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TOYOTA ENGINEERING STANDARD

NO.: TSZ0001G

TITLE: Control method for substances of environmental concern

CLASS: C2
Established/Revised: Rev. 11 ( Sep. 2011 )

This standard has been revised to ensure consistency with 2011 version GADSL (Global Automotive
Declarable Substance List).

Prepared and Written by: Design Quality Innovation Div.


Quality Audit Dept. ⒸTOYOTA MOTOR CORPORATION
Material Engineering Management Div.
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CLASS
TOYOTA ENGINEERING STANDARD TSZ0001G C2
Control method for substances of environmental concern

1. Scope
This standard covers the prohibition, restriction and reduction of the use of substances of
environmental concern contained in all parts and materials (including indirect materials) used in
vehicles along with the control of usage information on such substances.

2. Terms and Definitions


2.1 Substance of Environmental Concern
(1) A substance suspected of causing detrimental effects on environmental conservation or human
health
(2) In this standard, any substances that are determined to be applicable, if incorporated in vehicles,
to (1) during use or disposal of the vehicles are shown in Tables 1 through 8.

2.2 Substance Code


A code allocated to a substance of environmental concern for identification. Substance codes in this
standard comply with CAS numbers, which are allocated by the Chemical Abstract Service
(hereinafter abbreviated as "CAS") of the American Chemical Society and are used widely around the
world. There are some substances or substance groups of unknown CAS numbers. For such
substances, Toyota numbers (T#### or M####) are allocated.

3. Substance Prohibition
The substances of environmental concern shown in Table 1 and Tables 4 to 7 shall be prohibited from
use in any vehicles for any destinations. Use of lead, mercury, cadmium and hexavalent chromium
shall however conform to exemption specified in relevant regulations.

4. Substance Restriction
The substances of environmental concern shown in Table 2 shall be prohibited from use in vehicles
depending on their uses and/or the destination of the vehicles.

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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5. Usage Information Control Rule (Substances of Environmental Concern shown in Table 3)


If any of the substances of environmental concern shown in Table 3 and applicable to Section 5.1 are
used, items shown in Section 5.3 shall be identified in units shown in Section 5.2.

5.1 Substance of Environmental Concern Subject to Control


(1) Those contained at a percentage content exceeding the threshold values shown in Table 3.
Note that the threshold values have been determined on the basis of the content of substances
of environmental concern in their "virtually homogenous material units."
(2) The "virtually homogenous material unit" of, for example, a printed wiring board containing lead
is not the board itself but solder, PZT, lead glass and other components.
Example of virtually homogenous material units
(a) Surface-treated steel sheet
Steel
Coating that is formed through surface treatment
(b) Composite material
Composite material as a whole (Individual components such as binding material, fiber
reinforcement and filler are not considered as virtually homogenous material units.)

5.2 Control Units


(1) For purchased parts, use their delivery part numbers as control units.
Usage information control by the unit of delivery part number is applicable to all component parts
(excluding TMC supply parts), materials and indirect materials (adhesives, sealers, identification
paints, etc.).
(2) TMC supply parts shall be controlled by units different from those for purchased parts.

5.3 Controlled Information


(1) Parts information
(a) Part number
(b) Part name
(c) Part mass
(2) Information related to containing portion of the part
(a) Containing portion: "virtually homogenous material unit" that contains substances of
environmental concern (See Section 5.1.) Surface treatment specification numbers shall be
identified if containing portions are the surface treatment films. (Surface Treatment
Specification Numbers)
(i) Numbers specified by Toyota Standards (TS) (Example: TSH6524G-BC)
(ii) If not specified by TS, official specification numbers, such as JIS or ISO numbers
(b) Mass of containing portion: mass of containing portion per part
(3) Information related to contained substance of environmental concern
(a) Substance code
substance code (CAS Nos. or Toyota Nos.) specified in Table 3 (controlled substances)
(b) Substance mass
mass of substance of environmental concern per "containing portion per part"
(c) Purpose of use
the purpose of using the substance of environmental concern

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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TOYOTA ENGINEERING STANDARD TSZ0001G

Table 1 Prohibited Substance


(1)
No. Substance name CAS/Toyota No. Applicable law
1332-21-4,
132207-32-0,
77536-66-4,
12172-73-5,
1 Asbestos 77536-67-5, Air Pollution Control Law
12001-29-5,
12001-28-4,
77536-68-6,
Various
2 Dioxines and Furanes Various Dioxines Special Measures Law
3 Ozone depleting substances See Table 4 Ozone Layer Protection Law
Chemical Substance Examination and
4 PCB: Porichlorinated Biphenyls
Various Regulation Law
5 PCT: Polychlorinated Terphenyl EC552/2009
Poisonous and Deleterious Substances
6 Sodium Azide 26628-22-8
Control Law
7 Lead and its compounds 2000/53/EC,
8 Cadmium and its compounds Depending on use, some are exempted from
Various
9 Mercury and its compounds prohibition.
(2)
10 Hexavalent Chromium 2010/115/EU
92-67-1,
11a 4-Aminobiphenyl and its salts, all members 1, 4
Various
92-87-5,
11b Benzidine and its salts, all members 1, 4
Various
91-59-8,
11c 2-Naphthylamine and its salts, all members 1, 4
Various
92-93-3,
11d 4-Nitrobiphenyl and its salts, all members 1, 4
Various
12 Diamino-diphenyl-methane 101-77-9 1
13 Pentachlorophenol (PCP) and its salts, all members M0027 1, 4
14 Sulfur Hexafluoride 2551-62-4 11, 12
15 Tris-(1-aziridinyl) phosphine oxide 545-55-1 4
16 Tris (2, 3-dibromopropyl) phosphate [TRIS] 126-72-7 4
17 Vinyl chloride monomer 75-01-4 1
18 Polybrominated Biphenyls M0011 4
19 Pentabromodiphenyl ether ('Penta') 32534-81-9 2, 4
20 Octabromodiphenyl ether ('Octa') 32536-52-0 2, 4
Polybrominated diphenyl ethers (excluding Decabromo
21 M0012 2, 4
Diphenylether)
(3)
22 Azo-dyes See Table 5 4
23 4, 4'-bi-o-toluidine 119-93-7 4
24 Toluene-2, 4-Diamine 95-80-7 4
25 4, 4'-Methylenebis-(2-chlorobenzenamine) 101-14-4 4
26 Chloroaniline 106-47-8 1
27 Phenol, 2-(2H-benzotriazol-2-yl)-4, 6-bis(1, 1-dimethylethyl)- 3846-71-7 2
85535-84-8,
28 Short length Chlorinated Paraffines (SCCP: C10 to 13) 4
71011-12-6
29 Perfluorooctane Sulfonates (PFOS), all members 1763-23-1 etc. 2, 4
30 Hydrofluorocarbons (HFC's), all members See Table 6 11, 12
31 Perfluorocarbons (PFC's), all members See Table 7 11, 12
32 Bis (chloromethyl) ether (BCME) 542-88-1 13
33 Chloromethyl methyl ether (CMME) 107-30-2 13
Dodecachloropentacyclo 1, 3, 4-Metheno-1H-cyclobuta (cd)
34 2385-85-5 13
pentalene, Mirex
35 Hexachlorobenzene 118-74-1 13
36 Hexachloro-1, 3-butadiene (HCBD) 87-68-3 13
37 2-Methoxyethanol 109-86-4 13
38 Pentachlorobenzene 608-93-5 13
39 Tetrachlorobenzene, all members 634-66-2 etc. 13

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 1 (Continued)
(1)
No. Substance name CAS/Toyota No. Applicable law
3194-55-6,
40 Hexabromocyclo dodecane (HBCD) 4736-49-6, 2
25637-99-4 etc.
41 Dimethyl fumarate 624-49-7 4
42 Triorganotin compounds all members, all members 56-35-9 etc. 2, 4
43 N-Nitroso dimethyl amine 62-75-9 12
44 Hexachlorocyclohexane 58-89-9 2

Notes:
(1) Refer to Attached Table 1, which shows the major examples of applicable laws.
(2) A maximum concentration value up to 0.1 mass% by weight in homogeneous materials for
lead, hexavalent chromium and mercury and up to 0.01 mass% by weight in homogeneous
material for cadmium shall be tolerated. As for the items that the expiry of the exemption is
not yet determined in 2010/115/EU, it may be determined in the future.
In addition, if the exemption provisions (ANNEX II) in the European ELV Directive are
amended, the latest exemption provisions shall be satisfied and its expiry of the exemption
shall be 1 year earlier than the date stipulated by the Directive as a rule.
(3) Azo pigment that liberates 30 ppm or more amine compounds shown in Table 5.

6. Content Examination of Substances of Environmental Concern


Examine the content of substances of environmental concern in accordance with the applicable laws.
If no examination methods are specified, determine the method through consultation between the
parties concerned.

Table 2 Restricted Substance (Prohibited from Use Depending on Use and/or Vehicle Destination)
No. Substance name CAS/Toyota No. Use restriction (applicable law)
Use prohibited in vehicles for Nordic countries and Russia
45 Methanol 67-56-1
(SFS 1985:840)
46 2,4,6-Tri-tert-butylphenol 732-26-3
47 N, N'-ditolyl-p-phenylenediamine 27417-40-9
Use prohibited in vehicles for Japan (Chemical Substance
48 N, N'-dixylyl-p-phenylenediamine 28726-30-9
Examination and Regulation Law)
49 N, N'-tolyl-N'-xylyl-p-phenylenediamine 70290-05-0
50 Polychlorinated Naphthalenes, all members M0005
For Europe, the use of arsenic as antiseptic agent for wood is
prohibited. (EC552/2009)
Other uses are prohibited in principle (excluding
51 Arsenic and its compounds, all members M0007
semiconductors, LED, lead battery and copper foil of printed
plate board. Threshold value 0.01 mass%, threshold value
for metal is 0.05 mass%)
50-32-8,
192-97-2,
56-55-3, For Europe, the use of extender oil for tires that has the
218-01-9, following threshold value or higher is prohibited.
52 Polycyclic aromatic hydrocarbons (PAH)
205-82-3, Benzo(a)pyrene 50-32-8: 1 ppm, total with other: 10 ppm
207-08-9, (EC552/2009)
53-70-3,
205-99-2
Ammonium Perchlorate, Perchlorates, all 7790-98-9, Use for new parts prohibited (excluding detonator for airbags,
53
members Various seatbelt pretensioners and coin battery)
1163-19-5 New adoption of this substance is prohibited for Japan,
54 Decabromo Diphenylether
T0217 America, Canada, Europe and China.
Use other than as fuel is prohibited.
55 Benzene 71-43-2
(EC552/2009)

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 3 Controlled Substance


Threshold Applicable
No. Substance name CAS/Toyota No. Use example (4) (1)
value law
(2)
7 Lead and its compounds M0001 Uses specified in 0.1 mass%
5
9 Mercury and its compounds M0003 2010/115/EU 0.1 mass%
45 Methanol 67-56-1 0.1 mass% 7
46 2,4,6-tri-tert-butylphenol 732-26-3 0.1 mass% 2
1,4-Benzendiamine,
47 27417-40-9 0.1 mass%
N,N'-bis(methylphenyl)-
1,4-Benzendiamine,
48 28726-30-9 0.1 mass%
N,N'-bis(dimethylphenyl)- 2
1,4-Benzendiamine,
49 70290-05-0 0.1 mass%
N-dimethylphenyl-
50 Polychlorinated Naphthalenes M0005 Uses other than those 0.1 mass%
50-32-8, restricted in Table 2
192-97-2,
120-12-7,
Benzo(a)pyrene
56-55-3,
50-32-8: 1 ppm,
52 Polycyclic aromatic hydrocarbons (PAH) 218-01-9, 1, 4
total with other:
205-82-3,
10 ppm
207-08-9,
53-70-3,
205-99-2
56 1-Chloro-2,3-epoxy-propane 106-89-8 Epoxy plastic monomer 0.1 mass% 1
Volatile component in
57 Acetaldehyde 75-07-0 0.1 mass% 1
plastic, etc.
58 Acetamide 60-35-5 Softener 0.1 mass% 1
Polyacrylamide plastic
59 Acrylamide 79-06-1 0.1 mass% 1
monomer
60 Acrylonitrile 107-13-1 Monomer of ABS plastic, etc. 0.1 mass% 1
Alkylphenol ethoxylates, all members Surfactant (windshield
61 M0019 0.1 mass% 3
Nonylphenol ethoxylates, all members washer fluid)
62 Aniline and its salts, all members M0020 Pigment 0.1 mass% 1
Flame retardant (retarding
63 Antimony and its compounds M0006 0.1 mass% 1
aid), solid lubricant
Flame retardant, solid
64 Antimonytrioxide (Diantimonytrioxide) 1309-64-4 0.1 mass% 1
lubricant
65 Aromatic amines and their salts: M0021 Impurities in natural dye 0.01 mass% 1, 4
Barium compounds (organic or water
66 M0022 Pigment, stabilizer 1 mass% 1
soluble) except Ba-carboxylate.
Beryllium and its compounds, all
67 M0008 Electrical contact 0.1 mass% 1
members
68 Biocidal coatings and additives M0023 Biocidal coating, additive 0.1 mass% 1, 4
Polybrominated
69 M0031 Flame retardant 0.1 mass% ---
Terphenyls (PBT), all members
EU risk
70 Tetrabromobisphenol A (TBBPA) 79-94-7 Flame retardant 0.1 mass%
assessment
Flame retardant made of
71 Brominated flame refardants M0012 0.1 mass% 4
synthetic resin, etc.
72 Butadiene (1,3-Butadiene) 106-99-0 Dien rubber, ABS plastic 0.1 mass% 1
0.1 mass%
M0015, Regardless of the
142844-00-6, threshold value,
Friction lining, insulation
73 Mineral Fibers (Natural or Synthetic) 329211-92-9, the substance 1
material
14464-46-1, must be
675106-31-7 controlled if it is
used intentionally
Solvent for cleaner, mildew-,
74 Chlorinated hydrocarbons: M0024 0.1 mass% 1, etc.
moss-proofing agent

Note (4): Standard for implementing control. The threshold values for metallic compounds have
been determined on the basis of the mass of individual metallic elements.

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 3 (Continued)
Threshold Applicable
No. Substance name CAS/Toyota No. Use example (4) (1)
value law
75 Chloroparaffines, unbranched (C14 to 30) M0013 Flame retardant 0.1 mass% 4
Cobalt and its compounds excluding Zinc-cobalt electro plating,
76 M0009 0.1 mass% 1
cobalt in steels alloy
8050-09-7
148499-15-4
65997-13-9 Solder, adhesive, warnish
77 Colophony (Rosin) 0.1 mass% 30
64365-17-9 and ink
65997-06-0
91081-53-7
78 Copper, metallic 7440-50-8 Friction lining 0.1 mass% ---
Dichloropropanole (1, Solvent for flame retardant,
79 96-23-1 0.1 mass% 1
3-Dichloro-2-propanole) etc.
80 Ethyl-/Methyl-Glycols and their Acetates: M0014 Solvent for wax, dye 0.1 mass% 1
81 Formaldehyde 50-00-0 Adhesive 0.1 mass% 1
82 Hexamethylene tetramine 100-97-0 Curing, foaming agent --- ---
Unreacted substance of
83 Hydrazine 302-01-2 0.1 mass% 1
plastic, pigment, etc.
84 Hydrochlorofluorocarbons (HCFC's) Various Refrigerant 0.1 mass% 6
Unreacted substance,
85 Methylacrylamidomethoxy-acetate 77402-03-0 0.1 mass% 1
by-product of plastic
Unreacted substance,
86 Monomethyldibromodiphenylmethane 99688-47-8 by-product of insulation fluid, 0.1 mass% 4
plastic
Unreacted substance,
87 Monomethyldichlorodiphenylmethane 81161-70-8 by-product of insulation fluid, 0.1 mass% 4
plastic
Unreacted substance,
88 Monomethyltetrachlorodiphenylmethane 76253-60-6 by-product of insulation fluid, 0.1 mass% 4
plastic
89 N, N-Dimethylformamide 68-12-2 Solvent for raw material 0.1 mass% 1
Welding, plating, special
90 Nickel and its compounds, all members M0010 0.1 mass% 4
metal
Additive for coolant, cutting
91 Nitrites, all members M0025 oil, curing agent for special 0.1 mass% 1
rubber
92 Nitroso amines M0026 --- --- 1
93 Diorganotin compounds M0016 Stabilizer for plastic 0.1 mass% 1
335-67-1,
PFOA and its salts, Perfluorooctanoic 3825-26-1,
94 acids C8F1502X (X = H, NH4, and Metal 335-95-5, Water repellant, etc. 0.1 mass% 14
salts), all members 2395-00-8,
335-93-3, etc.
Unreacted substance,
95 Phenol 108-95-2 deterioration product of 0.1 mass% 1
plastic
Dye, synthetic rubber
96 Phenylendiamines and its salts M0029 0.1 mass% 1, 4
material
Phthalates (excluding DBP, DEHP and
97 M0017 Plasticizer 0.1 mass% 1, 4
BBP)
98 Nitrocellulose 9004-70-0 Initiating explosive 0.1 mass% ---
Radioactive substances(including scrap
99 T0795 Discharge lamp 0.1 mass% 8
metal), all members
Unreacted substance of
100 Styrene (Vinyl benzene) monomer 100-42-5 0.1 mass% 1
plastic
Unreacted substance of
101 Styrene oxide (Epoxy styrene) 96-09-3 0.1 mass% 1
plastic
102 Thallium and its compounds M0032 Electronic parts 0.1 mass% 1
Thioperoxydicarbonicdiamide Biocidal agent, additive for
103 137-26-8 0.1 mass% 2
([(H2N)C(S)]2S2), tetramethyl- rubber
104 Tri(2-chloroethyl)phosphate 115-96-8 Flame retardant 0.1 mass% 1

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 3 (Continued)
Threshold Applicable
No. Substance name CAS/Toyota No. Use example (4) (1)
value law
Biocidal agent, antiseptic for
105 Trichlorophenol and its salts, all members M0033 0.1 mass% 1
cloth, leather
Trichloropropane
106 96-18-4 Crosslinker, solvent 0.1 mass% 1
(1,2,3-Trichloropropane)
107 Trimethylphosphate 512-56-1 Flame retardant 0.1 mass% 4
108 Triphenylphosphate 115-86-6 Flame retardant 0.1 mass% 4
109 Secondary Amines See Table 8 Anticorrosive, lubricating oil 0.1 mass% 10
Selenium and its compounds, all 7782-49-2 Semiconductor, glass
110 0.1 mass% 9
members etc. coloring-agent
Additive for vinyl chloride
111 Dibutyl phthalate (DBP) 84-74-2 0.1 mass% 4
resin, rubber
Dioctyl phthalate (Di 2-ethylhexyl Additive for vinyl chloride
112 117-81-7 0.1 mass% 4
phthalate) (DEHP) resin, rubber
Additive for vinyl chloride
113 Benzylbutylphthalate (BBP) 85-68-7 0.1 mass% 4
resin, rubber
Additive for vinyl chloride EU-R
114 Diisobutylphthatlate (DiBP) 84-69-5 0.1 mass%
resin, rubber 790/2009
115 Cyclohexane 110-82-7 Adhesive, non-woven fabric 0.1 mass% 4
116 Acetamide, N-methyl- 79-16-3 Capacitor 0.1 mass% 1
117 Acetonitrile 75-05-8 High capacity condenser 0.1 mass% 1
678-39-7,
21652-58-4,
2043-57-4,
Surface treatment of fabrics
118 Flurotelemers 507-63-1, 0.1 mass% 14
and carpets
865-86-1,
2043-54-1,
2043-53-0
119 Naphthalene 91-20-3 Insect repellent 0.1 mass% 1
Stabilizer for epoxy resin,
120 Nonylphenol 25154-52-3 0.1 mass% 1
etc.
121 Silica, Crystalline 14808-60-7 Friction material --- ---
122 Toluene 108-88-3 Adhesive, paint 0.1 mass% 1, 4
Vulcanization accelerator for
123 1, 3-Di-o-tolylguanidine, DOTG 97-39-2 0.1 mass% 4
rubber
0.1 mass%
Regardless of
the threshold
Pigment Red 251, printing
value, the
124 Pigment Red 251 74336-60-0 ink pigment, fuel additive, 1
substance must
paint, adhesive
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
Benzenamine, N-phenyl-, reaction
value, the
125 products with styrene and 2, 4, 68921-45-9 Antioxidant for rubber 15
substance must
4-trimethylpentene
be controlled if it
is used
intentionally

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 3 (Continued)
Threshold Applicable
No. Substance name CAS/Toyota No. Use example (4) (1)
value law
0.1 mass%
Regardless of
the threshold
1, 4-Benzenediamine, N, N'-mixed Ph value, the
126 68953-84-4 Elastomer, antioxidant 15
and tolylderives substance must
be controlled if it
is used
intentionally
Regardless of
the threshold
N, value, the
Vulcanization accelerator for
127 N-Dicyclohexyl-2-Benzothiazolesulphena 4979-32-2 substance must 2
rubber
mide be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
128 2-Cyclohexen-1-one, 3, 5, 5-trimethyl- 78-59-1 Paint, ink, adhesive 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
129 Cyclopentasiloxane, decamethyl- 541-02-6 Silicone material 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
130 Cyclotetrasiloxane, heptamethylphenyl- 10448-09-6 Silicone material 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
131 Cyclotetrasiloxane, octamethyl- 556-67-2 Silicone sealant 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
Decanedioic acid, bis (1, 2, 2, 6, value, the
132 41556-26-7 Light stabilizer (paint) 15
6-pentamethyl-4-piperidinyl) ester substance must
be controlled if it
is used
intentionally

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 3 (Continued)
Threshold Applicable
No. Substance name CAS/Toyota No. Use example (4) (1)
value law
0.1 mass%
Regardless of
the threshold
value, the
133 2-(2-methoxyethoxy) ethanol 111-77-3 Brake fluid, ink 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
Internal mold release agent value, the
134 Fatty acids, C6-19-branched, zincsalts 68551-44-0 15
(rubber, etc.) substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
135 2-Furancarboxaldehyde 98-01-1 Fran resin material, others 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
Hexanedioic acid, 1, 6-bis (2-ethylhexyl) value, the
136 103-23-1 Plasticizer (PVC, rubber) 15
ester substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
Vinyl chloride stabilizer, drier value, the
137 Hexanoic acid, 2-ethyl- 149-57-5 15
for paint and ink substance must
be controlled if it
is used
intentionally
138 N-Methylpyrrolidone 872-50-4 Paint, ink, leather 0.1 mass% EC790/2009
0.1 mass%
Regardless of
the threshold
value, the
139 Pigment Red 3 2425-85-6 Pigment (paint, ink) 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
7-oxa-3, 20-diazadispiro
value, the
140 [5.1.11.2]-heneicosan-21-one, 2, 2, 4, 64338-16-5 Light stabilizer (paint, resin) 15
substance must
4-tetramethyl-
be controlled if it
is used
intentionally

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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TOYOTA ENGINEERING STANDARD TSZ0001G

Table 3 (Continued)
Threshold Applicable
No. Substance name CAS/Toyota No. Use example (4) (1)
value law
Regardless of
the threshold
Phenol, value, the
141 2-(5-chloro-2H-benzotriazol-2-yl)-4, 6-bis 3864-99-1 Ultraviolet absorber (resin) substance must 2
(1, 1'-dimethylethyl)- be controlled if it
is used
intentionally
0.1 mass%
Regardless of
Phosphonium, triphenyl (phenylmethyl)-, the threshold
Polymerization accelerator
salt with 4, 4'-[2, 2, value, the
142 75768-65-9 for epoxy resin, powdered 15
2-trifluoro-1-(trifluoromethyl) ethylidene] substance must
paint hardening accelerator
bis [phenol] (1:1) be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
143 Phosphoric acid tributylester 126-73-8 Paint, plasticizer 1, 15
substance must
be controlled if it
is used
intentionally
Phosphoric acid, tris (2-methylphenyl)
144 78-30-8 Plasticizer, lubricant additive 0.1 mass% 1
ester
0.1 mass%
Regardless of
the threshold
value, the
145 1-Propanol, 2-methoxy- 1589-47-5 LLC antifreeze 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
146 2-Pyrrolidinone, 1-ethenyl- 88-12-0 Water base paint, adhesive 15
substance must
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
Silanamine, 1, 1, the threshold
1-trimethyl-N-(trimethylsilyl)-, reaction value, the
147 68937-51-9 Silicone rubber 15
products with ammonia, substance must
octamethylcyclotetrasiloxane and silica be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
Siloxanes and Silicones, di-Me, value, the
148 70900-21-9 Silicone resin 15
hydrogen-terminated substance must
be controlled if it
is used
intentionally

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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TOYOTA ENGINEERING STANDARD TSZ0001G

Table 3 (Continued)
Threshold Applicable
No. Substance name CAS/Toyota No. Use example (4) (1)
value law
0.1 mass%
Regardless of
the threshold
Siloxanes and Silicones, Me 3, 3,
value, the
149 3-trifluoropropyl, Me vinyl, 68952-02-3 Fluorosilicone rubber 15
substance must
hydroxy-terminated
be controlled if it
is used
intentionally
0.1 mass%
Regardless of
the threshold
value, the
150 Vanadium (V) oxide 1314-62-1 Catalyst, paint 15
substance must
be controlled if it
is used
intentionally

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
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Table 4 Ozone-Depleting Substance


No. Substance name CAS No.
1 CFC11 (Trichlorofluoromethane) 75-69-4
2 CFC12 (Dichlorodifluoromethane) 75-71-8
3 CFC113 (1,1,2-Trichloro-1,2,2-trifluoroethane) 76-13-1
4 CFC113a (1,1,1-Trichlorotrifluoroethane) 354-58-5
5 CFC114 (1,1-Dichloro-1,2,2,2-tetrafluoroethane) 374-07-2
6 CFC114 (1,2-Dichloro-1,1,2,2-tetrafluoroethane) 76-14-2
7 CFC115 (Chloropentafluoroethane) 76-15-3
8 Halon1211 (Difluorochlorobromomethane) 353-59-3
9 Halon1301 (Trifluorobromomethane) 75-63-8
10 Halon2402 (1,2-Dibromo-1,1,2,2-tetrafluoroethane) 124-73-2
11 CFC13 (Chlorotrifluoromethane) 75-72-9
12 CFC111 (Pentachlorofluoroethane) 354-56-3
13 CFC112 (1,1,1,2-Tetrachlorodifluoroethane) 76-11-9
14 CFC112 (1,1,2,2-Tetrachloro-1,2-difluoroethane) 76-12-0
15 CFC112 (Tetrachlorodifluoroethane) 28605-74-5
16 CFC211 (Heptachlorofluoropropane) ---
17 CFC212 (Hexachlorodifluoropropane) 661-96-1
18 CFC213 (Pentachlorotrifluoropropane) 1652-89-7
19 CFC214 (1,1,1,3-Tetrachloro-2,2,3,3-tetrafluoropropane) 2268-46-4
20 CFC215 (1,1,3-Trichloro-1,2,2,3,3-pentafluoropropane) 1652-81-9
21 CFC215 (Trichloropentafluoropropane) ---
22 CFC216 (1,2-Dichloro-1,1,2,3,3,3-hexafluoropropane) 661-97-2
23 CFC217 (Chloroheptafluoropropane) 422-86-6
24 Carbon tetrachloride 56-23-5
25 1,1,1-Trichloroethane 71-55-6
26 HCFC21 (Dichlorofluoromethane) 75-43-4
27 HCFC22 (Chlorodifluoromethane) 75-45-6
28 HCFC31 (Chlorofluoromethane) 593-70-4
29 HCFC121 (1,1,2,2-Tetrachloro-1-fluoroethane) 354-14-3
30 HCFC121 (Tetrachlorofluoroethane) ---
31 HCFC121a (1,1,1,2-Tetrachloro-2-fluoroethane) 354-11-0
32 HCFC122 (Trichlorodifluoroethane) 354-21-2
33 HCFC123 (2,2-Dichloro1,1,1-trifluoroethane) 306-83-2
34 HCFC124 (2-Chloro-1,1,1,2-tetrafluoroethane) 2837-89-0
35 HCFC131 (Trichlorofluoroethane) 359-28-4
36 HCFC132 (Dichlorodifluoroethane) 431-06-1
37 HCFC132b (1,2-Dichloro1,1-difluoroethane) 1649-08-7
38 HCFC133 (1-Chloro-1,2,2-trifluoroethane) 431-07-2
39 HCFC133a (2-Chloro-1,1,1-trifluoroethane) 75-88-7
40 HCFC141 (1,2-Dichloro-1-fluoroethane) 430-57-9
41 HCFC141b (1,1-Dichloro-1-fluoroethane) 1717-00-6
42 HCFC142 (Chlorodifluoroethane) 25497-29-4

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 4 (Continued)
No. Substance name CAS No.
43 HCFC142b (1,1,1-Chlorodifluoroethane) 75-68-3
44 HCFC151 (Chlorofluoroethane) 1615-75-4
45 HCFC221 (Hexachlorofluoropropane) 422-40-2
46 HCFC222 (Pentachlorodifluoropropane) 422-49-1
47 HCFC223 (Tetrachlorotrifluoropropane) 431-81-2
48 HCFC224 (Trichlorotetrafluoropropane) 422-54-8
49 HCFC225 (Dichloropentafluoropropane) ---
50 HCFC225aa (2,2-Dichloro-1,1,1,3,3-pentafluoropropane) 128903-21-9
51 HCFC225ba (2,3-Dichloro-1,1,1,2,3-pentafluoropropane) 422-48-0
52 HCFC225bb (1,2-Dichloro-1,1,2,3,3-pentafluoropropane) 422-44-6
53 HCFC225ca (3,3-Dichloro-1,1,1,2,2-pentafluoropropane) 422-56-0
54 HCFC225cb (1,3-Dichloro-1,1,2,2,3-pentafluoropropane) 507-55-1
55 HCFC225cc (1,1-Dichloro-1,2,2,3,3-pentafluoropropane) 13474-88-9
56 HCFC225da (1,2-Dichloro-1,1,3,3,3-pentafluoropropane) 431-86-7
57 HCFC225ea (1,3-Dichloro-1,1,2,3,3-pentafluoropropane) 136013-79-1
58 HCFC225eb (1,1-Dichloro-1,2,3,3,3-pentafluoropropane) 111512-56-2
59 HCFC226 (Chlorohexafluoropropane) 422-57-1
60 HCFC231 (Pentachlorofluoropropane) 421-94-3
61 HCFC232 (Tetrachlorodifluoropropane) 460-89-9
62 HCFC233 (Trichlorotrifluoropropane) 421-99-8
63 HCFC234 (Dichlorotetrafluoropropane) 127564-83-4
64 HCFC235 (Chloropentafluoropropane) 422-02-6
65 HCFC241 (Tetrachlorofluoropropane) 666-27-3
66 HCFC242 (Trichlorodifluoropropane) 1112-13-6
67 HCFC243 (Dichlorotrifluoropropane) 134237-43-7
68 HCFC244 (Chlorotetrafluoropropane) 421-75-0
69 HCFC251 (Trichlorofluoropropane) 818-99-5
70 HCFC252 (Dichlorodifluoropropane) 134190-52-6
71 HCFC253 (Chlorotrifluoropropane) 421-47-6
72 HCFC253fb (3-Chloro-1,1,1-trifluoropropane) 460-35-5
73 HCFC261 (Dichlorofluoropropane) 420-97-3
74 HCFC262 (Chlorodifluoropropane) 420-99-5
75 HCFC271 (Chlorofluoropropane) 420-44-0
76 Dibromodifluoroethane 75-82-1
77 Dibromodifluoropropane 460-25-3
78 Tetrabromodifluoropropane ---
79 Dibromotrifluoropropane 70192-83-5
80 Dibromofluoroethane 358-97-4
81 Dibromofluoropropane 51584-26-0
82 Dibromofluoromethane 1868-53-7
83 Dibromopentafluoropropane 431-78-7
84 Tetrabromotrifluoropropane ---

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 4 (Continued)
No. Substance name CAS No.
85 Tetrabromofluoropropane ---
86 Tetrabromofluoroethane 306-80-9
87 Tribromodifluoroethane ---
88 Tribromodifluoropropane 70192-80-2
89 Tribromotetrafluoropropane
90 Tribromotrifluoropropane
91 Tribromofluoroethane ---
92 Bromodifluoroethane
93 Bromodifluoropropane
94 Bromodifloromethane 1511-62-2
95 Bromotetrafluoroethane 124-72-1
96 Bromotetrafluoropropane 679-84-5
97 Bromotrifluoropropane 421-46-5
98 Bromofluoroethane 762-49-2
99 Bromofluoropropane 352-91-0
100 Bromofluoromethane 373-52-4
101 Bromohexafloropropane 2252-79-1
102 Bromopentafluoropropane 460-88-8
103 Pentabromodifluoropropane
104 Pentabromofluoropropane ---
105 Dibromotetrafluoropropane
106 Tribromofluoropropane 75372-14-4
107 Hexabromofluoropropane ---
108 Halon2302 (Dibromotrifluoroethane) 354-04-1
109 2-Bromo-1,1,1-trifluoroethane 421-06-7
110 Bromotrifluoroethane ---
111 Methyl Bromide 74-83-9
112 Chlorobromomethane (Halon1011) 74-97-5
113 Dibromodifluoroethane (Halon 1202) 75-61-6

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 5 Regulated Amino Substances


No. Substance name CAS No.
1 Biphenyl-4-ylamine, 4-Aminobiphenyl, Xenylamine 92-67-1
2 Benzidine 92-87-5
3 4-Chloro-o-toluidine 95-69-2
4 2-Naphthylamine 91-59-8
o-Aminoazotoluene, 4-Amino-2',3-dimethylazobenzene,
5 97-56-3
4-o-Tolylazo-o-toluidine
6 5-Nitro-o-toluidine 99-55-8
7 4-Chloroaniline 106-47-8
8 4-Methoxy-m-phenylenediamine 615-05-4
9 4,4'-Methylenedianiline, 4,4'-Diaminodiphenylmethane 101-77-9
10 3,3'-Dichlorobenzidine, 3,3'-Dichlorobiphenyl-4,4'-ylenediamine 91-94-1
11 3,3'-Dimethoxybenzidine, o-Dianisidine 119-90-4
12 3,3'-Dimethylbenzidine, 4,4'-Bi-o-toluidine 119-93-7
13 4,4'-Methylenedi-o-toluidine 838-88-0
14 6-Methoxy-m-toluidine, p-Cresidine 120-71-8
4,4'-Methylene-bis-(2-chloro-aniline),
15 101-14-4
2,2'-Dichloro-4,4'-methylene-dianiline
16 4,4'-Oxydianiline 101-80-4
17 4,4'-Thiodianiline 139-65-1
18 o-Toluidine, 2-Aminotoluene 95-53-4
19 4-Methyl-m-phenylenediamine 95-80-7
20 2,4,5-Trimethylaniline 137-17-7
21 o-Anisidine, 2-methoxyaniline 90-04-0
22 4-Aminoazobenzene 60-09-3

Table 6 HFC's
No. Substance name CAS No.
1 Trifluoromethane 75-46-7
2 Difluoromethane 75-10-5
3 Fluoromethane 593-53-3
4 Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro 138495-42-8
5 1,1,1,2,2-Pentafluoroethane 354-33-6
6 Difluoroethane 75-37-6
7 1,1,2-Trifluoroethane 430-66-0
8 1,1,1-Trifluoroethane 420-46-2
9 1,1,1,2,3,3,3-Heptafluoropropane 431-89-0
10 1,1,1,2,2,3-Hexafluoropropane 677-56-5
11 1,1,1,2,3,3-Hexafluoropropane 431-63-0
12 1,1,1,3,3,3-Hexafluoropropane 690-39-1
13 1,1,2,2,3-Pentafluoropropane 507-55-1
14 1,1,1,3,3-Pentafluoropropane 460-73-1
15 1,1,1,3,3-Pentafluorobutane 406-58-6

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
in whole nor in part to ant third party without prior written consent of Toyota Motor Corporation..
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Table 7 PFC's
No. Substance name CAS No.
1 Perfluoromethane 75-73-0
2 Perfluoroethane 76-16-4
3 Perfluoropropane 76-19-7
4 Perfluorobutane 355-25-9
5 Perfluoropentane 678-26-2
6 Perfluorohexane 355-42-0
7 Perfluorocyclobutane 115-25-3

Table 8 Secondary Amines


No. Substance name CAS No.
1 N,N-Diethanolamin 111-42-2
2 N,N-Diethylamin 109-89-7
3 N,N-Di-i-propylamin 108-18-9
4 N,N-Dimethylamin 124-40-3
5 N,N-Di-n-propylamin 142-84-7
6 N,N-Di-n-butylamin 111-92-2
7 N,N-Ethylphenylamin 103-69-5
8 N,N-Methylethylamin 624-78-2
9 N-Methyl-N-phenylamin 100-61-8
10 Morpholin 110-91-8
11 Piperidin 110-89-4
12 Pyrrolidin 123-75-1

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
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Attached Table 1 Applicable Law

No. Law
1 EC1272/2008, EC790/2009
2 Chemical Substance Examination and Regulation Law
3 EU-D 2003/53/EC
4 EC552/2009
5 EU-D 2000/53/EEC
6 EC Regulation 2037/2000
7 SFS 1985:840; SFS 1986:8
8 Strahlenschutzverordnung (StrSchV)
9 Wastes Disposal and Public Cleaning Law
10 German TRGS 615.
11 Danish Statutory Order no. 552
12 EU-R 842/2006/EC
Prohibition of Certain Toxic Substances Regulations, 2005 (SOR/SOR/2005-41.
13
Published in Canada Gazette Part II, 2006-11-29 Vol.140, No.25)
14 EPA Voluntary Stewardship Program
15 CEPA1999

NOTES: The recipient of this standard shall undertake the following confidentiality obligations upon the receipt of this standard.
- The recipient shall discard by shredding or fire, or return to Toyota Motor Corporation if appropriate, the documents contained in this standard when they Rev. 11
are no longer necessary due to the termination of the work concerned or the revision of current version of this standard,
- This standard and the technical information related thereto are owned by and under sole control of Toyota Motor Corporation. They shall not be disclosed
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