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LHNga - Chapter 1. Raw Food Material Properties - Water and Polyssacharides - SBFT-HUST
LHNga - Chapter 1. Raw Food Material Properties - Water and Polyssacharides - SBFT-HUST
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WATER IN FOOD
• All foods contain at least some water
• Free water
• Held inside cells
• Maintains properties of free water
• May be removed
• Bound water
(Physicochemical bound water: Hydrogen bond,
electrostatic bond
Chemically bound water: covalent bond )
• Is part of molecule structure
• Reduced mobility
• Does not retain properties of free water
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Food moisture
1. Wet basic (wb) ADSORPTION EQUILIBRIUM
2. Dry basic (db)
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KELVIN EQUATION
Surfaces with porous structure contain voids that promote transport of water by capillary adsorption.
Capillary adsorption occurs when voids in the cellular structure are of the size to hold water in liquid form by
forces of surface tension.
SORPTION
ISOTHERM
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LANGMUIR MODEL
FREUNDLICH
MODEL
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BET MODEL
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OTHER MODELS
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1. Monossacharides
2. Oligosacchardes
WHERE WE CAN 3. Polysaccharides
FIND ➢Starch
➢Cellulose
CARBOHYDRATE CLASSIFICATION ➢Pectin
➢Hydrocolloid
• Guar and locust bean gums
• Xanthan
• Carageenans
• Algins
• Gum arabic
➢Dietary fiber/ fiber
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ISOMERS
MONOSACCHARIDES
Can not be hydrolysed
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OLIGOS ACCHARIDES
DIS ACCHARIDES
• Sucrose
• Oligo –few (1 vài) • Maltose
• Contain 2-10 monosaccharide
• Isomaltose
molecules
• Lactose
• Glycoside linkage
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SACCHAROSE
LACTOSE
(in Milk)
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LACTOSE INTOLERANCE
MALTOSE
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ISOMALTOSE
G l ucono-delta-lactone
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SORBITOL
GLYCEROL
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GLYCEMIC INDEX
SWEETNESS FACTORS
• GI ≤ 55: low.
• GI = 56- 69: medium.
• GI > 70: high
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POLYSACCHARIDES
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Pectin
Chitin
Xen lu lo za
Agar Lu o n g Ho n g Nga Asso c.P ro f.Dr- Han o i Un i . o f Sci . an d Te ch . Lu o n g Ho n g Nga Asso c.P ro f.Dr- Han o i Un i . o f Sci . an d Te ch .
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Agar
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Monosaccharide
properties • P roperties
• Solublize in water
• Isomerization
• Water absorption
• Form glycoside bonds
• Formation of a pyranose hemiacetal ring
Disaccharides • Crystalise
from
• Caramenlisation
• Interconversion
• Oxidation to aldonic acid and
aldonolactone
• Be oxidized
• Be reduced
• Non-enzyme browning
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Coversion in H +
C 12H22O11 + H2O →C 6H12O6 +
C 6H12O6
SUCROSE glucose fructose
• pH >6 → sản phẩm màu không
– Chemical mong muốn
properties Decomposed in alkaline
Caramenlization
L u o n g Ho n g Ng a As s o c .Pro f.Dr- Ha n o i Un i . o f Sc i . a n d
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2 - Properties of Starch
2.1 - Structure
• The most common native starches are corn (maize),
rice, wheat, potato, tapioca (cassava) and waxy maize. Amylose Amylopectin
- Glucose units are linked in a linear way
• Except for waxy maize, these starches generally with α(1→4) glycosidic bonds - Glucose units are linked in a linear way
contain from 15-27% amylose. with α(1→4) glycosidic bonds.
Starches
units
the source - It’s only soluble in hot water.
• High amylose starches contain more than 30% - Reacts with iodine => blue-black color
amylose and have quite different properties. They: - Reacts with iodine => blue-p urple
- The number of repeated glucose subunits color
• Are difficult to gelatinise > 100° C (n) is usually in the range of 300 to 3000, - Amylopectin is highly branched, being
• Can form films and fibres but can be many thousands formed of 2,000 to 200,000 glucose
units
Have more helical structure - may entrap fatty
acids – retards
granule swelling
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Starch gelatinizarion
PROPERTIES OF STARCH Starch granules → heat → water absorbing
→hydrating and swelling → breaking down
2.2 – Physical - S tarch becomes soluble in
hydrogen bonds and other bonds → diffuse →
w ater when heated.
Solubility gelatinization.
- Th e g ranules swell and
Gelatinized starch solution:
Water binding capacity / b u rst, the semi-crystalline
- Clarity
retention s tructure is lost and the
- Viscosity
s maller amylose molecules
Swelling Text - Consistency
s tart leaching out of the
- Volume increase
GelatinizationText granule, forming a network
th at holds water and
Starch granule (27 o C) Heat (40 o C) Swell (5 0 o C)
Viscosity Text i n creasing the mixture's
v i scosity.
- Th is process is called
Text
s tarch gelatinization
Gelatinize (70 -90 o C) Completely
Granule break down (65 o C)
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2 - Properties of Starch
STARCH 2.3 – Chemical
RETROGRADATION
Hydrolysis
- Hydrolysis of starches by acid (H+) or
enzymes.
- The enzymes that break down or
hydrolyze starch into the constituent
sugars are known as amylases…
D e x trinization
- If starch is subjected to dry heat, it
breaks down to form pyrodextrins(a
brown color), in a process known as
dextrinization.
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2.3 – Chemical
- The Iodine test is used to test for the
C h e mical tests presence of Starch.
- Iodine solution ( iodine dissolved in an
aqueous solution of potassium iodide) reacts
with starch producing a dark blue color.
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NOODLE
PREPARATION
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PUFFING AB ILITY
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APPLICATION
IN FOOD
INDUSTRY CELLULOSE
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• Odourless, colourless
• Cellulose CELLULOSE • Beta glucoside linkage
• Fruits and vegetable: 1-3% (peel)
PROPERTIES • Hydrophilic properties
• Cereal: 1-3% • Can not dissolve in water
• Hdrolyse to glucose by acid or enzyme
• Nuts: 5-23,5%
• Linear molecules
• Roots: 1-3% • Contains lost of –OH → self assemble to form
microfibril structure→ chắc, dai
• Meat, fish, egg, milk: <0,7%
Australia department of health
http://apjcn.nhri.org.tw/server/info/books-
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phds/books/foodfacts/html/data/data2c.html
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DIETARY FIBER
CELLULOSE
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CELLULOSE IN FOOD
PECTIN
• Fiber supplement
• Thickening/ emulsifying agent
• Calorie reducer
• Anti-caking agent
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TYPE O F HM pectin.
WHAT IS PECTIN PECTIN • The most common type of pectin.
(BASED O N • Usually labeled as either “rapid -set” or “slow-set.” based on
time and temp. to set
APPLICATIO N) • Extracted from citrus fruit peels. Rapid-set pectin takes a
higher temperature and less time to set, while slow-set
pectin takes a lower temperature and more time.
• HM pectin needs sugar and very specific acid levels in order
to firm up → for fruit preserves, jams, and jellies.
• The dominant component • Rapid-set pectin → suspension → for jams and
of pectin is a linear chain preserves (suspension is essentially the fruit morsels
of galacturonic acid in that hang, suspended, in the viscous jam).
which a proportion of the • Slow-set pectin → do not for suspension → for smooth
carboxyl acid groups are jelly
present as methylesters
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SOURCE OF PECTIN
ROLE OF PECTIN
• Important constituent on fruits
• Gelling agent
• Stablizers (For fruit opalescent or cloudy
juice)
• Thickening agent
• Can be hydrolyzed into smaller part
• Food fiber
• Structurizing agent
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PROPERTIES OF PECTIN • Thickening agent: Due to relatively low viscosities. However, pectin is
applied to drinks and fruit preparations because of its good mouthfeel and
• Gelling flavor release
• Thickening • Reactivity with protein: forming stable networks with protein→ stabilizer of
• React with protein acidified protein drinks and desserts in order to prevent protein coagulation,
and improver of various types of bread and dough in order to strengthen and
• Acid resistant stabilize network
• Acid resistant: pectin shows remarkable stability at acidic condition
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GELATION
PPROPERTIES OF AGAR PROCESS
• Solubility??? • The gelling portion of agar-agar has
a double helical structure.
• Double helices aggregate to form a
three-dimensional structure
framework which holds the water
molecules within the interstices of
the framework. Thus, thermo-
reversible gels are formed.
• The gelling property of agar-agar is
due to the three equatorial hydrogen
atoms on the 3,6-anhydro-L-
galactose residues, which constrain
the molecule to form a helix. The
interaction of the helixes causes the
formation of the gel
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AGAR APPLICATION
BIOTECHNOLOGY (PLANT TISSUE CULTURE FRUIT JUICE DAIRY PRODUCTS JAM AND BAKERY
CULTURE MEDIA (MICROBILOGY) PHARMACEUTICALS
CRICKET FARMING
MEAT & HAM
SOFT CANDY DENTISTRY
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CARRAGEENAN
• A family of linear sulphated polysaccharides (M~500-700) that are
extracted from red edible seaweeds.
CARRAGEENAN • Found in 1842-1862
• made up of repeating galactose units and 3,6 anhydrogalactose (3,6-
AG), both sulfated and nonsulfated. The units are joined by alternating
α-1,3 and β-1,4 glycosidic linkage
• Carrageenan consisted of D- Galactoze (17 – 31%), little L- Galactose.
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TYPE OF CARRAGEENAN
- Reduction in alkaline solution
❑ Kappa carra ge enan: polym er of D-ga lactose-4-sunlfate
- Precipitation
and 3,6 -anhydro D-galactose, consisted of 25% sulfate and - Swelling
34% 3,6-anhdro D-galactose linkage.
- Gelation
❑ Iota carrag e enan: Simil ar to Kappa- exc ept 3,6-anhydro PROPERTIES OF - Hydrolysis
D-galactose is sulf ated at C2. Consisted of 32 % sulfa te CARRAGEENAN - Viscosity
and 30% 3,6-anhdro D-galactose linkage. - Combine with protein
❑ Lambda c arrag e enan: most of monomers ar e D-g ala ctose- - Combine with starch
2-sunlfate (linkage at 1,3) and D-g al actose-2 ,6-disulfate . - Emulsion properties
Consisted of 35% sulf ate and without 3,6-anhdro D -
galactose linkage.
•
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❑ There the linkage between cation in protein and sulfate group (bearin g negative charge) of
carrageenan . If thereis any metal anion → m0re linkage .
CHITIN
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APPLICATION OF CHITOSAN
• Food additives
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