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Textbook Fundamentals and Applications of Supercritical Carbon Dioxide Sco2 Based Power Cycles 1St Edition Klaus Brun Ebook All Chapter PDF
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Fundamentals and Applications of Supercritical
Carbon Dioxide (sCO2) Based Power Cycles
Woodhead Titles
Concentrating Solar Power Technology
(ISBN 978-1-84569-769-3)
Modern Gas Turbine Systems
(ISBN 978-1-84569-728-0)
Combined Cycle Systems for Near-Zero Emission Power Generation
(ISBN 978-0-85709-013-3)
Fundamentals and
Applications of
Supercritical Carbon
Dioxide (sCO2) Based
Power Cycles
Edited by
Klaus Brun
Peter Friedman
Richard Dennis
Woodhead Publishing is an imprint of Elsevier
The Officers’ Mess Business Centre, Royston Road, Duxford, CB22 4QH, United Kingdom
50 Hampshire Street, 5th Floor, Cambridge, MA 02139, United States
The Boulevard, Langford Lane, Kidlington, OX5 1GB, United Kingdom
Practitioners and researchers must always rely on their own experience and knowledge in
evaluating and using any information, methods, compounds, or experiments described
herein. In using such information or methods they should be mindful of their own safety and
the safety of others, including parties for whom they have a professional responsibility.
To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors,
assume any liability for any injury and/or damage to persons or property as a matter of
products liability, negligence or otherwise, or from any use or operation of any methods,
products, instructions, or ideas contained in the material herein.
Library of Congress Cataloging-in-Publication Data
A catalog record for this book is available from the Library of Congress
List of contributors xi
The Editors xiii
Foreword xv
Overview xix
2 Physical properties 23
G. Musgrove, B. Ridens, K. Brun
Overview 23
Key Terms 23
2.1 Introduction 23
2.2 Qualities of supercritical CO2 23
2.3 Equations of state for calculating supercritical CO2 properties 24
2.4 Overview of thermodynamic property trends 29
2.5 Impurities of CO2 mixtures 35
2.6 Summary 38
References 39
3 Thermodynamics 41
P. Friedman, M. Anderson
Overview 41
Key Terms 41
3.1 Introduction 41
3.2 Governing relationships 46
3.3 Analysis 53
3.4 Example applications 61
3.5 Conclusions 66
References 66
vi Contents
4 High-temperature materials 67
B.A. Pint, R.G. Brese
Overview 67
Key Terms 67
4.1 Introduction 67
4.2 Thermodynamics of oxidation 76
4.3 Investigations of high-temperature corrosion in ambient
and subcritical CO2 79
4.4 Laboratory investigations of supercritical CO2 corrosion rates
and reaction products 81
4.5 Effect of CO2 on mechanical properties 92
4.6 Current status and ongoing supercritical CO2 work 93
4.7 Future directions 94
4.8 Conclusions 96
Acknowledgments 97
References 97
6 Economics 127
S. Wright, W. Scammell
Overview 127
Key Terms 127
6.1 Introduction (advantages and disadvantages in potential
markets) 127
6.2 Potential markets 128
6.3 Introduction to the economics of supercritical CO2 power plants 133
6.4 Project cost basis 138
6.5 Summary and conclusions of supercritical CO2 power system
economics 144
References 144
Contents vii
7 Turbomachinery 147
T.C. Allison, J. Moore, R. Pelton, J. Wilkes, B. Ertas
Overview 147
Key Terms 147
7.1 Introduction 147
7.2 Machinery configurations 149
7.3 Existing supercritical CO2 turbomachinery designs 154
7.4 Common design attributes and components 180
7.5 Compressor and pump design considerations for supercritical CO2 203
7.6 Turbine design considerations for supercritical CO2 208
7.7 Summary 210
References 211
Index 423
This page intentionally left blank
List of contributors
T.C. Allison Southwest Research Institute, San Antonio, TX, United States
R. Ames National Energy Technology Laboratory, Morgantown, WV, United States
M. Anderson University of Wisconsin, Madison, WI, United States
J.A. Bennett Southwest Research Institute, San Antonio, TX, United States
R.G. Brese University of Tennessee, Knoxville, TN, United States
K. Brun Southwest Research Institute, San Antonio, TX, United States
P.C. Bueno Southwest Research Institute, San Antonio, TX, United States
M. Carlson Sandia National Laboratories, Albuquerque, NM, United States
L. Chordia Thar Energy, LLC, Pittsburgh, PA, United States
E.M. Clementoni Naval Nuclear Laboratory, West Mifflin, PA, United States
R.A. Dennis National Energy Technology Laboratory, Morgantown, WV, United
States
B. Ertas GE Global Research, Niskayuna, NY, United States
D. Fleming Sandia National Laboratories, Albuquerque, NM, United States
P. Fourspring Naval Nuclear Laboratory, Niskayuna, NY, United States
P. Friedman Newport News Shipbuilding, Newport News, VA, United States
T. Held Echogen Power Systems (DE), Inc., Akron, OH, United States
S. Lawson National Energy Technology Laboratory, Morgantown, WV, United
States
A. Moisseytsev Argonne National Laboratory, Argonne, IL, United States
J. Moore Southwest Research Institute, San Antonio, TX, United States
G. Musgrove Southwest Research Institute, San Antonio, TX, United States
J. Pasch Sandia National Laboratories, Albuquerque, NM, United States
R. Pelton Hanwha Techwin, Houston, TX, United States
xii List of contributors
B.A. Pint Oak Ridge National Laboratory, Oak Ridge, TN, United States
M. Poerner Southwest Research Institute, San Antonio, TX, United States
B. Ridens Southwest Research Institute, San Antonio, TX, United States
A. Rimpel Southwest Research Institute, San Antonio, TX, United States
G. Rochau Sandia National Laboratories, Albuquerque, NM, United States
W. Scammell SuperCritical Technologies, Inc., Bremerton, WA, United States
D. Shiferaw Heatric Division of Meggitt (UK) Ltd, Poole, United Kingdom
J.J. Sienicki Argonne National Laboratory, Argonne, IL, United States
J. Stekli U.S. DOE Office of Solar Energy Technologies, Washington, DC, United
States
P. Strakey National Energy Technology Laboratory, Morgantown, WV, United
States
S. Sullivan Brayton Energy, Hampton, NH, United States
D. Thimsen Electric Power Research Institute, St. Paul, MN, United States
C.S. Turchi National Renewable Energy Laboratory, Golden, CO, United States
N.T. Weiland National Energy Technology Laboratory, Pittsburgh, PA, United
States
J. Wilkes Southwest Research Institute, San Antonio, TX, United States
S. Wright SuperCritical Technologies, Inc., Bremerton, WA, United States
The Editors
Acknowledgments
We would like to thank Dorothea Martinez for her tireless efforts and assistance while
putting this book together. Many others provided valuable input to make this book a
reality: To you a simple thanks is offered.
Foreword
For 100 years after its inception, the steam Rankine cycle dominated electric power
generation, as a result of its availability, and the suitability of its properties, including
saturation temperature and high liquid density. Feedwater heaters (typically 7e10)
raise Rankine cycle efficiency from around 28% to about 35% on an average and
improvements in high-temperature materials and control systems have led to evolu-
tionary improvements in plant efficiency. Recently, the availability of low-cost natural
gas and advancement in gas turbine engines resulted in growing deployment of
combined cycle power plants, which take advantage of the air Brayton cycle’s capacity
to accept high-temperature heat and the steam Rankine cycle’s ability to reject heat at
lower operating temperatures. For nuclear applications, high-temperature gas-cooled
reactors operating in closed Brayton cycles are gaining momentum as a replacement
for the steam Rankine cycle.
Although steam and air cycles will continue to dominate the power generation
industry in the foreseeable future, recent developments in high-temperature materials
as well as compact heat exchanger design have led to an interest in supercritical carbon
dioxide (sCO2) as an alternative. Closed Brayton cycle sCO2 plants combine many of
the advantages of Rankine cycles, including reduced pumping/compression power and
the ability to reject heat at low temperatures with the Brayton cycle’s suitability to
high-temperature heat inputs. Additionally, sCO2 plants are significantly simpler
than typical steam Rankine or combined cycle plants and offer a greater power density.
As gas turbine exhaust temperatures continue to increase, the application of an sCO2
bottoming cycle in combined cycle applications becomes increasingly advantageous.
Although the technology must be advanced before sCO2 plants are deployed commer-
cially, their simplicity and reduced footprint could give them an economic advantage
and their suitability to dry cooling could give them an advantage in areas where water
is limited. Conceptual designs indicate that sCO2 cycles are well suited to a broad
range of applications including fossil fuel plants (with and without carbon capture
and sequestration), nuclear, waste heat recovery, and concentrated solar energy.
This book is targeted at both engineers who are new to the topic of sCO2 (by sup-
plying sufficient background material) and specialists (with the inclusion of in-depth
reference material). Each chapter provides sufficient background material to be read
on its own, although duplication has been avoided. It is organized into four parts.
Part 1 provides a background on the fundamental concepts, including sCO2 properties,
sCO2 cycles, thermodynamic analysis, high-temperature materials that are in use or be-
ing developed, modeling of sCO2 cycle, and economic considerations. Part 2
xvi Foreword
Overview
This chapter provides an overview of the indirect-fired Brayton cycle utilizing
supercritical CO2 (sCO2) to illustrate the improvement in power cycle efficiency
over other fluids. Additionally, multiple variations of the power cycle are
reviewed to show why the recompression cycle with recuperation is typically
chosen for power generation with sCO2.
Key Terms
Brayton cycle, Recompression, Recuperated, sCO2 power cycle.
1. Introduction
The vast majority of electric power generation for the grid is accomplished by
coupling a thermal power cycle to a heat source. The nature and configuration of
the thermal power cycle is to provide efficient power production as it is economi-
cally attractive. Most of the thermal power cycles in commercial operation are either
air-breathing direct-fired open Brayton cycles (i.e., gas turbines) or indirect-fired
closed Rankine cycles, which use water as a working fluid (typical in pulverized
coal and nuclear power plants). Within each group are a myriad of potential config-
urations that vary in size and complexity. For any application, the best thermal po-
wer cycle will depend on the specific nature of the application and heat source.
In addition to these conventional thermal power cycles, cycles based on other
working fluids can be considered. In particular, the Brayton cycle based on su-
percritical CO2 (sCO2) as the working fluid is an innovative concept for convert-
ing thermal energy to electrical energy. Numerous studies have shown that these
sCO2 power cycles have the potential to attain significantly higher cycle effi-
ciencies than either a conventional steam Rankine cycle or even the state-of-
the-art ultrasupercritical (USC) steam Rankine cycle (Subbaraman et al.,
2011; Kacludis et al., 2012; Shelton et al., 2016). Higher cycle efficiency will
xx Overview
automatically lead to lower fuel cost, lower water usage, and in the case of fossil fuel
heat sources, lower greenhouse gas (GHG) emissions. Furthermore, the sCO2 cycles
operate at high pressures throughout the cycle, resulting in a working fluid with a
high density, which may lead to smaller equipment sizes, smaller plant footprint,
and therefore lower capital cost.
Starting
Generator
motor
Re- Main
Turbine
compressor compressor
Speed
reduction
gear F B A
T P
Cooling
(K) (MPa)
Gas
Q High temp cooler
recuperator
C
Low temp
recuperator
G H
D
Figure 1 Block flow diagram for recompression closed Brayton cycle. The state points
A through H are defined in Figure 4.R.8.
Courtesy Sandia National Laboratories (Pasch and Sandia, 2013).
24,000
Recompressor Q heater
22,000 out, low temp
recup out, high High temp
Main compressor recup out,
temp recup in Heater out,
20,000 out, low temp heater in turbine in
recup in B
18,000 C D E
Q lo
Q hig
16,000
w te
h tem
Pressure (kPa)
mp r
14,000
p re
ecup
cup
12,000
Gas cooler
10,000 out, main
compressor in
A H G F
8000
Low temp High temp Turbine out,
6000 recup out, recup out, high temp
gas cooler low temp recup in
4000 in, recomp recup in
Q gas in
cooler
2000 Saturation
dome
0
0 200 400 600 800 1000 1200
Enthalpy (kJ/kg)
temperature of approximately 600 C and a cycle pressure drop of 700 kPa. Points
CeH in Fig. 1 are the same as a recuperated Brayton cycle (RB). Differing from a
RB, a portion of the low-pressure CO2 exiting the recuperator bypasses the CO2 cooler
and is compressed to the maximum cycle pressure in a separate compressor from the
main CO2 compressor. Additionally, this stream bypasses the low-temperature portion
of the recuperator. The overall thermal effect is to provide a better match of thermal
capacity between the hot and cold sides of the recuperator and increase the overall
effectiveness of the recuperator. The disadvantage of this configuration is that the cycle
is more complex and an extra compressor is required. While the total amount of power
required for CO2 compression actually increases in this configuration, the net cycle ef-
ficiency increases because more CO2 can pass through the cycle for any given thermal
input. Note that in Fig. 1, two different values of the temperature and pressure are
shown for state point A. These correspond to two different scenarios for the CO2
cooler: a wet cooling case using water as the cooling medium and a dry cooling
case using air cooling. The dry cooling case has a lower efficiency than the wet cooling
case but the efficiency reduction could be reduced by increasing the minimum cycle
pressure.
Fig. 3 compares the cycle efficiency of the recompression CO2 Brayton cycle (RCBC)
with the RB for CO2 with a turbine inlet temperature of 700 C. The recuperated cycle
efficiency curves for N2 and He are also shown for comparison. For N2 and He, the
working fluid is not near the critical point at the exit of the cooler, therefore a recom-
pression cycle offers no benefit. For CO2, at the pressure ratio of maximum cycle ef-
ficiency, the efficiency of the recompression cycle is over 5 percentage points higher
than that of the RB.
60
50
Cycle efficiency (%)
40
He, RB
30
N2, RB
20 CO2, RB
CO2, RCBC
10
0
0 5 10 15
Pressure ratio
Figure 3 Recompression Brayton cycle efficiency. Plot shows cycle efficiency versus pressure
ratio for RCBC (solid line) and recuperated Brayton cycle (dashed lines, RB).
NETL; From White, C., 2016. “Analysis of Brayton Cycles Utilizing Supercritical Carbon
Dioxide - Revision 1”, DOE/NETL-4001/070114 (in preparation). See also: https://www.netl.
doe.gov/energyanalyses/temp/AnalysisofBraytonCyclesUtilizingSupercriticalCarbonDioxide_
070114.pdf.
Overview xxiii
55
50
Cycle efficiency (%)
45
40
35 Rankine
RCBC
30
25
20
250 350 450 550 650 750
Turbine inlet temperature (°C)
attain higher cycle efficiencies than conventional steam Rankine cycles, nonsupercrit-
ical Brayton cycles, or geothermal power cycles. This is achieved primarily by select-
ing the cycle operating state to minimize the power requirement for compressing the
working fluid and by using a high degree of thermal recuperation.
The range of potential applications for the indirect sCO2 Brayton cycle is broad since it can
be used in essentially any application that currently uses a Rankine cycle. Generally, the
operating point where the recompression sCO2 Brayton cycle attains its highest efficiency
requires a large degree of thermal recuperation. This reduces the heat loss in the CO2
cooler and allows the heat source to heat the maximum amount of working fluid and hence
generate the maximum amount of power output. A potential disadvantage of this high de-
gree of recuperation is that the temperature increase of the CO2 in the heat source is rela-
tively low. If the hot source operates across a wide temperature range, it will create
challenges in maintaining high cycle efficiency without discarding a significant portion
of the available hot source energy. Many of the promising applications for indirect
sCO2 Brayton cycle have heat sources that have a narrow temperature range. Examples
include applications with nuclear, solar, and geothermal heat sources. In each of these
cases, the sCO2 Brayton cycle operating state can be custom-configured to utilize the
maximum amount of energy available from the hot source. When the hot source temper-
ature range is large, more complex modifications to the cycle are generally required. This
may entail a higher degree of process-level heat integration, reduction in cycle recupera-
tion to increase the amount of hot source energy that can be utilized in the cycle, employ-
ing a more complex cascade cycle configuration, or possibly using a combined cycle
process in which the sCO2 Brayton cycle serves as the topping cycle and a Rankine cycle
is used as a bottoming cycle. Conceptual designs have been proposed for each of these
alternatives (Kimzey, 2012; Ahn, 2014; Bae et al., 2015).
The sCO2 Brayton cycle can also be configured for direct heating, which increases its
range of potential applications. The most promising application areas for direct cycles
are with fossil fuel sources. Although it is overall process efficiency and not cycle effi-
ciency that will determine whether a given thermal power cycle is more efficient, for
many applications, it is straightforward to demonstrate that a higher cycle efficiency
will lead to a higher process efficiency. This is because the fraction of energy from
the heat source that can be harvested by the power cycle is generally not diminished
with the sCO2 Brayton cycle and there is generally not an increase in the balance of plant
auxiliary power required by the plant for the sCO2 Brayton cycle compared to Rankine
cycles. Direct cycles also provide an intrinsic method to capture the water generated dur-
ing combustion as liquid water, which will partially offset the water withdrawal in a
water-cooled application. Oxy-fired direct cycles for fossil fuel applications have the
additional benefit of facilitating CO2 capture, significant given the US Environmental
Protection Agency’s Carbon Pollution Standards, issued under the authority of Section
111(b) of the Clean Air Act in August, 2015, that limit CO2 emissions from new coal-
fired power plants to 1400 lb CO2/MWh-gross (EPA web site, 2015).
Table 1 provides a listing of the major categories of applications for the sCO2 Brayton
cycle, the expected cycle configuration, the peak temperature for the working fluid,
xxvi
Table 1 Potential applications for sCO2 for power conversiondmodified from workshop (SwRI, 2013)
Temperature Pressure
Application Cycle type Motivation Size (MWe) ( C) (MPa)
Nuclear Indirect sCO2 Efficiency, size, water reduction 10e300 350e700 20e35
Fossil fuel (PC, CFB, .) Indirect sCO2 Efficiency, water reduction 300e600 550e900 15e35
Concentrating solar power Indirect sCO2 Efficiency, size, water reduction 10e100 500e1000 35
Shipboard propulsion Indirect sCO2 Efficiency, size <10e10 200e300 15e25
Shipboard house power Indirect sCO2 Efficiency, size <1e10 230e650 15e35
Waste heat recovery Indirect sCO2 Efficiency, size, simple cycles 1e10 <230e650 15e35
Geothermal Indirect sCO2 Efficiency 1e50 100e300 15
Fossil fuel (syngas, natural gas) Direct sCO2 Efficiency, water reduction, 300e600 1100e1500 35
CO2 cap
Overview
Overview xxvii
and the major benefits the sCO2 Brayton cycle may potentially demonstrate in each
application.
The principal benefit of the sCO2 Brayton cycle is the potential for an increase in both
cycle and process efficiency compared to processes that employ Rankine cycles. An in-
crease in process efficiency has many secondary benefits including a reduction in the ther-
mal input needed to generate a fixed amount of power, which lowers the size and capital
cost, and for some applications, also lowers the fuel usage and operating costs. Increasing
process efficiency also diminishes the environmental footprint of the process by reducing
water usage and in the case of fossil fuel applications, reducing GHG emissions.
There are other potential benefits of the sCO2 Brayton cycle as well, although they
remain to be demonstrated as convincingly as the potential for higher process effi-
ciency. Because of the relatively high density of the working fluid, there is a potential
for some of the unit operations to be smaller and less costly on a $/kWe basis. How-
ever, not all of the properties of the sCO2 Brayton cycle lend themselves to size and
cost reductions. For example, the sCO2 Brayton cycle is more complex than the
Rankine cycle which requires compressors instead of feedwater pumps, and requires
recuperators having larger heat duties than the heat source.
Another potential benefit is that the sCO2 Brayton cycle may prove to be more prac-
tical than the Rankine cycle for air cooling in locations where water cooling is not
available (Conboy et al., 2014). This is because the working fluid cooler in the
sCO2 Brayton cycle requires significantly less air flow than an air-cooled condenser
in a Rankine cycle having the same cooling duty. However, this benefit is achieved
through reduction in the average driving force for heat transfer in the cooler, which
would act to increase the required surface area for heat transfer, and some investigators
have questioned the practicality of air cooling in the sCO2 Brayton cycle (Moisseytsev
and Sienicki, 2014). With further analysis, development, and demonstration, the
impact of this technology on power plant costs and water usage will become clearer.
References
Ahn, Y., Baea, S.J., Kima, M., Choa, S.K., Baika, S., Lee, J.I., Cha, J.E., October 30e31, 2014.
Cycle layout studies of sCO2 cycle for the next generation nuclear system application.
Transactions of the Korean Nuclear Society Autumn Meeting, Pyeongchang, Korea.
Bae, S.J., Lee, J., Ahn, Y., Lee, J.I., 2015. Preliminary studies of compact Brayton cycle per-
formance for small modular high temperature gas-cooled reactor system. Annals of Nuclear
Energy 75. http://www.sciencedirect.com/science/article/pii/S0306454914003727.
Conboy, T.M., Carlson, M.D., Rochau, G.E., August 2014. Dry-cooled supercritical CO2 power
for advanced nuclear reactors. Journal of Engineering for Gas Turbines and Power 137,
012901. https://www.researchgate.net/publication/270772560_Dry-Cooled_Supercritical_
CO_2_Power_for_Advanced_Nuclear_Reactors.
EPA Website, August 2015. Carbon Pollution Standards for New, Modified and Reconstructed
Power Plants. https://www.epa.gov/cleanpowerplan/carbon-pollution-standards-new-
modified-and-reconstructed-power-plants#rule-summary.
xxviii Overview
EPRI, December 2014. Performance and Economic Evaluation of Supercritical CO2 Power Cycle
Coal Gasification Plant, 3002003734. http://www.epri.com/abstracts/Pages/ProductAbstract.
aspx?ProductId¼000000003002003734.
EPRI, August 2015. R-SCOT: Rocket Engine-Derived High Efficiency Turbomachinery for Electric
Power Generation, 3002006513. http://www.epri.com/abstracts/Pages/ProductAbstract.aspx?
ProductId¼000000003002006513.
Fleming, D., Conboy, T., Pasch, J., Rochau, G., Fuller, R., Holschuh, T., Wright, S., November
2013. Scaling Considerations for a Multi-Megawatt Class Supercritical CO2 Brayton Cycle
and Path Forward for Commercialization. SAND2013-9106. http://prod.sandia.gov/
techlib/access-control.cgi/2013/139106.pdf.
Invernizzi, C.M., 2013. Closed Power Cycles e Thermodynamic Fundamentals and Applica-
tions. © Springer-Verlag, London. http://dx.doi.org/10.1007/978-1-4471-5140-1.
Kacludis, A., Lyons, S., Nadav, D., Zdankiewicz, E., December 2012. Waste heat to power
(WH2P) applications using a supercritical CO2-based power cycle. In: Presented at Power-
Gen International 2012, Orlando, FL.
Kimzey, G., 2012. Development of a Brayton Bottoming Cycle using Supercritical Carbon
Dioxide as the Working Fluid. EPRI. http://www.google.com/url?sa¼t&rct¼j&q¼&esrc¼s&
source¼web&cd¼1&cad¼rja&uact¼8&ved¼0ahUKEwjYp8fvmuLLAhUBKB4KHVpi
CUQQFggcMAA&url¼http%3A%2F%2Fwww.swri.org%2Futsr%2Fpresentations%
2Fkimzey-report.pdf%26usg¼AFQjCNHKJpKIw7Gw1si89Rb3hcD-kjMgxQ%26sig2¼
wGXhCf4_ksw9CpN9jLbXGg%26bvm¼bv.117868183,d.dmo.
Moisseytsev, A., Sienicki, J.J., September 9e10, 2014. Investigation of a dry air cooling option for an
s-CO2 cycle. In: The 4th International Symposium e Supercritical CO2 Power Cycles, Pitts-
burgh, Pennsylvania. http://www.swri.org/4org/d18/sco2/papers2014/systemModelingControl/
44-Moisseytsev.pdf.
Pasch, J.J., Sandia, 2013.
Power Engineering Website, March 2016. http://www.power-eng.com/articles/2016/03/net-
power-breaks-ground-on-zero-emission-gas-fired-demo-plant.html.
sCO2 Power Cycle Roadmapping Workshop, February 2013. SwRI, San Antonio, TX.
Shelton, W.W., Weiland, N., White, C., Plunkett, J., Gray, D., March 29e31, 2016. Oxy-coal-
fired circulating fluid bed combustion with a commercial utility-size supercritical CO2
power cycle. In: The 5th International Symposium e Supercritical CO2 Power Cycles, San
Antonio, TX. http://www.swri.org/4org/d18/sco2/papers2015/104.pdf.
Subbaraman, G., Mays, J.A., Jazayeri, B., Sprouse, K.M., Eastland, A.H., Ravishankar, S.,
Sonwane, C.G., September 2011. Energy systems, Pratt and Whitney Rocketdyne, ZEPS
plant model: a high efficiency power cycle with pressurized fluidized bed combustion
process. In: 2nd Oxyfuel Combustion Conference, Queensland, Australia. http://www.
ieaghg.org/docs/General_Docs/OCC2/Abstracts/Abstract/occ2Final00143.pdf.
White, C., 2016. “Analysis of Brayton Cycles Utilizing Supercritical Carbon Dioxide - Revision
1”, DOE/NETL-4001/070114 (in preparation). See also: https://www.netl.doe.gov/energy-
analyses/temp/AnalysisofBraytonCyclesUtilizingSupercriticalCarbonDioxide_070114.pdf.
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Diaz, Hist. Verdad., 54. ‘Hizo la sala principal de Xicotencatl Oratorio.’ Ixtlilxochitl,
Hist. Chich., 294. ‘Hizo una iglesia en una casa de un ídolo principal.’ Tapia, Rel.,
in Icazbalceta, Col. Doc., ii. 572-3. This author does not intimate that Cortés
sought to force conversion, Bernal Diaz alone being responsible for the statement,
though Herrera adopts it. Eager to remove the reproach of infidelity from his
people, Camargo relates that Cortés insisted on the renunciation of idolatry, and
that the chiefs finally yielded, while placing upon him the responsibility of removing
the images. When the iconoclasm began, the people hastened to hide their
cherished idols, which they long worshipped in secret, although accepting
baptism. Hist. Tlax., 150-8. In a hieroglyphic painting still possessed by the
cabildo, says Ixtlilxochitl, it is shown that the lords were at this time baptized. He
gives their new names. Hist. Chich., 294.
[350] ‘Durò tres, ó quatro años.’ Remesal, Hist. Chyapa, 304; Dávila, Teatro
Ecles., i. 78; Camargo, Hist. Tlax., 140; Herrera, dec. ii. lib. vi. cap. xv. Solis dwells
upon the spiritual effect of the miracle, which occurred immediately after the
departure from Tlascala. Hist. Mex., i. 324-5. Torquemada devotes a whole
chapter to it, and states that the first cross was raised by unseen hands the night
after the arrival of the Spaniards in the city. The high-priest placed over it a guard,
who was surprised by a celestial light which appeared at midnight and drove out
the demon from the temple, iii. 200-3.
[351] ‘Lo primero que mandaua nuestro Capitan era quebralles las tales carceles,
y echar fuera los prisioneros.’ Bernal Diaz, Hist. Verdad., 55.
[352] In order to obtain by them a race of heroes. Most writers, following Bernal
Diaz and the less explicit chroniclers, allow Xicotencatl to give only one daughter,
but Ixtlilxochitl names two, Hist. Chich., 294. and Juarros, in his biography of the
Alvarados, enumerates their different wives, and among them the two sisters, with
their full names and their descendants. Pedro de Alvarado’s only surviving issue,
he says, was a daughter Leonor, by Luisa, who married first Pedro Puertocarrero
and afterward Francisco de la Cueva, nephew of the Duke of Alburquerque. The
other sister also left a daughter. Hist. Guat., 347-8. Bernal Diaz mentions also a
son, Pedro, by Luisa. Hist. Verdad., 54; Clavigero, Storia Mess., iii. 54. According
to Camargo, 300 young and pretty slave girls, destined for the sacrifices, were the
first women offered. They were at first declined, but finally accepted for the suite of
Marina. Finding that they were well treated, the lords offered their own daughters
in marriage. Hist. Tlax., 148-50. A number of women were added to the suite of
Marina and of the new wives, from the first families in the state, another authority
intimates. Gomara, Hist. Mex., 86; Herrera, dec. ii. lib. vi. cap. xi.
[353] Camargo, Hist. Tlax., 150-1. They opened a road to Cempoala, and brought
effects from Villa Rica, including presents for the lords. Ixtlilxochitl, Hist. Chich.,
294.
[354] Tapia writes, ‘Yo que esto escribo pregunté á Muteczuma y á otros sus
capitanes,’ and was told that the Mexicans could readily have subdued little
Tlascala, but they preferred to use her as a means, close at hand, for exercising
their youth and armies in warfare, and for supplying war captives for the sacrifices!
Tapia, Rel., in Icazbalceta, Col. Doc., ii. 572. ‘Juntaua dozientos y trezientos mil
hombres para vna batalla.’ Gomara, Hist. Mex., 89. The Tlascaltecs spoke of their
descent from giants, and produced gigantic bones in evidence thereof. Some of
these were sent to Spain by Cortés, together with the report. Bernal Diaz, Hist.
Verdad., 55.
[355] Torquemada places the arrival of this embassy immediately after Cortés’
entry into Tlascala, Monarq. Ind., i. 433, while Clavigero dates it at Tecohuatzinco.
Storia Mess., iii. 51-2. Brasseur de Bourbourg calls it the second embassy, Hist.
Nat. Civ., iv. 165, for he accepts the statement of Ixtlilxochitl, Hist. Chich., 288, that
the first envoys saw Cortés at his camp by San Juan de Ulua. For Ixtlilxochitl’s
career, see Native Races, v. 474-7.
[356] Bernal Diaz relates that Cortés detained these men as hostages, while he
sent Alvarado and Bernardino Vazquez de Tapia to Mexico to communicate with
Montezuma, and to examine the route and approaches to the city. They had hardly
left before the company began to censure the rashness of sending two valuable
men on so risky a mission, and Cortés accordingly sent to recall them. Tapia
having fallen sick on the road, they gladly returned, but left the guides to proceed
to Mexico.
[357] ‘Me dijeron ... que para ello habia enviado Muteczuma de su tierra ...
cincuenta mil hombres, y que los tenia en guarnicion á dos leguas de la dicha
ciudad ... é que tenian cerrado el camino real por donde solian ir, y hecho otro
nuevo de muchos hoyos, y palos agudos hincados y encubiertos para que los
caballos cayesen y se mancasen, y que tenian muchas de las calles tapiadas, y
por las azoteas de las casas muchas piedras.’ Cortés, Cartas, 70. The stream
within the temple was a myth, which the Cholultecs sought to maintain in order to
frighten their enemies. Oviedo and Gomara relate that Xicotencatl junior was
concerned in these plots, and that, warned by his sister, the wife of Alvarado,
Cortés had him quietly seized and choked to death, iii. 497; Hist. Mex., 90.
Whoever may have been throttled, it certainly was not the general, for he met his
fate at a later date. According to Bernal Diaz the whole army was consulted as to
whether all were prepared to start for Mexico. Many of those owning estates in
Cuba raised objections, but Cortés firmly declared that there was no other way
open than the one to Mexico, and so they yielded. Hist. Verdad., 56.
[358] ‘Y dar la obediencia â nuestro Rey, y Señor, sino que los ternia por de malas
intenciones.’ Bernal Diaz, Hist Verdad., 56. According to Camargo, Patlahuatzin of
Tlascala was sent with the message. The Cholultecs seized and flayed his face
and arms, cutting off the hands, so that they were left dangling by the skin from
the neck. In this guise they sent him back with the reply that thus would they
receive the white gods whose prowess he had extolled. The Tlascaltecs
demanded that Cortés should avenge the cruelty and the insult, and he did so in
the massacre of Cholula. This, continues the narrator, is commemorated in
Tlascalan song, but the account is evidently mixed, and probably refers chiefly to
some earlier occurrence. Hist. Tlax., 161-2. Brasseur de Bourbourg assumes that
Patlahuatzin is merely insulted and ill-treated. The two peoples had once been
friends and allies, but during the last battle which they fought against their
common enemy, the Aztecs, the Cholultecs had suddenly changed sides and
fallen on the rear of their unsuspecting allies, inflicting great slaughter. Herrera,
dec. ii. lib. vi. cap. xviii.
[359] Three of the members are imprisoned for favoring an alliance with the
Spaniards, but they escape and come to Cortés, says Herrera, Id.
[360] Cortés, Cartas, 71, says that he sent this message by the Cholultec
messengers.
[361] ‘É así lo asentó un escribano.’ Id., 72. ‘Otro dia vinieron muchos señores y
capitanes de Chololla.’ Gomara, Hist. Mex., 91. According to Brasseur de
Bourbourg, Cortés is already en route for Cholula when the friendly council
members appear to bring excuses and invitations. Hist. Nat. Civ., iv. 169-70.
Bernal Diaz, indeed, appears to say that the Cholultecs sent to excuse themselves
from appearing before Cortés so long as he remained in hostile territory. Hist.
Verdad., 57.
CHAPTER XIV.
SUBJUGATION OF CHOLULA.
October, 1519.
The pillage was continued for some time longer,[393] and as the
Tlascaltecs cared chiefly for fabrics, feathers, and provisions,
particularly salt, the Spaniards were allowed to secure all the gold
and trinkets they could, though these were far less in amount than
had been expected.[394] When the real work was over, Xicotencatl
appeared with twenty thousand men and tendered his services; but
Cortés could offer him only a share in the booty for his attention, and
with this he returned to Tlascala to celebrate the downfall of the
hated and boastful neighbor.[395]
The prayers of the chiefs who had been spared, supported by
the neighboring caciques, and even by the Tlascalan lords, prevailed
on Cortés to stop the pillage after the second day, and to issue a
pardon, although not till everything of value had been secured. Some
of the chiefs were thereupon sent forth to recall the fugitive
inhabitants, and with such good effect that within a few days the city
was again peopled. The débris and gore being removed, the streets
speedily resumed their accustomed appearance, and the shops and
markets were busy as before, though blackened ruins and desolated
homes long remained a testimony of the fearful blow.[396] Impressed
no less by the supposed divine penetration of the white conquerors
than by their irresistible prowess and terrible revenge, the natives
were only too ready to kiss with veneration the hand red with the
blood of their kindred. To this they were also impelled by finding that
the Spaniards not only allowed no sacrifice of captives, but ordered
the Tlascaltecs to release the prisoners they had hoped to carry into
slavery. This was a most trying requirement to the allies, but at the
instance of Maxixcatzin and other lords they obeyed in so far as to
restore the greater proportion of the thousands who had been
secured.
The intervention of the Tlascaltec lords and chiefs in behalf of
the Cholultecs tended to promote a more friendly feeling between
the two peoples, particularly since the one had been satiated with
revenue and the other humbled, and Cortés took advantage of this to
formally reconcile them. Whatever may have been their sincerity in
the matter, they certainly found no opportunity to renew their feud.
The captain-general having fallen, the people, with Cortés’
approval, chose a successor from the ranks of the friendly chiefs.
[397] Cortés assured them of his goodwill and protection so long as
they remained the loyal subjects they now promised to be, and he
hoped that nothing would occur hereafter to mar their friendly
intercourse. He explained to them the mysteries of his faith, and its
superiority over the superstitious worship of the idols which had
played them false during the late conflict, counselling them to cast
aside such images, and let their place be occupied by the redeeming
emblems of Christianity. The terrified natives could only promise
obedience, and hasten to aid in erecting crosses, but the idols
nevertheless retained their places. Cortés was quite prepared to take
advantage of his power as conqueror to compel the acceptance of
his doctrines by the now humbled people, but Padre Olmedo
representing the futility of enforced conversion, he contented himself
with breaking the sacrificial cages and forbidding the offering of
human victims. As it was, idolatry had suffered a heavy blow in this
terrible chastisement of the holy city, rich as she was in her
sanctuaries and profound in her devotion. The gods had proved
powerless! Although a number of temples were speedily restored to
their worship, the great pyramid was never again to be graced by
pagan rites. Twice had this temple shared in the destruction of the
city, only to rise more beautiful than ever in its delusive attractions;
now a simple stone cross stood upon the summit, erected by Cortés
to guard the site on behalf of the church which was there to rise a
few years later. This was dedicated to the Vírgen de los Remedios,
whose image is said to have been left in the city by her conquerors.
[398]
FOOTNOTES
[362] ‘Hiço sacrificar treynta muchachos el dia que se partieron.’ Oviedo, iii. 497.
[363] Estimated by Cortés at around 100,000. Others say he was offered 10,000
to 20,000 men.
[364] This is the figure deduced from later references. ‘Quedaron en mi compañía
hasta cinco ó seis mil.’ Cortés, Cartas, 72. Dismissing the 100,000 with presents,
he retained only 3000. ‘Por no ponerse en manos de gente barbara.’ Herrera, dec.
ii. lib. vii. cap. i. ‘Six thousand warriors,’ says Ixtlilxochitl, Hist. Chich., 294. He
gives the names of their chiefs, which differ wholly from those mentioned in
Camargo, Hist. Tlax., 160. ‘Fueron tãbien con el muchos mercaderes a rescatar
sal y mantas.’ Gomara, Hist. Mex., 91.
[365] Cartas, 74-5. ‘En el tiempo de la guerra salian en campo ochenta ó noventa
mill hombres de guerra.’ Oviedo, iii. 498. ‘Ultra triginta millia familiarum capiebat.’
Las Casas, Regio. Ind. Devastat., 26. ‘Parecio ... en el assiento, y prospetiua a
Valladolid.’ Herrera, dec. ii. lib. vii. cap. i.
[368] Chimalpain, Hist. Conq., 100, 107-8. For history and description of city and
temples, see Native Races, ii.-v.
[371] ‘Les dieron aquella noche a cada vno vn gallipauo.’ Gomara, Hist. Mex., 92.
[372] ‘Lo que traian era agua, y leña,’ says Bernal Diaz, Hist. Verdad., 58.
[373] ‘Do Muteczuma estaba habia mucho número de leones é tigres é otras
fieras, é que cada que Muteczuma quirie las hacie soltar, é bastaban para
comernos é despedazarnos.’ Tapia, Rel., in Icazbalceta, Col. Doc., ii. 574;
Gomara, Hist. Mex., 92.
[374] Cortés told them to wait, for he would start for Mexico on the following day,
and they promised to do so, says Bernal Diaz, Hist. Verdad., 58.
[375] On his entry into the city Cortés also observed suspicious features. ‘Algunas
calles de la ciudad tapiadas, y muchas piedras en todas las azoteas.’ Cartas, 72.
[376] ‘Hermano de otro moço que traia la vieja que la acompañaua.’ Bernal Diaz,
Hist. Verdad., 59. This is probably the young man who, according to Peter Martyr,
reveals the plot to Aguilar. A ‘Cempoal maiden’ was also warned by a Cholultec
woman, dec. v. cap. ii.
[377] ‘Dieron al capitan-general vn atambor de oro.’ Gomara, Hist. Mex., 92. This
official was the husband of the old woman. Bernal Diaz, Hist. Verdad., 59.
[378] ‘Auian de quedar veinte de nosotros para sacrificar á los idolos de Cholula.’
Bernal Diaz, Hist. Verdad., 59. Others say half the captives.
[379] Marina won them over. Id. ‘Dos que andauan muy solicitos.’ Herrera, dec. ii.
lib. vii. cap. i. Brasseur de Bourbourg supposes that the friendly chiefs were those
who gave the first intimation of the plot, Hist. Nat. Civ., iv. 174, and it is not unlikely
that they did warn the Spaniards.
[380] Oviedo regards the Cholultecs as having rebelled against Montezuma, iii.
498. But they stood rather in the position of allies. See Native Races, v. Bernal
Diaz assumes that half the Aztec troops were admitted.
[381] ‘Los Mexicanos ... trataron con los Señores de los Tres Barrios.’
Torquemada, i. 438. Herrera has been even more explicit, and Bernal Diaz
confirms this in several places, without specifying the number. ‘Otros barrios, que
no se hallaron en las traiciones.’ Hist. Verdad., 60.
[382] Three years old, half males, half females. Herrera, dec. ii. lib. vii. cap. ii.
Oviedo supposes the females to be young virgins, iii. 498. Bernal Diaz says five
children and two other persons.
[383] Most authors, following Gomara and Herrera, assume that only carriers were
asked for, but Diaz writes warriors, and correctly, no doubt, since it could not be
Cortés’ plan or desire to wreak vengeance on helpless carriers, but rather on the
very men who proposed to attack him. According to Tapia, followed by Gomara,
Cortés upbraids the lords for lying and plotting, but they assure him of their loyalty.
Rel., in Icazbalceta, Col. Doc., ii. 575. It is not likely that he would have roused
suspicion by such language.
[385] Picked warriors were brought, pretending to be slaves and carriers. Tapia,
Rel., in Icazbalceta, Col. Doc., ii. 575. ‘Cõ hamacas para lleuar los Españoles.’
Gomara, Hist. Mex., 93.
[386] According to Bernal Diaz the envoys are told of this on the preceding
evening, and are thereupon placed under guard. Hist. Verdad., 59.
[387] Tapia states that most of the lords and chiefs whom Cortés addressed were
killed. Rel., in Icazbalceta, Col. Doc., ii. 575. ‘Some of them,’ say Ixtlilxochitl and
Gomara, while Clavigero, Brasseur de Bourbourg, and others suppose that all
these leaders were pardoned, which is not likely, since so many less guilty men
fell. ‘El que solia mãdar, fue vno de los que murieron en el patio.’ Bernal Diaz,
Hist. Verdad., 60. He intimates that the real carriers were allowed to leave the
court, the warriors alone being detained for slaughter. The two friendly priests
were sent home to be out of harm’s way. This leads to the supposition that all the
rest of the leading men fell. ‘Los otros señores naturales todos murieron.’ Oviedo,
iii. 499.
[390] Camargo, Hist. Tlax., 163-4; Torquemada, i. 440. ‘Se dejaron allí quemar.’
Tapia, Rel., in Icazbalceta, Col. Doc., ii. 576.
[391] Cortés, Cartas, 73-4; Gomara, Hist. Mex., 94; 6000 and more within two
hours. Ixtlilxochitl, Hist. Chich., 294. Las Casas lets him first kill 6000 unarmed
carriers and then proceed to devastate the city. Regio. Ind. Devastat., 27.
[392] ‘Eché toda la gente fuera de la ciudad por muchas partes della.’ Cortés,
Cartas, 74. The statement of Bernal Diaz that the friendly priests were sent home,
to be out of harm’s way, shows also that parts of the city were respected. See
notes 17 and 23. ‘El marques mandaba que se guardasen de no matar mujeres ni
niños.’ Tapia, Rel., in Icazbalceta, Col. Doc., ii. 576.
[393] For two days, says Tapia, Id., and Bernal Diaz intimates that it ended with
the second day. Hist. Verdad., 60.
[394] ‘Tomaron los Castellanos el oro, y pluma, aũque se halló poco.’ Herrera,
dec. ii. lib. vii. cap. ii. ‘Ovo mucho despojo de oro é plata,’ says Oviedo, iii. 499,
probably because he knew Cholula to be rich; but a great deal of private treasure
at least must have been taken out of the city when the women were sent away.
The Tlascaltecs carried off 20,000 captives, he adds.
[395] Herrera, ubi sup. Oviedo allows a reinforcement of 40,000 Tlascaltecs to join
in the massacre and pillage, iii. 498, and Bernal Diaz, Hist. Verdad., 60, says the
late comers joined in the pillage on the second day. The Tlascaltecs brought the
Spaniards food, of which they had fallen short. Ixtlilxochitl, Hist. Chich., 295.
[396] A very similar massacre and raid was perpetrated by the Chichimec-Toltecs
at the close of the thirteenth century. Native Races, v. 484-7.
[397] Gomara, Hist. Mex., 95. Finding that the brother of the deceased was,
according to custom, entitled to the office, Cortés appointed him. Bernal Diaz, Hist.
Verdad., 60. Oviedo intimates that one governor was chosen to take the place of
all the other ruling men. iii. 499.
[399] Spanish chroniclers as a rule approve the deed as necessary and just, either
in tacit or open comment, and a few devout missionaries, who have assumed the
rank of Indian apostles, are the only ones to take exception. Chief among these
stands Las Casas, as might be expected from his sympathy with Velazquez, and
from his character as Indian protector. He condemns it in the most unmeasured
terms as a base murder of innocent and defenceless people, committed merely
with a view to spread terror. Six thousand carriers, he writes, were shut up in a
court and put to the sword, while the many discovered alive on the following days
were thrust through and through. The chiefs of the city and neighborhood, to the
number of over 100, were chained together to a circle of poles and burned alive,
and the king, who fled with 30 or 40 followers to a temple, met the same fate
there. While the soldiers were butchering and roasting the captives, ‘eorum
Capitaneum summa lætitia perfusum in hunc cantum prorupisse:
Las Casas, Regio. Ind. Devastat., 26-8. A number of finely executed copper
plates are appended to illustrate these deeds.
Bernal Diaz expresses himself hotly against this version, and states that
several of the first Franciscans who came to Mexico held an investigation at
Cholula of the massacre. After examining the leaders, and other persons who had
witnessed it, they came to the conclusion that the story of the conquerors was
true, and that the slaughter was a well merited punishment for a plot which
involved the lives of Cortés’ soldiers, and would, if successful, have stayed the
conquest for God and the king. Diaz had heard the pious Motolinia say that
although he grieved over the deed, yet, being done, it was best so, since it
exposed the lies and wickedness of the idols. Hist. Verdad., 61. The Franciscans
did not probably care to weigh carefully the value of testimony from new converts
given before a tribunal composed of their religious and political masters, nor were
they likely to favor a Dominican friar like Las Casas when the interest of their