1

2011 21
08:25

-
- -
- - -19 19

-
83
-
NO - - - -
F Cl br I PS 2
-

1
-

4 -
8 3 - 5

2 2 - 6-

2
 S S

3
4
 4- 4
109.5 sp3

2 4

1
4 Sp3
4 S
P

P
S

5
- 2
P
- 2

6
7
 -

10% -

10%

8
9
 - -

10
 2011 21
08:51

11
12
13
14
15
16
17
 2011 21
09:46

-
30

-
-

- - - -

18
dH=-212.8 kcal/mol

30

19
 -

20
 -

- -

21
 2

22
23
 -

-2

24
 9
- 1

9
-
3
-
-
2-

25
 0

60

26
 -

- - -

27
 - - -
- 6
-6 5 -
-

-
KCAL 27

27.6

26.4

6.5

-
-120
2
0

0 - -
6.5 - - -
kcal/mol
-

28
 -
a-axial
e-equatorial

99%

29
 - 2 -
2 -

Cis-1,2-dicloropropan

Trans-1,2-dicloropropan

30
 2011 07
09:23

31
 4
-1
- 2

32
 1

-
-

33
34
 2011 07
09:47

+d -l
R S

2
2
-
2^n
-ZE

35
 2

63

2 -

36
3

37
 C2

E 2 -

C3

C2
H2
H3 1

3-methyl -2(E)-hexene
2
E
H C

3(trans),5(trans)-nonadiene

38
 - - -
- -

- - -
-
-
- -

39
 2011 14
08:15

- -2,3 -

40
D
20
20-
L
Level-

41
42
 -1
-4

R-

S-

43
2-

44
 2011 16
08:47

45
- - CO
-
-

46
 -
- -

2
-

10

-
- 4

0 -

47
- - - -
- - 2
-

48
-

2
S R

49
50
 - 2 OH 1 H-
- - -

51
52
 2

-
-

53
 -
2011 21
08:55

- -

54
 adition

CH
CCl

2 - 2

55
 2

syn -

2
63
100

cis
-
-

-
2

56
 3
-

1-

57
 -

58
59
60
61
62
63
64
65
66
67
68