Bai’ BINH LUQNG HON HOP ACID H,SO, & H3PO. BANG PHUONG PHAP CHUAN BO BIEN THE Myc tiéu hge tip 3 = Trinh bay dugc nguyén tic chudn 46 hn hgp acid bing phép do dign thé. = Tinh duge két qua him lugng méi acid sau khi chudn 46 bing phép do dién thé. 1, Nguyén tie H,SO, la mét acid manh 6 2 nfc phn ly. Khi ding NaOH dé chudn 46, cdc phan mg xy ra nihu sau: H,S0,+NaOH —> NaHSO,+H;0 (74) ‘NaHSO« phn ly khOng hoan toan nén kh6 xéc dinh diém twong duong cia née ndy ma phan mg thung di thing qua ndc phan ly thir 2. NaHSO,+NaOH > Na;SO,+H:0 (7.2) Phan img 7.2 06 buéc nhay & pH=4 -> 10 HPO, 1a 1 acid trung binh c6 3 ndc phan ly va cdc phan tmg voi NaOH xay ra nhu sau: H;PO,+NaOH — -> NaHPO,+H20 (73) pH két thc phan tmg 7.3 tir 4,1 - 5,2 (chi thj bromocresol, helianthin, 4 methyl) NaH;PO, +NaOH —> Na:HPO,+H,0 7a) pH két thite phiin tng 7.4 tir 9,2 - 10 (chi thj phenolphtalein) NaHPO,+ NaOH -> Na;PO.+H,0 (75) Phan tng 7.5 khong c6 bude nhay trong méi trrémg HzO vi HPO,” la m6t acid rit yéu khéng thé hign tinh acid trong méi trudng nude (khé cho proton). Khi chudn 46 hén hyp H2SO; & HPO, bing dung dich chun NaOH 0,1 N. Néu diing chi th mau vi phat hign diém két thie bing mét thumg thi rt khé thdy sur chuyén mau chi thi cita timg nde 6 cd 2 acid. Hign nay, ngudi ta sit dung may do dign thé dé theo doi sy bién ddi thé (hay bién d8i pH) va ghi nhdn timg ndc phan ly cia 2 acid nay. Trong may do dign thé cia bai thyc tap nay 06 dign cye kép gdm dign eye chi thj la dign ce Thiiy tink va dign eye so sinh 1a dién cite Calomel. Sau khi thye hign, sinh vien s& vé dung dao ham bie | cia ApH/ AV (truc tung) theo V (ml) NaOH 0,1 N (tryc hoinh) 43 sir dung. Diém tuong duong durge xéc dinh bing diém cue dai ctia during dgo ham bic 1. . 2. Thude thir: Dung dich NaOH 0,1 N. Chi thj mau phenolphtalein, bromocresol. 3. Tiérhanh 3.1. Chuiin dign cyc kép khi do pH = Higu chun dign cuc theo quy trinh huéng dan sir dung kém theo may etia mOt trong cc may sir dung la may do pH tay hing sin xudt, Vi dy: WTW 525 hay Metrohm 744, 3.2. Dink lugng hin hgp acid H2S0,& HsPO, = “Trong cée ¢6 m6 50 mi, cho vio 10 ml dung dich eda hn hyp 2 acid 48 dinh lueng (dung dich A). Dé cé khudy tit vo cbc o6 md. Chinh t8e 6 khully sao cho khOng gay ra bot khi trong dung dich. = Nhiing dign eye kép vao dung dich A (phai cho clu mudi cia dign eye ngap vio dung dich). = Dé may 6 vj tri chite nang do pH. ~ Nhé NaOH 0,1 N tir buret xuéng. Ghi nhén su thay 43i pH tuong ting voi s6 ml NaOH 0,1 N nhé xudng (ting mi ml va khi gan t6i diém tuong duong gid xudng con khoang 0,1 - 0,05 ml 4 Scanned with CamScannertwong tg 1 gigt). Khi da qua diém tuong dong nhé thém 1-2 ml. Sau 46 ngimg. = Vé during cong chun 49 pH theo V (ml) hay du’mg dao ham bic 1 ApH /AV theo V (ml). = Xée dinh diém tuong duong trén dé thj theo diém uén cia durémg cong chun 4} (a) hay idm owe dai cia dung dao ham bic 1(b). pH /av von, av Hinh 7.1: Céc duimg biéu dign pH theo V(ml) (a) va dgo him ApH/ AV theo V(ml) (b) = EP): diém tuong duong thir 1; EP2: diém tuong duong thir 2 4. Tinh toan va bio céo két qua ‘Trinh bay két qua bling bang theo doi bude nhay pH va dudmg biéu dién pH theo V (ml) hay ApH / AV theo V(ml) bing Excel 2V, —Vs)*Nnow XE, . Pago, (g/t) SUVA Tmo “Eases; Byso," 49 Vy VN woe Enns 5 5 Pago, (e/1) = 202 =O N ne Faves 5 By,p04 = 327 10 Vj: thé tich NaOH trén buret nhé xudng phan img voi ton b§ H3S0, va 1/3 H3PO« Vy: thé tich NaOH trén buret nhé xudng phén tong véi toain 66 HzSOx va 2/3 HsPO« Tinh ndng 46 ciia dung dich H)SO. va dung dich HsPOs theo mol / lit va. gam / It. Ghi cha: Néu sir dung chi thj mau, quy trinh dinh lugng duge thye hign nhu sau: Trong binh én 100 ml, cho vio 10 ml dung dich cia hdn hgp 2 acid 48 dinh Iuong (dung dich A). Thém 3 giot chi thi bromocresol va nh3 NaOH 0,1 N xudng va xie din diém két thie 1 Ki chi thi chuyén tir mau vang sang mau luc, Sau dé thém tiép 3 gigt, phenolphtalein va xéc dinh diém két thie 2 khi hn hop chi thj mau chuyén tir xanh Iyc sang tim. (Cu hoi ty Ikiém tra 7 1. Acid sulfuric va acid phosphoric c6 bao nhiéu née phan ly? Cée nc nay déu cé thé dé dang xd dinh ? Tai sao ? 7 2. Néu eéch trinh bay bang ghi két qua cita thé tich 48 do theo thé thay 46i ? C6 nh xét gi khi én bude nhay thé ? : : 3. Trinh bay nhting nét khée bigt khi xée dinh diém tuong duong bing my do thé va xe dinh diém két thic bing sy 43i mau cia chi thj trong phurong phép cchudn 46 thé tich. Néu Ién cae um va khuyét diém cia 2 phuong phip ? . . 4, Néu cach chudn may do pH truéc khi sir dung ? Quy trinh chudn may pH gidng nhau cho tit ca cde thuong higu ? + Scanned with CamScanner