CONCEPT 1

SERIES 3 +
CONCEPTS 7 .. 55 1
:

A B C D E 5 15 34 53 88

A
B
C
D
E

SERIES 3 +

CONCEPT 2

CONCEPTS 7 .. 56 1
:

. N-14 2 Li-7

. Be-9 2 He-4

. N-15 7 H-2

. Ga-31 3 B-10

SERIES 3 +

CONCEPT 3

CONCEPTS 7 .. 56 2
:

3.1
2 18 32 36 86
1)

2)

3.2

1) 5

2) EN 4

3) 5p-orbital 1

4) 4

SERIES 3 +

CONCEPT 4

CONCEPTS 7 .. 55 3
:

4.1
31
( )

4.2


1) [Ar] 4s2 3d10 4p6 5d1

2) [Ar] 4s2 3d10 4p5 5s2 5p1

3) [Ar] 4s2 3d10 4p5 5s2 4d3 5d2

4) [Ar] 4s2 3d10 4p6 5s1

SERIES 3 +

CONCEPT 5

CONCEPTS 7 .. 55 2
:

5.1

1) O2- 140 pm , N3- 171 pm , Se2- 198 pm

S2-

2) Sr2+ 127 pm , Cs+ 165 pm Ba2+

3) Na+ , K+ , Mg2+ , Ca2+

4) S2- , Se2- , Cl- , Br-

5.2
31 34 37 52
1) 4

2) 4

CONCEPT 6

SERIES 3 +
CONCEPTS 7 .. 56 3
: IE

W X Y Z (MJ/mol)
L K

IE1

IE2

IE3

IE4

IE5

IE6

IE7

0.53

7.31

11.8

1.41

2.86

4.59

7.48

9.45

53.3

0.81

2.43

3.67

25.0

32.8

1.32

3.40

5.31

7.48

12.0

13.3

71.3

1) W Z
2) X Y
3) Y Z
4) X Z
5) W X
6) W X Y Z

SERIES 3 +

CONCEPT 7

CONCEPTS 7 .. 55 4
:

7.1
MgCl2 , MgF2 Na2O
1)
2)

7.2

1) NaOH Mg(OH)2 Al(OH)3

2) KCl (aq) 0.1 M KCl (l)

7.3

1) 4 A B 2 B A
2) 6 C D 4 D C

CONCEPT 8

SERIES 3 +
CONCEPTS 7 .. 56 6
:

8.1

1) BaCl2 + Na2SO4
2) Na2S + Pb(NO3)2

3) K2CO3 + CaCl2

4) AgNO3 + MgCl2

8.2
Ag+ Na+ Ba2+

NaCl , Na2CO3 , NaOH , HCl H2SO4

CONCEPT 9

SERIES 3 +
CONCEPTS 7 .. 55 5
:

9.1

N3

BH3

NH4+

CO32-

SF4

1)

2)

3)

4)

5)

6)

9.2
6

XeO4

NO3

CONCEPT 10

SERIES 3 +
CONCEPTS 7 .. 56 4
:

10.1

1)

H
O
H a
O

2)

N d H
H H

10.2

1) BCl3 NCl3 CH4

2) H2S NH3 H2O

3) SF6 CS2 NO3-

4) ClO4- PH3 PCl3

10.3

BF3
NCl3
PH3

NH4+

H3O+

I3

1)
2)

H2CO

CO2

CONCEPT 11

SERIES 3 +
CONCEPTS 7 .. 56 5
:

(kJ/mol)
. H2(g) 2H(g)
H = 436 kJ
. 2Cl(g) Cl2(g)
H = 242 kJ
. H2(g) + Cl2(g) 2HCl(g)
. CH4(g) C(g) + 4H(g)

= 182 kJ
H = 1652 kJ

. C(g) + 2HCl(g) CH2Cl2(g)

= -618 kJ

1) H-Cl kJ/mol
2) C-H kJ/mol
3) C-Cl kJ/mol

4) Cl2
C4H10(g) + Cl2(g) C4H9Cl(g) + HCl(g)

= ? kJ/mol

5) CH4 + 2Cl2 CH2Cl2 + 2HCl

SERIES 3 +

CONCEPT 12

CONCEPTS 7 .. 55 6
:

W X Y Z 8 11 17 20
1)
2)
3)

4) 4

5) 4

SERIES 3 +

CONCEPT 13

CONCEPTS 7 .. 55 7
:

1)
2)
3) IE3
4)
5)

6) Diatomic molecule
7) 3

8) IE1 2, 3, 5 6 2-3

CONCEPT 14

SERIES 3 +
CONCEPTS 7 .. 55 8
:

14.1
-

14.2

7A
14B
19C
25D
32E

37F

54G

82H

CONCEPT 15

SERIES 3 +
CONCEPTS 7 .. 56 7
:

3 A B C

Cl2/C6H14 , Br2/C6H14 I2/C6H14

Cl2/C6H14
I2/C6H14
Br2/C6H14
A

1) Cl2 A
2) B I2/CCl4
3) AgNO3
4) B C

SERIES 3 +

CONCEPT 16

CONCEPTS 7 .. 55 9
:

16.1

1) block
2) 1

16.2
d-orbital
1) d-orbital xyz

2) d-orbital xyz

16.3
d-orbital
1) 4

2) 6

CONCEPT 17

SERIES 3 +
CONCEPTS 7 .. 56 8
:

17.1

CO32-

NO3-

ClO4-

PO43-

CrO42-

CN-

NO2-

ClO3-

PO33-

Cr2O72-

SCN-

OCN-

ClO2-

MnO4-

MnO42-

CO

NH3

ClO-

Mn2O3

MnO2

SO42-

SO32-

S2O82-

S2O32-

S4O62-

17.2

[Cu(NH3)4(H2O)2](NO3)2
[Ag(NH3)2][Ag(CN)2]
KNa[NiCl4]
[Fe(NH3)6][Cr(CN)6]
[Co(SO4)(NH3)5]Br

Fe = Cr =

SERIES 3 +
CONCEPTS 7 .. 55 10
:

18.1

1)
2)
3)

4)

5)

6)

7)

8)

18.2

1)

2)

3)

5)

+ .........

6)

+ .........

7)

8)

+ ..

.. +

4)

+ ..

+ ..

+ ..
......... +

CONCEPT 18

SERIES 3 +

CONCEPT 19

CONCEPTS 7 .. 55 11
:

Po-218 Po-218 32.4 g 549

Po-218 4.05 g
1) Po-218

2)

3) 366

4) Po-218 10.8

SERIES 3 +

CONCEPT 20

CONCEPTS 7 .. 56 9
:

20.1
Q 15 mg
Q 0.800 g 1
4
1) Q 1 31
()

2) 2 1 .. 56

20.2
Pd-103 17
Pd-103 5.00 Pd-103
150 mg
1)

2) 4

SERIES 3 +

CONCEPT 21

CONCEPTS 7 .. 55 12
:

21.1
5.0% 1 3.4
1.02 g/cm3
1.05 g/cm3
1)

2)

21.2
1.0 M 500 cm3 60%
60%w 1.47 g/cm3
1.84 g/cm3
1) 60%w

2) :

SERIES 3 +

CONCEPT 22

CONCEPTS 7 .. 56 11
:

22.1
MgSO4 2.40 MgCl2 0.1 mol/dm3 200 cm3
500 cm3
1) Mg2+ mol/dm3

2) SO42- : Cl-

22.1
CuSO4 0.50 mol/dm3 100 cm3 CuCl2
500 cm3 Cu2+ 0.90 mol/dm3
1) CuCl2 (Cl = 35.5, Cu = 64)

2) Cl- : SO42- ()

SERIES 3 +
CONCEPTS 7 .. 55 19
:

1) 0.5 500 g

2) 40% 250 cm3

3) 50%

4) 0.2 2 (K = 39 , Mn = 55)

CONCEPT 23

CONCEPT 24

SERIES 3 +
CONCEPTS 7 .. 55 13
:

CH3OH

-98oC

68oC

15% w

C6H12O6

148oC

15% w

C3H8O3

18oC

290oC

15% w

1) 3 mol/kg

2)

3)

SERIES 3 +

CONCEPT 25

CONCEPTS 7 .. 56 13
:

6.5 oC (C10H8) 6.40 50.0

-0.4 oC A 3.80
-5.0 oC
1) molality

2)

3) : A 6.5 oC
-0.4 oC -5 oC

4) A A

CONCEPT 26

SERIES 3 +
CONCEPTS 7 .. 55 15
:

26.1
STP

1)
NO2
2.3 g
2)

CO

3)

Cl2

4)

SO2

5.6 dm3
1.81022
12.8 g

26.2
6.021023 2 atm, 27 oC Cl2O
17.4

SERIES 3 +

CONCEPT 27

CONCEPTS 7 .. 56 10
:

27.1
Q
.
. HCl HNO3
. Q 4.00
6.00
. .
5.00
. . 4.00
. Q +2

1) . QxSy x : y
2) . QmOn m : n
3) .
4) S = 32 O =16 Q
5) Q .

27.2
3 E F G 3
2 : 1 , 8 : 1 3 : 2 GO2
E : F : G 3 : 8 : 6 3 2

SERIES 3 +

CONCEPT 28

CONCEPTS 7 .. 56 14
:

28.1
BaCl2 nKCl5H2O
4/5 n

28.2
CuSO45H2O MgSO4
19.6 180 oC 40
16.0
1)

2) MgSO4 ()

SERIES 3 +

CONCEPT 29

CONCEPTS 7 .. 55 14
:

29.1

HOCOC6H4COOH + 2CH3OH H3COCOC6H4COOCH3 + 2 H2O
500 g 80% 200 g
388 g
1)

2)

3)

29.2

2C6H5NO2 + 4C6H14O4 C12H10N2 + 4C6H12O4 + 4H2O
(C12H10N2) 246.0
400

SERIES 3 +

CONCEPT 30

CONCEPTS 7 .. 55 14
:

(NH3) 51.0 g (NH2Cl) 103.0 g (N2H4)

60
1)

2)
3)

4)

SERIES 3 +

CONCEPT 31

CONCEPTS 7 .. 56 15
:

31.1
SO2 Ca(OH)2 ()
Ca(OH)2(s) + SO2(g) CaSO3(s) + H2O(l)
CaSO3(s) + O2(g) + H2O(l) CaSO42H2O(s)
SO2 3.75% 32 oC 760 mmHg
( RT 25.0 atmL/mol)
1) Ca(OH)2 1

2) CaSO4 1

31.2
CO2 (LiOH) CO2 Li2CO3
1 m3 CO2 1%
27oC 760 mmHg ( R = 0.08)

SERIES 3 +

CONCEPT 32

CONCEPTS 7 .. 55 20
:

32.1
10
60

O2(g) + CS2(l) CO2(g) + SO2(g)

32.2
CH3OH(aq) + HCl(g) CH3Cl(g) + H2O(g)
HCl 1.12 m3 8 dm3
STP 0.56 m3 CH3Cl H2O
HCl 0.8 g/cm3
1)

2)

3)

4) HCl

SERIES 3 +

CONCEPT 33

CONCEPTS 7 .. 56 16
:

33.1

1 0.8 g/cm3

33.2
1
810
dehydrate 99.5%v
E20 20
80
1)

2) 0.8 g/cm3 100

()

SERIES 3 +

CONCEPT 34

CONCEPTS 7 .. 56 12
:

H2O2
. 10.00 cm3 H2O2
. 2 10 cm3 ()
H2O2 + H+ + I- I2 + H2O
. 1-2
. Na2S2O3 0.500 mol/dm3
Na2S2O3 20.00 cm3 ()
I2 + S2O32- I- + S4O62
1) 50 mL, 100 mL, 250 mL .

2) . (limiting reagent)

3) .

4)

5) H2O2 %w/v

CONCEPT 35

SERIES 3 +
CONCEPTS 7 .. 55 17
:

1)

2)

3) 5

CONCEPT 36

SERIES 3 +
CONCEPTS 7 .. 56 17
:

1)

2)

3)

4)

5)

6)

7)

8)

9) (IV)

10)

11)

12)

13)

14)

15)

20)

21)

22)

23)

24)

CONCEPT 37

SERIES 3 +
CONCEPTS 7 .. 55 18
:

(oC)

34
-24

1) A B C D E
2)

56

SERIES 3 +

CONCEPT 38

CONCEPTS 7 .. 56 18
:

(oC)
C3H7NH2
49
CH3COOH
118
CH3COOC2H5
77
1)

2) 3 2

SERIES 3 +

CONCEPT 39

CONCEPTS 7 .. 56 19
:

3 2.00 atm SO2 4

1.50 atm 1
SO3 1.25 atm 600 K

1) atm

2)

3) atm

4) KP

SERIES 3 +

CONCEPT 40

CONCEPTS 7 .. 56 20
:

1)

2)

3)

4)

5)

6) 2800 oC 2730oC
molar mass

7)

CONCEPT 41

SERIES 3 +
CONCEPTS 7 .. 55 21
:

200 kJ

420 kJ

+150 kJ

300 kJ

240 kJ

-50 kJ

1)
2)

3)

4)

SERIES 3 +
CONCEPTS 7 .. 56 24
:

1) (RDS)

2)

3) (H)

4)

5) (intermidiate)

CONCEPT 42

CONCEPT 43

SERIES 3 +
CONCEPTS 7 .. 55 22
:

(s)
[A] (mol/L)
[B] (mol/L)

[C] (mol/L)

[D] (mol/L)

10

1.50

2.50

20

0.90

1.60

0.30

0.90

30

0.40

0.85

40

0.75

2.25

1) W X Y Z

2) A 30-40 mol/Ls

3)

4) mol/Ls

CONCEPT 44

SERIES 3 +
CONCEPTS 7 .. 56 23
:

A 0.3 50 cm3 B 0.3 50 cm3

()

()
A
B
C
D
0

0.10

0.10

0.05

0.09

0.12

0.06

1) W, X, Y Z

2) 1 /

3) 0-1 1-2

4)

SERIES 3 +

CONCEPT 45

CONCEPTS 7 .. 55 24
:

A2+ 0.5 M B 1.0 M

5.0 cm3 1 [AB4]2- 410-5
1)

2) M/s

3) 1

SERIES 3 +

CONCEPT 46

CONCEPTS 7 .. 56 22
:

10.8 g 5.0 mol/dm3

200 cm3
80
1)
2)

3) mol/s

4) ()

CONCEPT 47

SERIES 3 +
CONCEPTS 7 .. 55 23
:

47.1

1)
2) H2
3) HCl 0.1 M
HCl 0.2 M

47.2
(H2C2O4) KMnO4 H2SO4
KMnO4 KMnO4
2 KMnO4 + 5 H2C2O4 + 3 H2SO4 K2SO4 + 2 MnSO4 + 8 H2O + 10 CO2

1
2
3
4

(cm3)
KMnO4
K2C2O4
MnSO4
H2SO4
0.005
0.050
0.1
1 mol/dm3
3
3
mol/dm
mol/dm
mol/dm3
2
2
1

2
2
1

2
2
1
3
4
4
2

1)
2) X 4
3)

(oC)

(s)

15
25
15
15

45
38
22
X

CONCEPT 48

SERIES 3 +
CONCEPTS 7 .. 56 21
:

A 2A(g) B(g) + C(g) A

2
A (mol/dm3)
(s)
1
2
0

4.0

200

2.2

3.3

400

1.3

2.0

600

1.5

1 5.0 10-3 mol/dm3s

2 1.5 1
1) X Y

2) A

3) 2

4)

CONCEPT 49

SERIES 3 +
CONCEPTS 7 .. 56 25
:

N2(g) + O2(g)
2NO2(g)
N2O4(g)
N2O5(g)

2NO(g)
2NO(g) + O2(g)
NO2(g)
N2O4(g) + O2(g)

K1 = a
K2 = b
K3 = c
K4 = d

a b c d
1) 4NO2(g) + O2(g)
2N2O5(g)

2) NO2(g)

N2(g) + O2(g)

3) N2O4(g)

N2(g) + 2O2(g)

4) 2NO(g)

N2(g) + NO2(g)

SERIES 3 +

CONCEPT 50

CONCEPTS 7 .. 55 25
:

SO2(g) +

H2(g) +

SOCl2(g) +

CO(g) +

O2(g)
I2(g)
H2O(g)
H2O(g)

SO3(g)
HI(g)
SO2(g) + HCl(g)
CO2(g) + H2(g)

1) O2

2) SO2

3)

4)

5)

CONCEPT 51

SERIES 3 +
CONCEPTS 7 .. 56 28
:

1)

.... SO2(g) + ..

SO3(g) +

, K=

N2

2) steam reforming

H2O(g) + ..

, K=

N2

3) (II)

+ CuO(s) + ..

.. +

, K=

N2

4) (N2H4)

. N2H4(g)

N2

.. + . +

K=

SERIES 3 +

CONCEPT 52

CONCEPTS 7 .. 56 26
:

1 2 0.5
5.0 dm3
2SO2(g) + O2(g)
2SO3(g)

SO3
40
1)

2) mol/dm3

3) ()

SERIES 3 +

CONCEPT 53

CONCEPTS 7 .. 55 26
:

NOCl Cl2 10 227 oC

2.05 atm 0.06 mol/dm3 Cl2
NOCl
NOCl(g)
NO(g) + Cl2(g)

1) NOCl Cl2

2) NOCl

3) KC

SERIES 3 +

CONCEPT 54

CONCEPTS 7 .. 55 28
:

2.0 NOCl , N2 , O2 Cl2 0.20 , 0.10 , 0.30 , 0.40

()
NOCl(g)
N2(g) + O2(g) + Cl2(g)

1)

2) N2 NOCl 2
N2

CONCEPT 55

SERIES 3 +
CONCEPTS 7 .. 56 27
:

Haber process 250

N2(g) + 3H2(g)

(oC)
25

640

2NH3(g)
200
0.45

400
0.0002

1) endothermic exothermic
2) 400 oC

SERIES 3 +
CONCEPTS 7 .. 55 27
: -

H2B 2 Ka1 Ka2

Kw
Ka1 , Ka2 Kw
1) B2-(aq) + H2O(l)

2) HB (aq) + H2O(l)

3) B2-(aq) + H+(aq)

4) HB (aq) + H3O+(aq)

HB (aq) + OH (aq)

H2B(aq) + OH (aq)

HB (aq)

H2B(aq) + H2O(l)

CONCEPT 56

SERIES 3 +

CONCEPT 57

CONCEPTS 7 .. 55 29
: --

NH3
HSO4CH3COOH
H2O
H2NCH2COOH
HOOCCOO

SERIES 3 +

CONCEPT 58

CONCEPTS 7 .. 56 29
: - -

58.1
-
H2PO4H2O
H2SO4
HSO4S2CO32CH3COONH4+
SO42NH3
Al(OH)3

58.2

1) ZnO + 2H+ Zn2+ + H2O

2) ZnO + H2O + 2 OH [Zn(OH)4]2-

3) Al(OH)3 + 3 HCl AlCl3 + 3 H2O

4) Al(OH)3 + OH [Al(OH)4]

SERIES 3 +

CONCEPT 59

CONCEPTS 7 .. 55 31
: pH

. NaOH 0.80 g 200 cm3

. KOH 5.6 g 500 cm3
. 49 %w/v 5.0 cm3 250 cm3

1) pH 3

2) . . 10 cm3 pH

3) . . 10 cm3 pH

4) . cm3 pH .

CONCEPT 60

SERIES 3 +
CONCEPTS 7 .. 56 30
: [H+] [OH-] pH

C3H7NH2 0.1 M

NH3 0.2 M

C6H5NH2 1 M

N2H4 0.03 M

pH 11.85

pH 11.3

pH 9.3

pH 10.48

log 2 = 0.3, log 3 = 0.48, log 7 = 0.85

CONCEPT 61

SERIES 3 +
CONCEPTS 7 .. 56 31
: -

61.1
HA 1.0 mol/dm3 50 cm3 pH 4
1)

2) 150 cm3 pH

3)

61.2

mol/dm
pH

mol/dm
pH

HCOOH

2.0

1.70

0.5

NH4OH

0.02

10.78

2.0

C6H5COOH

0.15

2.52

0.60

HCN

1.00

4.70

0.04

SERIES 3 +

CONCEPT 62

CONCEPTS 7 .. 56 31
:

62.1
MOH molar mass 70 MOH
50.00 cm3 HCl 0.100 mol/dm3 HCl
20.00 cm3
1) MOH

2) MOH g/100 cm3

62.2
CH3COOC6H4COOH
1 50 cm3 KOH 0.010 M
KOH 40 cm3 1

SERIES 3 +

CONCEPT 63

CONCEPTS 7 .. 55 32
: pH

63.1
pH
1) HCl 0.1 M 10 cm3 KOH 0.10 M
2) 0.2 M 20 cm3 NaOH 0.10 M
3) 0.05 M 20 cm3 HCl 0.100 M

63.2
pH 3.3 10.00 cm3 NaOH
0.02 mol/dm3 NaOH 10.00 cm3 (log 2 = 0.3)
1)

2)

3) pH

CONCEPT 64

SERIES 3 +
CONCEPTS 7 .. 56 32
: -

64.1
3

1-3, 8-10
3-5
8-10

- , -
-
-

1) pH 5.5-6.0
2) pH 10-11
3) pH 3.0-3.5
4) pH 2.4-2.6

64.2
3

KInd
110-4
510-6
110-8

- 10

1) pH 5.5-6.0
2) pH 10-11
3) pH 3.0-3.5
4) pH 2.4-2.6

CONCEPT 65

SERIES 3 +
CONCEPTS 7 .. 55 30
: pH

pH

1) CH3COOH(aq)

NaOH(aq)

0.04 mol/dm3

0.01 mol/dm3

20.00 cm3
Ka = 210-5

2) HCOOH(aq)
1.00 mol/dm3

KOH(aq)
1.00 mol/dm3

10.00 cm3
Ka = 210-4

3) C6H5NH2
0.10 mol/dm3
20.00 cm3
Kb = 210-5

H2SO4
0.05 mol/dm3

pH

SERIES 3 +

CONCEPT 66

CONCEPTS 7 .. 56 34
: pH

(HCOOH)
50.00 cm3 NaOH 2.000 mol/dm3
NaOH 50.00 cm3 Ka 410-4
1) mol/dm3

2) pH

3) pH 8.3-10.0

4) pH

5) pH NaOH 40.00 cm3

CONCEPT 67

SERIES 3 +
CONCEPTS 7 .. 56 33
:

0.1

A. HCOOH
410-4

D. NH4OH

1.810-5

B. CH3COOH

1.810-5

E. NaOH

C. HCl

F. CH3COONa

pH
1) A 20 cm3 + E 10 cm3

2) B 5 cm3 + F 15 cm3

3) C 10 cm3 + D 15 cm3

4) C 30 cm3 + E 10 cm3

CONCEPT 68

SERIES 3 +
CONCEPTS 7 .. 55 34
: -

Hypochlorus (HClO)
Nitrous (HNO2)
Hydrofluoric (HF)
Hydrasonic (HN3)

3.510-8
4.510-4
7.210-4
1.910-5

1) 4

2) HClO 0.1 M 90 cm3 KClO 0.1 M 70 cm3

pH

3) HN3 0.2 M 60 cm3 NaOH 0.1 M 20 cm3

pH

SERIES 3 +

CONCEPT 69

CONCEPTS 7 .. 56 35
:

FeSO4 KMnO4

Na2C2O4 3.35 g
250.00 cm3

KMnO4 10.00 cm3

50.00 cm3 ()
MnO4- + H2C2O4 + H+ Mn2+ + CO2 + H2O
FeSO4 FeSO4 10.00 cm3
KMnO4 KMnO4 20.00 cm3 ()
KMnO4 + H2SO4 + FeSO4 K2SO4 + MnSO4 + Fe2(SO4)3 + H2O
1)

2)

3)

4) FeSO4

SERIES 3 +
CONCEPTS 7 .. 55 35
:

1) P4 + 5 O2 P4O10

2) P4O10 + 6 H2O 4 H3PO4

3) PCl3 + 3 H2O H3PO3 + 3 HCl

4) 2Cu2O + Cu2S 6Cu + SO2

5) 2NO2 + 2OH NO2 + NO3 + H2O

CONCEPT 70

CONCEPT 71

SERIES 3 +
CONCEPTS 7 .. 55 36
:

1) Pb3O4 + HCl PbCl2 + Cl2 + H2O

2) Pb3O4 + HNO3 Pb(NO3)2 + PbO2 + H2O

3) Cr2O72- + SO32- + .

Cr3+ +

SO42- + .

4) MnO4 + Br + .

MnO2 + BrO3 + .

5) BCl3 + LiAlH4 B2H6 + LiCl + AlCl3

6) H3PO2 + AgNO3 + H2O H3PO4 + Ag + HNO3

7) H3PO2 + CuSO4 + H2O

H3PO4 + Cu + H2SO4

()

()

SERIES 3 +
CONCEPTS 7 .. 55 39
:

E0 (V)
2.93
K+(aq) + e K(s)
2.91
Ba2+(aq) + 2e Ba(s)
2.76
Ca2+(aq) + 2e Ca(s)
2.71
Na+(aq) + e Na(s)
2.38
Mg2+(aq) + 2e Mg(s)
3+

1.68
Al (aq) + 3e Al(s)
2+

0.76
Zn (aq) + 2e Zn(s)
3+

0.74
Cr (aq) + 3e Cr(s)
2+

0.44
Fe (aq) + 2e Fe(s)
2+
0.28
Co (aq) + 2e Co(s)
0.25
Ni2+(aq) + 2e Ni(s)
0.14
Sn2+(aq) + 2e Sn(s)
0.13
Pb2+(aq) + 2e Pb(s)
0.04
Fe3+(aq) + 3e Fe(s)

1)
2)
3) Ni2+
4)

CONCEPT 72

CONCEPT 73

SERIES 3 +
CONCEPTS 7 .. 55 37
:

A.
B.
C.
D.
E.
F.
G.

Zn2+(aq) + 2e Zn(s)
Cr3+(aq) + 3e Cr(s)
Co2+(aq) + 2e Co(s)
Ni2+(aq) + 2e Ni(s)
I2(s) + 2e 2I(aq)
Br2(l) + 2e 2Br(aq)
MnO4(aq) + 8H+ + 5e Mn2+(aq) + 4H2O

A C

D E

E G

B F

E0 (V)
0.76
0.74
0.28
0.25
+0.54
+1.08
+1.51

E0cell

CONCEPT 74

SERIES 3 +
CONCEPTS 7 .. 56 36
:

Fe3+ + e- Fe2+
Fe2+ + 2e- Fe
Fe3+ + 3e- Fe
O2 + 4H+ + 4e- 2H2O

E0 = +0.77 V
E0 = -0.44 V
E0 = -0.04 V
E0 = +1.23 V

1)
a. 2Fe + O2 + 4H+ 2Fe2+ + 2H2O

b. Fe + 2Fe3+ 2Fe2+

2) -0.46 V

3) +1.27 V

CONCEPT 75

SERIES 3 +
CONCEPTS 7 .. 55 38
:

O2(g) + 2H2O + 4e 4OH

O2(g) + 4H+ + 4e 2H2O
I2(s) + 2e 2I(aq)
S4O62-(aq) + 2e 2S2O32-(aq)
2SO32-(aq) + 3H2O + 4e S2O32-(aq) +6OH (aq)
2H2O + 2e H2(g) + 2OH (aq)
K+(aq) + 4e K(s)
Fe2+(aq) + 2e Fe(s)

E0 = +0.40 V
E0 = +1.23 V
E0 = +0.54 V
E0 = +0.08 V
E0 = -0.57 V
E0 = -0.83 V
E0 = -2.93 V
E0 = -0.44 V

1) KOH

2) K2S2O3

3) KI

4) FeI2

5) H2S2O3

SERIES 3 +

CONCEPT 76

CONCEPTS 7 .. 56 37
:

NO3 + 4H+ + 2e NO + 2H2O

E0 = +0.96 V
NO3 + 2H+ + e NO2 + H2O
E0 = +0.78 V
MnO4 + 2H2O + 3e MnO2 + 4OH
E0 = +0.59 V
SO42- + 4H+ + 2e SO2 + 2H2O
E0 = +0.20 V
Au3+ + 3e Au
E0 = +1.50 V
Ag+ + e Ag
E0 = +0.80 V
Cu2+ + 2e Cu
E0 = +0.34 V
1) 1

2) 1

3) 1

4) 1

5) 1

SERIES 3 +
CONCEPTS 7 .. 56 38
:

1)

2)

CONCEPT 77

SERIES 3 +

CONCEPT 78

CONCEPTS 7 .. 56 39
:

.
.
.
.

SERIES 3 +

CONCEPT 79

CONCEPTS 7 .. 56 40
:

( Sb2S3 85)
400
C + O2 CO
Sb2O3 + CO Sb + CO2
(S = 32, Sb = 122)
1) ( C 100%)

2)
20 ( RT 25)

SERIES 3 +

CONCEPT 80

CONCEPTS 7 .. 55 40
:

80.1

1) 85 15

2) 80 20

80.2
1) 7 2

2) 3 1

SERIES 3 +

CONCEPT 81

CONCEPTS 7 .. 56 41
:

. 45 0 0 NH2CONH2
. 0 20 0 Ca(H2PO4)2
. 15 0 45 KNO3

1) 5 10 15 100 kg

2) 15 5 15 100 kg

CONCEPT 82

SERIES 3 +
CONCEPTS 7 .. 55 41
:

82.1

B2O3
Na2O CaO
Na2O 12-16%
CaO 10-15%

SiO2 100%
PbO 18-40%
Na2O, K2O 10-40%
CaF2 NaF

82.2

CONCEPT 83

SERIES 3 +
CONCEPTS 7 .. 55 42
:

83.1
IUPAC
H3C
H3C

CH
H2C

CH

CH2 CH

CH3

H2C

CH3

H2C

CH2 CH3

CH3

CH2 CH

CH2 CH3

H3C

CH2 CH3

CH

Br

Cl

Cl

Br

Br

83.2
IUPAC

OH

NH

OH

NH

SERIES 3 +
CONCEPTS 7 .. 55 44
:

84.1
C4H8
1) ( 2 )

2)

84.2
C5H10
1) ( 3 )

2) ( 2 )

84.3

CONCEPT 84

SERIES 3 +
CONCEPTS 7 .. 56 42
:

85.1

1) 2,2-dimethylhexane 2,3,4-trimethylpentane
2) dimethylbenzene ethylbenzene
3) 1,4-dimethylcyclohexene 2,4-hexadiene
4) 2-butyne 1,3-butadiene
CH3

CH3

5)

H3C

CH3

H3C

CH3

85.2

1) C4H8O Na Br2

2) C6H12 I2

3) C5H10O2 Na

4) C5H10O Br2

CONCEPT 85

SERIES 3 +
CONCEPTS 7 .. 55 43
:

86.1

1) C 2
2) 3-
3) dehydrogenation
4)
5) 1- secondary alcohol

86.2

1)

2) 2--2- 1,2,3--2-

3) - 2--1,4-

4)

5) 3- 3,4-

CONCEPT 86

SERIES 3 +

CONCEPT 87

CONCEPTS 7 .. 56 43
:

87.1
0.2 CO2 1.0
1)

2) 1

3)

87.2
X X 6.72 dm3
33.6 dm3 52.8 X
Br2

87.3
Y 1 3
1 Y Br2
Y

SERIES 3 +

CONCEPT 88

CONCEPTS 7 .. 56 44
:

4 80-90 g/mol 1

1)

2)

3)

4)

CONCEPT 89

SERIES 3 +
CONCEPTS 7 .. 56 45
:

1)

2)

3)

2-hexene

2-hexanol

4)

5)

6)

3-

3,4-

7)

2,2,4-

8)

2-

CO2

9)

N-ethylpropanamide

Ethanamine
propanoic acid

10)

butanamine

Butylammonium
chloride

SERIES 3 +

CONCEPT 90

CONCEPTS 7 .. 55 45
:

90.1
A C H O 2.0 g CO2 4.4 g H2O 2.4 g
A Na A

90.2
B 50 20
B 1 B

SERIES 3 +

CONCEPT 91

CONCEPTS 7 .. 55 46
:

91.1

1) 2

2) 2

91.2


1)

2)

3) ?

91.3

SERIES 3 +
CONCEPTS 7 .. 56 47
:

1)
2)
3)
4)

5)

6)

7) addition polymerization

8) engine knocking knock

9) vulcanization

CONCEPT 92

SERIES 3 +

CONCEPT 93

CONCEPTS 7 .. 55 47
:

93.1
PVC PTFE ABS PETE PS PMMA
1)

2) homopolymer

93.2

1)
2)

93.3
HDPE LDPE

93.4

CONCEPT 94

SERIES 3 +
CONCEPTS 7 .. 56 47
:

1)
2)

3)

4)

5)

.
.

SERIES 3 +

CONCEPT 95

CONCEPTS 7 .. 56 48
:

A B C (side chain) CH2COOH , CH2OH CH2C6H5

1) A B C

2) A C

3) A B C 1 (
)

CONCEPT 96

SERIES 3 +
CONCEPTS 7 .. 55 48
:

96.1
5%

1)
2)
3)
4)

96.2

H2 N

H2N

CH2

COOH

H2N

CH

COOH

CH

COOH

CH

CH3

CH3

CH3

1
2 2
3 2
4 3
1)

2) 3

SERIES 3 +

CONCEPT 97

CONCEPTS 7 .. 56 49
:

97.1

1)
2)
3)
4)

97.2
491

39.28 4.32

SERIES 3 +

CONCEPT 98

CONCEPTS 7 .. 56 50
:

1)

2)

3)
Cu2+

4) 18 C

SERIES 3 +
CONCEPTS 7 .. 55 49
:

1)

2)
4

3)
3

4)

CONCEPT 99

SERIES 3 +

CONCEPT 100

CONCEPTS 7 .. 55 50
:

100.1
N
NH4+
1-2 .

1)
2)

100.2