Datos:

𝐿𝐿∗𝑎𝑎𝑎𝑎𝑎𝑎
𝟐𝟐𝟐𝟐𝑹𝑹𝟐𝟐 𝑻𝑻𝑻𝑻𝟐𝟐 27(0.08205 )²(305.25 K)²
Tc= 32.1°C + 273.15 K = 305.25 K 𝒂𝒂 = 𝑚𝑚𝑚𝑚𝑚𝑚∗𝐾𝐾
=
𝟔𝟔𝟔𝟔𝟔𝟔𝟔𝟔 64(48.8 atm)
𝐿𝐿∗𝑎𝑎𝑎𝑎𝑎𝑎
Pc= 48.8 atm 5.42
𝑚𝑚𝑚𝑚𝑚𝑚 2
𝑔𝑔
MC2H6 =30
𝑚𝑚𝑚𝑚𝑚𝑚
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
mx= 10 g 𝑹𝑹𝑹𝑹𝑹𝑹 �0.08205
𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾
� (305.25 K) 𝐿𝐿
𝒃𝒃 = = 0.064
𝟖𝟖𝟖𝟖𝟖𝟖 8(48.8 atm) 𝑚𝑚𝑚𝑚𝑚𝑚
V= 1.5 L

P= 7.4 atm
𝒎𝒎 10 𝑔𝑔
𝐿𝐿∗𝑎𝑎𝑎𝑎𝑎𝑎 𝒏𝒏 = = 𝑔𝑔 = 0.33 𝑚𝑚𝑚𝑚𝑚𝑚
R= 0.08205 𝑴𝑴 30
𝑚𝑚𝑚𝑚𝑚𝑚∗𝐾𝐾 𝑚𝑚𝑚𝑚𝑚𝑚

𝒏𝒏𝟐𝟐 𝒂𝒂
𝒑𝒑 + � � (𝒗𝒗 − 𝒏𝒏𝒏𝒏)
𝑽𝑽𝟐𝟐
𝑻𝑻 =
𝒏𝒏𝒏𝒏

𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
(0.33)2 𝑚𝑚𝑚𝑚𝑙𝑙2 � 5.42 �
�7.4 𝑎𝑎𝑎𝑎𝑎𝑎 + � 𝑚𝑚𝑚𝑚𝑚𝑚² �� �1.5𝐿𝐿 − (0.33 𝑚𝑚𝑚𝑚𝑚𝑚) �0.064 𝐿𝐿 ��
(1.5)²𝐿𝐿² 𝑚𝑚𝑚𝑚𝑚𝑚
=
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
0.33 𝑚𝑚𝑚𝑚𝑚𝑚 �0.08205 �
𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾

𝑎𝑎𝑎𝑎𝑎𝑎 [1.4786]
�7.4 𝑎𝑎𝑎𝑎𝑎𝑎 + 0.2671 � (7.6671 𝑎𝑎𝑎𝑎𝑎𝑎)(1.4786 𝐿𝐿)
= 𝐿𝐿 = = 𝟒𝟒𝟒𝟒𝟒𝟒. 𝟑𝟑𝟑𝟑
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
0.027 0.027
𝑘𝑘 𝑘𝑘
Datos: a)
a) 𝒂𝒂 =
𝟐𝟐𝟐𝟐𝑹𝑹𝟐𝟐 𝑻𝑻𝑻𝑻𝟐𝟐
𝟔𝟔𝟔𝟔𝟔𝟔𝟔𝟔
𝑻𝑻𝐶𝐶 = -228.7°C + 173.15 = 44.45 K
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎 2
𝑷𝑷𝐶𝐶 = 25.9 𝑎𝑎𝑎𝑎𝑎𝑎 27 �0.08205 � (44.45 𝐾𝐾)2 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
𝑎𝑎 = 𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾 = 0.2217
𝑔𝑔 64(25.9 𝑎𝑎𝑎𝑎𝑎𝑎) 𝑚𝑚𝑚𝑚𝑚𝑚²
𝑴𝑴𝑁𝑁2 = 28
𝑚𝑚𝑚𝑚𝑚𝑚

b) 𝒃𝒃 =
𝑹𝑹𝑹𝑹𝑹𝑹
𝟖𝟖𝟖𝟖𝟖𝟖
𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐿𝐿2
𝑎𝑎 = 1.39 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
𝑚𝑚𝑚𝑚𝑚𝑚² �0.08205 � (44.45 𝐾𝐾) 𝐿𝐿
𝑏𝑏 = 𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾 = 0.0178
𝐿𝐿 8(25.9 𝑎𝑎𝑎𝑎𝑎𝑎) 𝑚𝑚𝑚𝑚𝑚𝑚
𝑏𝑏 = 0.0391
𝑚𝑚𝑚𝑚𝑚𝑚

b)
𝐿𝐿
𝑽𝑽𝑽𝑽 = 𝟑𝟑𝟑𝟑 = 3 �0.0391 � = 0.1173 𝐿𝐿
𝑚𝑚𝑚𝑚𝑚𝑚

𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐿𝐿2
𝒂𝒂 1.39
𝑷𝑷𝑷𝑷 = = 𝑚𝑚𝑚𝑚𝑙𝑙2 = 33.67 𝑎𝑎𝑎𝑎𝑎𝑎
𝟑𝟑𝟑𝟑𝒄𝒄 𝟐𝟐 3(0.1173 𝐿𝐿)

𝐿𝐿
𝒃𝒃𝒃𝒃𝒃𝒃𝒃𝒃 �0.0391 𝑚𝑚𝑚𝑚𝑚𝑚� 8(33.67 𝑎𝑎𝑎𝑎𝑎𝑎)
𝑻𝑻𝑻𝑻 = = = 128.43 𝐾𝐾
𝑹𝑹 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
0.08205
𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾
Datos:
T= ?

n= 2.35 mol
𝒏𝒏𝟐𝟐 𝒂𝒂
V= 1.25 L T=�𝑷𝑷 + � (𝑽𝑽 − 𝒏𝒏𝒏𝒏) = 𝒏𝒏𝒏𝒏
𝑽𝑽²
P= 15 atm
𝐿𝐿∗𝑎𝑎𝑎𝑎𝑎𝑎
R= 0.08205
𝑚𝑚𝑚𝑚𝑚𝑚∗𝐾𝐾

𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐿𝐿²
(2.35 𝑚𝑚𝑚𝑚𝑚𝑚)2 �1.39 � 𝐿𝐿
𝑚𝑚𝑚𝑚𝑚𝑚²
�15𝑎𝑎𝑎𝑎𝑎𝑎 + � �1.25 𝐿𝐿 − (2.35 𝑚𝑚𝑚𝑚𝑚𝑚) �0.0391 �� = 𝑛𝑛𝑛𝑛𝑛𝑛
(1.25 𝐿𝐿)² 𝑚𝑚𝑚𝑚𝑚𝑚

7.676 𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐿𝐿2

�15 𝑎𝑎𝑎𝑎𝑎𝑎 � (1.25 𝐿𝐿 − 0.091885 𝐿𝐿) = 𝑛𝑛𝑛𝑛𝑛𝑛
1.5625 𝐿𝐿2

(15 atm+ 4.9126 atm) (1.158115 L) = nRT

(19.9126 𝑎𝑎𝑎𝑎𝑎𝑎)(1.58115 𝐿𝐿)

= 𝑇𝑇
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
(2.35 𝑚𝑚𝑚𝑚𝑚𝑚) �0.08205 �
𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾

𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
23.06 𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐿𝐿 ∗ 𝐾𝐾
𝑇𝑇 = 1 = 119.60
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎 𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐿𝐿
0.08205
𝐾𝐾

T= 119.60 K
 Datos: 3850 𝑐𝑐𝑚𝑚3
1 𝐿𝐿
1000 𝑐𝑐𝑚𝑚3
= 3.850 𝐿𝐿

m= 60 g de Argón 𝟐𝟐𝟐𝟐𝑹𝑹𝟐𝟐 𝑻𝑻𝒄𝒄𝟐𝟐

𝒂𝒂 =
V= 3850 cm³= 3.850 L 𝟔𝟔𝟔𝟔𝟔𝟔𝟔𝟔
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎 2
T= 23° C + 273.15 K = 296.15 K 27 �0.08205 � (151.15 𝐾𝐾 )2
𝑎𝑎 = 𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾
64(48 𝑎𝑎𝑎𝑎𝑎𝑎)
Tc= -122°C + 273.15 K = 151.15 K
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
𝑎𝑎 = 1.3474
Pc= 48 atm 𝑚𝑚𝑚𝑚𝑚𝑚 2
𝑔𝑔
𝑀𝑀𝐴𝐴𝐴𝐴 = 40
𝑚𝑚𝑚𝑚𝑚𝑚

𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
𝑹𝑹𝑹𝑹𝑹𝑹 �0.08205 𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾 � (151.15 𝐾𝐾) 𝐿𝐿
𝒃𝒃 = = = 0.03224
𝟖𝟖𝟖𝟖𝟖𝟖 8(48 𝑎𝑎𝑡𝑡𝑡𝑡) 𝑚𝑚𝑚𝑚𝑚𝑚

𝒎𝒎 60 𝑔𝑔
𝒏𝒏 = = 𝑔𝑔 = 1.5 𝑚𝑚𝑚𝑚𝑚𝑚
𝑴𝑴 40
𝑚𝑚𝑚𝑚𝑚𝑚

𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
𝒏𝒏𝒏𝒏𝒏𝒏 𝒏𝒏𝟐𝟐 𝒂𝒂 (1.5 𝑚𝑚𝑚𝑚𝑚𝑚) �0.08205 � (296.15 𝐾𝐾) (1.5 𝑚𝑚𝑚𝑚𝑚𝑚)2 �1.3474 �
𝑷𝑷 = − 𝟐𝟐 = 𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾 − 𝑚𝑚𝑚𝑚𝑚𝑚
𝑽𝑽 − 𝒏𝒏𝒏𝒏 𝑽𝑽 𝐿𝐿 (3.850 𝐿𝐿)2
3.850 𝐿𝐿(1.5 𝑚𝑚𝑚𝑚𝑚𝑚) �0.03224 �
𝑚𝑚𝑚𝑚𝑚𝑚

36.448 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎 3.03265 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎

𝑃𝑃 = − = 9.37 𝑎𝑎𝑎𝑎𝑎𝑎
3.3664 𝐿𝐿 14.8225 𝐿𝐿
 C2H6
Datos: 12(2) + 1(6) = 24 + 6 =30
𝑔𝑔
𝑚𝑚𝑚𝑚𝑚𝑚
Tc= 32.1°C + 273.15 K = 305.15 K

Pc= 48.8 atm 𝟐𝟐𝟐𝟐𝑹𝑹𝟐𝟐 𝑻𝑻𝒄𝒄𝟐𝟐

𝒂𝒂 =
𝑔𝑔 𝟔𝟔𝟔𝟔𝟔𝟔𝟔𝟔
𝑀𝑀𝐶𝐶2𝐻𝐻6 = 30
𝑚𝑚𝑚𝑚𝑚𝑚 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎 2
27 �0.08205 � (305.25 𝐾𝐾 )2 𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾
m= 10 g 𝑎𝑎 =
64(48.8 𝑎𝑎𝑎𝑎𝑎𝑎)
= 5.42
𝑚𝑚𝑚𝑚𝑚𝑚 2
V= 1.5 L

P= 7.4 atm
𝑹𝑹𝑹𝑹𝑹𝑹
𝑳𝑳∗𝒂𝒂𝒂𝒂𝒂𝒂 𝒃𝒃 =
a= 5.42 𝟖𝟖𝟖𝟖𝟖𝟖
𝒎𝒎𝒎𝒎𝒎𝒎𝟐𝟐
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
b= 0.064
𝑳𝑳 �0.08205 � (305.25 𝐾𝐾) 𝐿𝐿
𝒎𝒎𝒎𝒎𝒎𝒎 𝑏𝑏 = 𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾 = 0.064
8(48.8 𝑎𝑎𝑎𝑎𝑎𝑎) 𝑚𝑚𝑚𝑚𝑚𝑚
n= 0.33 mol

𝒎𝒎 10 𝑔𝑔
𝒏𝒏 = = 𝑔𝑔 = 0.33 𝑚𝑚𝑚𝑚𝑚𝑚
𝑴𝑴 30
𝑚𝑚𝑚𝑚𝑚𝑚

𝒏𝒏𝟐𝟐 𝒂𝒂
�𝑷𝑷+ �(𝑽𝑽−𝒏𝒏𝒏𝒏)
𝑽𝑽²
T=
𝒏𝒏𝒏𝒏

𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐿𝐿²
(0.33 𝑚𝑚𝑚𝑚𝑚𝑚)2 �5.42 �
�7.4 𝑎𝑎𝑎𝑎𝑎𝑎 + 𝑚𝑚𝑚𝑚𝑚𝑚² � �1.5 𝐿𝐿 − (0.33 𝑚𝑚𝑚𝑚𝑚𝑚) �0.064 𝐿𝐿 ��
(1.5 𝐿𝐿)² 𝑚𝑚𝑚𝑚𝑚𝑚
𝑇𝑇 =
𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
0.33𝑚𝑚𝑚𝑚𝑚𝑚 �0.08205 �
𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾

𝑎𝑎𝑎𝑎𝑎𝑎
(7.4 𝑎𝑎𝑎𝑎𝑎𝑎+ 1.4786 )(1.4786)
𝑇𝑇 = 𝐿𝐿
𝐿𝐿∗𝑎𝑎𝑎𝑎𝑎𝑎 = 414.38 𝐾𝐾
0.027
𝑘𝑘
 Datos: 51.5 𝑐𝑐𝑚𝑚3
1 𝐿𝐿
1000 𝑐𝑐𝑚𝑚3
= 0.0515 𝐿𝐿

mx= 0.180 g
V= 51.5 cm³ = 0.0515 L

T= 27° C + 273.15 K = 300.15 K

P= 760 mmHg = 1 atm

Pc= 47.7 atm

Tc= 288.5° C + 273.15 K = 561.65 K 𝒎𝒎𝒎𝒎𝒎𝒎 [𝟏𝟏 + 𝟗𝟗 (𝑷𝑷𝑷𝑷𝑷𝑷)] �𝟏𝟏 − (𝟔𝟔𝟔𝟔𝟔𝟔𝟐𝟐 )�

𝑴𝑴 = ∗ ∗
𝐿𝐿∗𝑎𝑎𝑎𝑎𝑎𝑎 𝑷𝑷𝑷𝑷 [𝟏𝟏𝟏𝟏𝟏𝟏(𝑻𝑻𝑻𝑻𝑻𝑻)] 𝑻𝑻𝟐𝟐
R= 0.08205
𝑚𝑚𝑚𝑚𝑚𝑚∗𝐾𝐾

𝐿𝐿 ∗ 𝑎𝑎𝑎𝑎𝑎𝑎
(0.180 𝑔𝑔) �0.08205 � (300.15 𝐾𝐾) [1 + 9 (1 𝑎𝑎𝑎𝑎𝑎𝑎)(561.65 𝑘𝑘)] [1 − (6)(561.65 𝐾𝐾)2 ]
𝑚𝑚𝑚𝑚𝑚𝑚 ∗ 𝐾𝐾
𝑀𝑀 = ∗ ∗
1 𝑎𝑎𝑎𝑎𝑎𝑎 (0.0515 𝐿𝐿) [128(300.15 𝐾𝐾)(47.7 𝑎𝑎𝑎𝑎𝑎𝑎)] (300.15 𝐾𝐾)2

𝑔𝑔
M = 81.23
𝑚𝑚𝑚𝑚𝑚𝑚