bond
c) High Laftice enetgy Jani
Mucrua Shasinq e electrens
Smal ea the onic sizeLese s
he
nteaianic distance So mose oill be arans 7ule, Explain's covalent
Laticeepeg chasacie n iomicband,
Ex Lattree
enesgy erde Smallea the size off Cation larges
LiF> LiO7 L B, LI ts Pts Polasism Poco es qpeate
TS the Covalen1 nalse
gF AgC17 B7 Ag1 L i a Nac kcr> Rbci CsC)
Mgo ao So > Bao 2 a s aes the Size ef anim areaten îs
he polasSabilil f more s covalent
GaFa Caca> Ca Cal2 Na Nak2 NaC) N a F alu
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Highes he Chaage,
more is Polas Symmei cal poly atome mo luee
a poude polasisabili a no n-polas zo because
AlE bond moment cancell each othes
A1LAiB, pIClz Ex
sn h B
M
o TonTt nala= 16(Xp-g)+3.SC- C
As A = Electonega y A
az2g M n E N

lAsElectonegelinlg differense
hehseenA 4B inceases covalet
Diatomcnceadu oith differe
-nee ele ctronegatvi s ase
nauledecreases
ele f onre naide
nalua pplas upo
ncreases.
H F H-C) HBY
D9pole mement:(u 9 D 103Dlao.T4D
AS ENdifference increas es
= ElectME chasge x benel length, di pole momeot inca eases
unit D Delbye HE
Molele coith O ase hon H2 NH3
1.9 D u184D
a Dolas moleLules
In be0zeneqeatey fhe
s)nq
Ex: Diatommnc molewes of same di pole mement, geae rs
elemen e nen-olag: esmmeny.
Ex: O2, N C , F2 e l So Ortho meta > Pasa

Tans semes
C TSo met
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Coovdnate cevalent bond
To0c
chosoctel m opel Dahve bond
Shavng of rom only one ao
ionic nale experimen
Electven donovs e i s bases
J heeo ic
Elechron acce ptoa Leis aud
ind he . of ianic nalute of
o4
Ex:
diatomic
melecle hoving dp NH+ H H-NH
bond and
leng
momen 1.98D
C24:8xlo esu
O.92 A 1D 10esucnd
Valence Bond TheoyT)
Uexp: 1-98 D
bond aial ovez tap
Aheordtcal:
u heoh cal: 2x d
.xIo o.92xo° cm bond =
sidewise ov latesal
4.u2x 1o esu.
cm
oveslap ping
E 4-42)
i s shrong ea than bonel
. ianicnaluse1.98 y(o0= 44.8-
bonels Ss. sp andl p-p ovexlap
T bonel only p-p ovelap
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efe
Poge
Hbridisahea NSEPR Thecy
one sone p
sp Gecmetry depends on No.of bend
to pP paiss lone pairs f on a
ane s 4 cetral atum
three p Reps adu J
4 Lone. lene pau Lone- bond
Sp
one s
bond
7e pulsion
poui bondpai
Ssp ones three p oned Cda
ones, threep 4 tuo d C d t HybiBornc
sa Pai Lone
par sbond
hape Ex
angle Ex:
sp4
ones threep threc O i nea co BeFa
S sp
180
Nao

HyboidhsaTo Sp3 Trigona

plano c,CeHG
V+M-C+A Gao)
2 y-shape N, s.
VValence Hel5P CC bent )
SnC
M-Monoeva end alor
d Catonit chasge
3S3 4
(4120)
Tetabedsa CH Si H4,
A anionic chaige spd 0.28 SO H
CCl4, Si4Xeo NiC
7 -s p d sp 3 1 Pysamidal NH3,PCl3,
Cio7)PM, Xeo3
Cepasatevneleo 2 V shayeH H5,
(Bet) o
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Poge
Hybridu BP LPShepes Examp P LP shape
pentngonal TS
dsp 410 Sua
plana
bipyramida

50Tnqnal Pcls Fs SpN3

bipynamidal |A AsFs
6 disterad
ockahedaa
XeF
4
1 see-sa SF, TeC
3 2 Tshape Z Bend Parametes b
Dend length
23 ear Xe Bond length & 1
atomicsize
60Octahedsal sF,?FP
Bend eoegy
spPda-5 Squae
Bone eneg
Bened length
PyYamielXeo
Greates the Elechpnegshvil
alaliderene,qreate 3 the omd
42Squane Iu poleag ihe

plan aeate is the bend

enel9y.
HE HE2 HB> HI
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As a resull of eonange
3)Band angle bond Iength become eu
depends cn Repulsiorn.

hybiclisaon
as S-Chasacte
S-chasac
s a erut fYegonane bon
In reases
bond ange moese erdes sgeing to change
inc

molecles having aesonance

bends Oe MEET
4)Band esde:
Ne. of present Tota No. of bands bla teoo atoms in
o d mS:
Bo all the structies
Bond erdes o Bond Total No ofresomahng stouchaes
Donel length en
ExD Beze ne:
A s 5 -chaaacf increRse
Bond Odes increase

N, NEN 3
Do2 =1.S

O D =O 2 Caroo roule io

delecaligallen of lene
Reserance:4
poirs r bend poirS with in molet.
pelalh n Terenange

Bo2+3 +1= =h33

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oeeasing orel es ef moleculag&
3)O ortals or
14 Ex:o
os 4o Is <2s < 2s 42P
Bo 21 S
Moledasorb heery ncreasi ng ovdu ofmolecula
fo oo
ori tes foY
4.NaNaCa,
Atomic a bitals Combihe
o pes ef eculasoroiny Is 41s2o2s 2 2 s <
less T2P2<c242=i2p,
Bonding Bmo eneag, m
Stable indi cate as
fovou benel-m Band ovdes = Ne- Na
2 Sorbitaly u
NB Ne. Bond.e oro
NA Ne f ant bonding e h
Anth bnoling r6mo) mero enesay
enelay
e stoble, molicatee a iNB 2NA2 Bond is stale
deesnot favax bono m a l ,
Bondondes oksabilhilg o Bendeneugyd
Sameorb
epet9y Saunme enth
Only
Only
amelay Can Con ne ND=NA
mdeu dloed
Bno E ABMO
NS4a
45+15 2+299
IS+2s X
2MV
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DialerdeCanfqusalien
NA Magnehre Burelcades
2 Diamagnehc
o1
H2
pasamag ncs

2 deesnot exst
1s 2 212
1S A doesnet eis
Be
r2s2s T 2 72p 4 2 Paramagmehd
KK

C2
2 diamas9nehe &

N KK s P25 2pA2 2 Diamagnee 3

2

2p 12 Paamogne
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Dete
Page C
to Calelalk Bondordu Hydsegen kendaaq:
Fick molecule-o ens
ovce
Electhstatic of attvact
coNalently bonded H-atom aon
betushan
hoving
214 ofthe melecade elechoneqahue
molal
B o - N & - N A = 1 0 -emaining C5O4N) of same ov anothey
2
H - -F.A-F
Ten melecades Total Bond orel
O=3 -H

Intelmol erulas -oending:

toe di&se-
16 1o6 =2 bend behoeen
RE
ent me leules, Ex: Hao NH,

15 =2.S
Intramole loa Roone.ng:
H- bon formed ihin
17 huo aems o5 he same melete
4)

2- 18 lo- 1 -H

o-Ditropheral
o-hydaox benpoT
d
18

Co Lg 3

No IS Lo-S=2.s
 Effechof Hboncling:

EIOC
Compounds havingH-bomd
H-oond ah
BP
mere

biikk
Hydbagon b e n d l i n g o S d u b i

moleule Can form 44

Nola:1ae
H-6ona
Isostes
Molecles oy iens ith same 0-H
n e f n d aoms
Ex
4 CN ) CH4 4NH
a) NCo
bcoN,

ddd-d