alasSMAte

ER 32
5
a722
Gaseous State
ectuye 6

Envichmant factoy (arabam's law)

A-h Bislightev
6-ne
Sxd containey
h YA h n M2
nfa YB P h2 h'
h h M2 AL/M22
nz h2 M h M
th =h M2
ntoYhz h2 M M2 Enrichnuad tactoy
h M2 M
hz M h hL/M
Mi/
hzn h2

Kinatic Thsory o Goses

Pastulates
A gaseouS susttm_comprises of identical hard sphaves
with thuSame mass.size Ond shape.

2 The volume
occupied bu tha qas malecules is naaliqible
J
WYt the Volunue at containe

3 Gascous maleculeS are in_ContinouS Yandom motion_collicding

with each othur and thewals f the _container thus exevting
Apressure on the ualls

4:AlL of these collisions are COmpletcly elastic thus thaYC is

ho ogs of charay due to these collisiang
Speeds-is all unils ih 9 Dote
Poge 26

5Th qos molcculo don't

interact stker at
ith cach dther at ohal).
Ihus thiy PE is o. PE-forudial Fngy-

6 Ncton's laws of Motion aic pplicable on qes malctulsard

thieffect of qrauity is nuglqDi

Molecular Yelocitics
Avg UI+ u2 tUz t--tun

mp amona all bmaletules which occurs MOSt

2
Dns 2 tat

Uav=3RT Unp2RT Uy 3 RT
JUM() MC19) MCE
14av is in m|S
R 8.314
Molk

Tk

Unp Uav Utim JU

=:L129 I.224
 Kinatic Gos Eq
o l moldculos
PV LNBym

uass olholerul
2

13PV

Total K-f. (foy n ole)=3nRT

Avg KE:lpermole)= 3 AT Not deperadent

on
type of gas)
Boltzar Constant =k
Ava KE:(pe olecule)=/RT K=1.38x10 T

3KT
*ThTs k-E is onty translatienatotien of gase

Maxwell Bltzman distnbution curve

Tconstant

Tha term dNYepresents tha fraction o molecules

Ndu
having aYelocity in thi yanqe d u to utdu.
 Um OAY 0 Page 3&

A to u
4 tDu
vclocityYangc

in any
AYca under thecurvef r a c t i o n o f maleules thatraqc
In that range

thu total
YCpresents

the
velocity
cxtrchaa
(low
vaes(low
in
AYeQ under the
c u v e
and highvvelocity rarge
and high velocity
Yonge
velocity rqngfelike
0 to u less frattiond1
ess o oletules
molecule
1attibh

iadicating VCYy
uz to e i s less
in these ranges. yangesisaxin
aYe present in tha intermediafc
molccules
I population of
ConStant,a n d
s
thi entive c u Y v e
lh total area_undey
IS cqual to u n i t y )
tYcprescntsth totalfralFion of melecules
the
Th velocity Corycspondinq to the peak o thu Graph is
hmostprobable velocity.
T2T
NO

Ata hiqhar temperature the peak oB tha amph owe

and thu aca under t e cuYVe in highur yelociby vange
IncreaseS

Th ayea undcy th Cuyve ih lower velociky range is more

Ov lower tcmp

ha aYco undty te curve in highux velocity rgngc is norc

ToYG hight tomp T

Unp (most probable) inCYeases with incrcase in Tempcerau

The totagl avea undtr t h UVe Still
Ycmaiha tu se heEL)
 el
al Sa clASSMALe
Dafe
N Page 89

by decreasinq thu moleculgy wciqht sane efcctis obscrved

aa y itKcasing the temp

ea Gases 20
A Sam pleofNeon is oriqinally 10 by_rmole in NeonoN
22
isetope and t Yermaining is Ne isotope In hOLw nan
steps oetfuston, 51: hvichment d the lighter isokope
CAn be achieved

Xog3-10. 30 loq =0.30

h nLM2
ha/w hM L3=o.u7 dog3=0.u77
lo45 =. 6I

2 loq 1 0. 845
22
20 20

3
10