Textbook Magnetic Properties of Paramagnetic Compounds Magnetic Susceptibility Data Part 3 1St Edition R T Pardasani Ebook All Chapter PDF

Magnetic Properties of Paramagnetic
Compounds Magnetic Susceptibility

Data Part 3 1st Edition R. T. Pardasani
Visit to download the full and correct content document:
https://textbookfull.com/product/magnetic-properties-of-paramagnetic-compounds-ma
gnetic-susceptibility-data-part-3-1st-edition-r-t-pardasani/
More products digital (pdf, epub, mobi) instant
download maybe you interests ...
Magnetic Properties of Paramagnetic Compounds Magnetic

Susceptibility Data Part 4 1st Edition R. T. Pardasani
https://textbookfull.com/product/magnetic-properties-of-
paramagnetic-compounds-magnetic-susceptibility-data-part-4-1st-
edition-r-t-pardasani/


Advances in magnetic materials : processing,

properties, and performance 1st Edition Zhang
https://textbookfull.com/product/advances-in-magnetic-materials-
processing-properties-and-performance-1st-edition-zhang/
Magnetic Resonance Brain Imaging Modeling and Data
Analysis Using R Jörg Polzehl
https://textbookfull.com/product/magnetic-resonance-brain-
imaging-modeling-and-data-analysis-using-r-jorg-polzehl/
Fundamentals and applications of magnetic materials 1st

Edition Krishnan
https://textbookfull.com/product/fundamentals-and-applications-
of-magnetic-materials-1st-edition-krishnan/
Rare earth and transition metal doping of semiconductor

materials synthesis magnetic properties and room
temperature spintronics 1st Edition Dierolf
https://textbookfull.com/product/rare-earth-and-transition-metal-
doping-of-semiconductor-materials-synthesis-magnetic-properties-
and-room-temperature-spintronics-1st-edition-dierolf/
Nuclear Magnetic Resonance Vasudevan Ramesh
https://textbookfull.com/product/nuclear-magnetic-resonance-
vasudevan-ramesh/
Magnetic Monopole Noise Ritika Dusad
https://textbookfull.com/product/magnetic-monopole-noise-ritika-
dusad/
New
Series
Numerical Data
and Functional Relationships
in Science and Technology
GROUP II VOLUME 31
Molecules
and
Radicals
Magnetic
Properties of
Paramagnetic
Compounds
SUBVOLUME C
Magnetic Susceptibility Data
Part 3
MATERIALS.SPRINGER.COM
123
Landolt-Bo€rnstein: Numerical Data and Functional
Relationships in Science and Technology – New Series
Group II: Molecules and Radicals
Volume 31C
Landolt-B€ornstein
Numerical Data and Functional Relationships
in Science and Technology
New Series
Units and Fundamental Constants in Physics and Chemistry
Elementary Particles, Nuclei and Atoms (Group I)

(Formerly: Nuclear and Particle Physics)
Molecules and Radicals (Group II)

(Formerly: Atomic and Molecular Physics)
Condensed Matter (Group III)

(Formerly: Solid State Physics)
Physical Chemistry (Group IV)

(Formerly: Macroscopic Properties of Matter)
Geophysics (Group V)
Astronomy and Astrophysics (Group VI)
Biophysics (Group VII)
Advanced Materials and Technologies (Group VIII)
Some of the group names have been changed to provide a better description of their contents.
A. Gupta
Editor
Magnetic Properties of
Paramagnetic Compounds
Subvolume C
Magnetic Susceptibility Data – Part 3
R. T. Pardasani, P. Pardasani
Authors
Editor
A. Gupta
Department of Chemistry
University of Delhi
Delhi, India
Authors
R. T. Pardasani P. Pardasani
Department of Chemistry Department of Chemistry
School of Chemical Sciences and University of Rajasthan
Pharmacy, Central University of Jaipur, India
Rajasthan
Bandar Sindri, Ajmer, India
ISSN 1615-1852 ISSN 1616-9530 (electronic)

ISBN 978-3-662-49200-0 ISBN 978-3-662-49202-4 (eBook)
https://doi.org/10.1007/978-3-662-49202-4
Library of Congress Control Number: 2015940003
© Springer-Verlag Berlin Heidelberg 2016

This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned,
speci cally the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on micro lms or in any
other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or
dissimilar methodology now known or hereafter developed.
The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the
absence of a speci c statement, that such names are exempt from the relevant protective laws and regulations and therefore free for
general use.
The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and
accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, express or implied, with respect
to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to
jurisdictional claims in published maps and institutional af liations.
Printed on acid-free paper
This Springer imprint is published by Springer Nature

The registered company is Springer-Verlag GmbH, DE
The registered company address is: Heidelberger Platz 3, 14197 Berlin, Germany
Preface
In continuation to our efforts to update the magnetic susceptibility data of paramagnetic compounds, a new
Volume II/31C is presented herewith covering literature partly from 1991 to 1995. Since most of the
researchers these days consult the literature online, a new pattern is being introduced with effect from this
volume. All the magnetic properties of each individual substance are listed as a single document which is
self-explainable and allowing search in respect of substance name, synonyms, common vocabulary, and
even structure. It is hoped that a new pattern will facilitate greater accessibility of magnetic data and
enhance the use of Landolt-B€ornstein.
The editor wishes to express her thanks to the authors R. T. Pardasani and Pushpa Pardasani for this
excellent volume. The encouraging support of Dr. Wolfgang Finger from Springer is gratefully acknowl-
edged.
New Delhi Archana Gupta

June 2013
v
Contents
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Magnetic properties of di-μ-hydroxo-bis(bipyridyl)dicopper(II) sulphate pentahydrate . . . . . 11
Magnetic properties of bis{copper(II)} complex of ascidiacyclamide . . . . . . . . . . . . . . . . . . . . 13
Magnetic properties of dafone chlorocuprate complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Magnetic properties of a mixed valence copper (I, II) phosphate . . . . . . . . . . . . . . . . . . . . . . . 17
Magnetic properties of copper(II) porphyrin п-cation radical . . . . . . . . . . . . . . . . . . . . . . . . . 19
Magnetic properties of di-μ-hydroxo-bis(1, 10-phenanthroline)dicopper(II) sulphate
pentahydrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Magnetic properties of di-μ-hydroxo-bis(N, N, N0 , N0 -tetramethylethylenediamine)
dicopper(II) nitrate trihydrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Magnetic properties of dinuclear copper(II) complex of Schiff base derived from 2,
6-diformyl-4-methylphenol and 1-aminoethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
Magnetic properties of polymeric, two dimensional μ, 2, 20 -bipyrimidine, μ-oxalato
bridged and μ-chloro-bridged copper(II) complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
0
Magnetic properties of copper(II) complex of N, N -bis(2-cyanoethyl)-5, 7-dioxo-1, 4, 8,
11-tetraazacyclotetradecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
Magnetic properties of π-cation radical of Cu(II) porphyrin . . . . . . . . . . . . . . . . . . . . . . . . . . 31
6-diformyl-4-methylphenol and 1, 2-diaminoethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
6-diformyl-4-methylphenol and 1, 3-diaminopropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Magnetic properties of copper(II) methylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Magnetic properties of copper(II) ethylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
Magnetic properties of copper(II) phenylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
Magnetic properties of α-copper(II) methylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
Magnetic properties of α-copper(II) ethylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
Magnetic properties of α-copper(II) phenylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Magnetic properties of β-copper(II) methylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
Magnetic properties of trimetallic(Cu3) oxomethylphosphonate dehydrate . . . . . . . . . . . . . . . 53
Magnetic properties of Bis[(μ-nitrato-O)bis(nitrato)bis(μ-pyridazine)(pyridazine)
copper(II)]copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
Magnetic properties of (nitrato)(nitrato-O, O’)tris(pyridazine)copper(II) . . . . . . . . . . . . . . . . 57
Magnetic properties of bis(nitrato)tetrakis(pyridazine)copper(II) . . . . . . . . . . . . . . . . . . . . . . 59
vii
viii Contents
Magnetic properties of (nitrato)tetrakis(pyridazine)copper(II)nitrate . . . . . . . . . . . . . . . . . . . 61

Magnetic properties of copper oxide arsenate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Magnetic properties of anhydrous β-copper(II) formate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Magnetic properties of anhydrous α-copper(II) formate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
Magnetic properties of linear trinuclear Cu(II) complex derived from acyclic hexadentate
Schiff base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Magnetic properties of dinuclear imidazole bridged copper(II) complex of singly
condensed Schiff base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
Magnetic properties of dinuclear imidazole bridged copper(II) complex of
non-symmetrical Schiff base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
Magnetic properties of dinuclear copper(II) acetate complex of macrocyclic ligand . . . . . . . . 75
Magnetic properties of tetranuclear copper(II) acetate complex of macrocyclic ligand . . . . . . 77
Magnetic properties of mononuclear copper(II) complex of macrocyclic ligand . . . . . . . . . . . 79
Magnetic properties of mononuclear copper(II) complex of methylated macrocyclic
ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
Magnetic properties of oximato-bridged asymmetric dinuclear copper(II) complex with
a Cu(II)-I bond . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83
Magnetic properties of copper(II) hydrogenselenite . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Magnetic properties of copper(II) hydrogenselenite aqua complex . . . . . . . . . . . . . . . . . . . . . 88
Magnetic properties of copper(II) hydrogenselenite nitrate complex . . . . . . . . . . . . . . . . . . . . 91
Magnetic properties of copper(II) manganese(II) heterobimetallic hydrogenselenite . . . . . . . . 94
Magnetic properties of copper(II) cobalt(II) heterobimetallic hydrogenselenite . . . . . . . . . . . . 97
Magnetic properties of copper(II) nickel(II) heterobimetallic hydrogenselenite . . . . . . . . . . . . 100
Magnetic properties of copper(II) copper(II) homobimetallic hydrogenselenite . . . . . . . . . . . . 103
Magnetic properties of copper(II) zinc(II) heterobimetallic hydrogenselenite . . . . . . . . . . . . . 105
Magnetic properties of binuclear copper(II) complex of a macrocyclic ligand derived from
pyridine-N-oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
Magnetic properties of aqua(L-aspartato)(2,20 -bipyridine)copper(II) trihydrate . . . . . . . . . . . 109
Magnetic properties of diethylenetriamine-bis(tetracyano-quinodimethanido) copper(II)
complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111
Magnetic properties of binuclear copper(II) complex of binucleating ligand 2,
6-diformyl- 4-methylphenoldi(benzoylhydrazone) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
Magnetic properties of copper hexafluoroacetylacetonate complex with
nitroxide-4-amido-2, 2-dimethyl-5, 5-dimethoxy-3-imidazoline-1-oxyl . . . . . . . . . . . . . . . . . . . 115
Magnetic properties of copper(II) chloride complex with 1, 2, 4-triazole . . . . . . . . . . . . . . . . . 117
Magnetic properties of copper(II) bromide complex with 1, 2, 4-triazole . . . . . . . . . . . . . . . . . 119
Magnetic properties of copper(II) chloride complex with 1, 2, 4-triazole . . . . . . . . . . . . . . . . . 121
Contents ix
Magnetic properties of copper(II) bromide complex with 1, 2, 4-triazole . . . . . . . . . . . . . . . . . 124

Magnetic properties of copper(II) complex of 2-aminopyrimidine . . . . . . . . . . . . . . . . . . . . . . 126
Magnetic properties of binuclear copper(II) complex of macrocyclic aza-amido ligand . . . . . . 128
Magnetic properties of copper(II)-praseodymium(III) complex of 2, 6-bis[(dimethylamino)
methyl]-4-methylphenolato ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131
Magnetic properties of tetranuclear copper(II) complex of 2, 6-bis[(dimethylamino)
methyl]-4-methylphenol ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
Magnetic properties of trinuclear pyridazine-bridged Cu3(II) complex . . . . . . . . . . . . . . . . . . 135
Magnetic properties of trinuclear pyridazine-bridged Cu2Ni complex . . . . . . . . . . . . . . . . . . . 137
Magnetic properties of Cu(II) complex with pyridazinecarboxamide ligand . . . . . . . . . . . . . . 139
Magnetic properties of heterodinuclear iron(III)-Cu(II) complex with Schiff base and
acetylacetone ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
Magnetic properties of copper(II) squarate tetrahydrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Magnetic properties of bis[μ-chloro-dichlorobis{2, 6-bis(4-amino-2-thiabutyl)}
4-methylphenolato-(N, N1, S, S1-μ-O)dicopper(II)-μ-Cl] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
Magnetic properties of bis[2, 6-diacetylpyridine-bis(10 - phthalazinylhydrazonato)
copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148
Magnetic properties of copper(II) chloride adduct of undeprotonated 2,
6-diacetylpyridine-bis(10 -phthalazinylhydrazone) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150
Magnetic properties of copper(II) chloride adduct of monodeprotonated 2,
6-diacetylpyridine-bis(10 -phthalazinylhydrazone) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152
Magnetic properties of copper(II) chloride adduct of undeprotonated 2,
6-diacetylpyridine-bis(10 -phthalazinylhydrazone) water solvate . . . . . . . . . . . . . . . . . . . . . . . . 154
Magnetic properties of copper(II) chlorate adduct of monoprotonated 2,
6-diacetylpyridine-bis(10 -phthalazinylhydrazone) water solvate . . . . . . . . . . . . . . . . . . . . . . . . 156
Magnetic properties of tetrakis{[3, 5-bis(pyridine-2-yl)-pyrazolate) (aqua)
copper(II) nitrate monohydrate} complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 158
Magnetic properties of {[3, 5-bis(pyridine-2-yl)-pyrazolate)(aqua) copper(II)] chloride} . . . . . 161
Magnetic properties of {[3, 5-bis(pyridine-2-yl)-pyrazolate)(aqua) copper(II)] bromide} . . . . . 163
Magnetic properties of copper(II) complex of Schiff-base derived from amino acid and
ethyl-α-ketocyclopentylcarboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
Magnetic properties of copper(II) dipropylenetriamine thiocyanate nitrate complex . . . . . . . . 171
Magnetic properties of binuclear copper(II) complex of pyridoxal benzoyl hydrazine . . . . . . . 173
Magnetic properties of binuclear copper(II) complexes of pyridoxal o-hydroxy
hydrazones . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 176
x Contents
Magnetic properties of binuclear copper(II) complexes of pyridoxal picolinoyl hydrazine . . . . 178

Magnetic properties of binuclear copper(II) complexes of pyridoxal nicotinoyl
hydrazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180
Magnetic properties of binuclear copper(II) complexes of pyridoxal isonicotinoyl
hydrazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182
Magnetic properties of dimeric copper(II) acetate complex of 2-formyl
pyridinethiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
Magnetic properties of tetranuclear ternary pyrophosphato-copper(II)-2-formyl pyridine
thiosemicarbazone complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Magnetic properties of rare earth-copper molecular materials . . . . . . . . . . . . . . . . . . . . . . . . 188
Magnetic properties of rare earth-copper molecular materials . . . . . . . . . . . . . . . . . . . . . . . . 190
Magnetic properties of copper complex with di-pyridylmethane . . . . . . . . . . . . . . . . . . . . . . . 192
Magnetic properties of diaqua-bis(N-acetyl-D, L-phenylglycinato)-bis(imidazole)
copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
Magnetic properties of cis-(9, 10-dihydro-9-oxo-10-acridineacetato-μ-O) copper(II) . . . . . . . . 196
Magnetic properties of copper(II) complex of Schiff base derived from 2-[(2-aminoethyl)
thiomethyl]-benzimidazole and 2, 6-diacetylpyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Magnetic properties of imidazolate bridged dinuclear Cu(II)-Fe(III) octaethylporphyrin . . . . 201
Magnetic properties of imidazolate bridged dinuclear Cu(II)-Fe(III) porphyrin . . . . . . . . . . . 204
Magnetic properties of copper(II) chelate containing symmetric N, N0 -dimethyl-1,
2-diaminoethane and acetylacetone, with chlorate as anion . . . . . . . . . . . . . . . . . . . . . . . . . . . 206
Magnetic properties of mixed ligand copper(II) chelate containing N, N-dimethyl-1,
2-diaminoethane and acetylacetone, with chlorate as counter anion . . . . . . . . . . . . . . . . . . . . . 208
Magnetic properties of copper(II) chelate containing N, N-dimethyl-1, 2-diaminoethane
and 3-cyano-2, 4-pentanedione with hexafluorophosphate as anion . . . . . . . . . . . . . . . . . . . . . 210
Magnetic properties of copper(II) chelate containing N, N-dimethyl-1, 2-diaminoethane,
3-cyano-2, 4-pentanedione and water with tetrafluoroborate anion . . . . . . . . . . . . . . . . . . . . . 212
Magnetic properties of copper(II) chelate containing N, N-dimethyl-1, 2-diaminoethane,
3-cyano-2, 4-pentanedione and water with perchlorate anion . . . . . . . . . . . . . . . . . . . . . . . . . . 214
2-diaminoethane and 3-cyano-2, 4-pentanedione with azide anion . . . . . . . . . . . . . . . . . . . . . . 216
2-diaminoethane, 3-cyano-2, 4-pentanedione and o-nitrite . . . . . . . . . . . . . . . . . . . . . . . . . . . . 218
2-diaminoethane, 3-cyano-2, 4-pentanedione and thiocyanate . . . . . . . . . . . . . . . . . . . . . . . . . 220
Magnetic properties of mixed ligand copper(II) chelate containing N, N-dimethyl- 1,
2-diaminoethane, 3-cyano-2, 4-pentanedione and isocyanide . . . . . . . . . . . . . . . . . . . . . . . . . . 222
2-diaminoethane, 3-cyano-2, 4-pentanedione and fluoride . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224
2-diaminoethane, 3-cyano-2, 4-pentanedione and chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226
Contents xi

2-diaminoethane, 3-cyano-2, 4-pentanedione and bromide . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228
2-diaminoethane and 3-cyano-2, 4-pentanedione . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 230
2-diaminoethane and 3-cyano-2, 4-pentanedione with perchlorate anion . . . . . . . . . . . . . . . . . 232
Magnetic properties of copper(II) chelate containing N, N-dimethyl-1, 2-diaminoethane
and 3-cyano-2, 4-pentanedione with nitrate counterion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234
Magnetic properties of mixed ligand copper(II) chelate containing bis(N, N-dimethyl-1,
2-diaminoethane) and bis(3-cyano-2, 4-pentanedione) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236
Magnetic properties of mixed ligand copper(II) chelate containing N, N, N0 ,
N0 -tetramethyl-1, 2-diaminoethane and bis(3-cyano-2, 4-pentanedione) . . . . . . . . . . . . . . . . . . 238
Magnetic properties of mixed bridged, dinuclear copper(II) chloride complex with
dinucleating, 3, 5-bis(pyridin-2-yl)pyrazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240
Magnetic properties of mixed bridged, dinuclear copper(II) bromide complex with
dinucleating 3, 5-bis(pyridin-2-yl)pyrazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 242
3-(6-methylpyridin-2-yl)-5-(pyridin-2-yl) pyrazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244
Magnetic properties of mixed bridged, dinuclear copper(II) bromide complex with
3-(6-methylpyridin-2-yl)-5-(pyridin-2-yl)pyrazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246
dinucleating 3, 5-bis(6-methylpyridine-2-yl)pyrazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 248
Magnetic properties of dinuclear bis(μ-3-pyridin-2-yl-1, 2, 4-triazolato) copper(II)
compound containing N-methylimidazole as CO-ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 250
Magnetic properties of dinuclear bis(μ-3-pyridin-2yl-1, 2, 4-triazolato) copper(II)
compound containing pyrazole as CO-ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 252
Magnetic properties of polynuclear bis(μ-3-pyridin-2-yl-1, 2, 4-triazolato) copper(II)
compound containing 4, 40 -bipyridine as CO-ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 254
Magnetic properties of copper(II) croconate trihydrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 256
Magnetic properties of dinuclear (Cu/Cu) complex of a novel oxamide-type ligand
coordinating in the trans conformation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 258
Magnetic properties of phenolato bridged, heterodinuclear CuIIMnII dimer . . . . . . . . . . . . . . 260
Magnetic properties of oximato bridged, heterodinuclear CuIIMnII dimer . . . . . . . . . . . . . . . 262
Magnetic properties of oxamidato bridged, heterodinuclear CuIIMnII dimer . . . . . . . . . . . . . 264
Magnetic properties of dinuclear hydroxo bridged copper(II) chloride complex of
tetradentate (N4) thio-diazine ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266
Magnetic properties of dinuclear hydroxo bridged copper(II) bromide complex of
Magnetic properties of dinuclear hydroxo-bridged copper(II) nitrate complex of
Magnetic properties of binuclear fumarato-bridged bis[(N-(2-diethylamino)ethyl)-
salicylideneaminato]copper(II) complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273
xii Contents
Magnetic properties of bis(dimethyl sulfoxide) adduct of tetra-μ-formato-dicopper(II);

tetracarboxylato-bridged copper(II) dimer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275
Magnetic properties of a seven-spin cluster formed by an alkyl nitronyl nitroxide
biradical and copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 277
Magnetic properties of a pyrazine-bridged dinuclear copper(II) complex . . . . . . . . . . . . . . . . 279
Magnetic properties of a hydrogen bonded polynuclear copper(II) complex . . . . . . . . . . . . . . 281
Magnetic properties of syn-anti carboxylate-bridged dinuclear copper(II) complex . . . . . . . . . 283
Magnetic properties of μ-phthalato-bis(piperidine)Cu(II) chain complex . . . . . . . . . . . . . . . . . 285
6-diformyl-4-methylphenol and 1-aminopropane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 287
Magnetic properties of oximato bridged CuIICuII dimeric complex containing bipyridine
and aqua ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 289
Magnetic properties of oximato-bridged CuIICuII dimeric complex containing
terpyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291
Magnetic properties of oximato-bridged CuIINiII dimeric complex containing cyclam . . . . . . . 293
Magnetic properties of copper(II) complex of 2-nitroso-4-methylaniline . . . . . . . . . . . . . . . . . 295
Magnetic properties of copper(II) complex of 2-nitroso-4, 6-dimethylaniline . . . . . . . . . . . . . . 297
Magnetic properties of a 2D layered copper(II) complex with bridging trans-oxamidate
and pyrimidine ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 299
Magnetic properties of dinuclear copper(II) complex of thioether-pyridazine macrocycle . . . . 301
Magnetic properties of dinuclear copper(II) complex of thioether-pyridazine macrocycle . . . . 304
Magnetic properties of binuclear copper(II) complex of substituted methylpyrazole . . . . . . . . 306
Magnetic properties of polymeric 3, 5-dimethylpyrazolatecopper(II) . . . . . . . . . . . . . . . . . . . . 308
Magnetic properties of polymeric 4-chloro-3, 5-dimethylpyrazolate copper(II) . . . . . . . . . . . . 311
Magnetic properties of polymeric 4-bromo-3, 5-dimethylpyrazolate copper(II) . . . . . . . . . . . . 314
Magnetic properties of polymeric 3, 4, 5-trimethylpyrazolate copper(II) . . . . . . . . . . . . . . . . . 316
Magnetic properties of dinuclear copper(II, II) complex of thioether-pyridazine
(hexathiapyridazinophane) macrocycle ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318
Magnetic properties of dinuclear copper(II, I) complex of thioether-pyridazine
macrocycle ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320
Magnetic properties of dinuclear copper(II) complex of thioether-pyridazine macrocyclic
ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 322
Magnetic properties of copper(II) complex of thioether-pyridazine macrocyclic ligand . . . . . . 324
Magnetic properties of copper(II) complex of Schiff-base derived from
S-methyldithiocarbazate and glyoxal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 326
Magnetic properties of copper(II) complex of Schiff-base derived from
S-benzylthiocarbazate and glyoxal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 328
Magnetic properties of copper(II) dichloride complex of 2-acetylpyridine-3-(4-methyl)
piperazinyl-thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330
Contents xiii
Magnetic properties of copper(II) dibromide complex of 2-acetylpyridine-3-(4-methyl)

Magnetic properties of copper(II) chloride complex of 2-acetylpyridine-3-(4-methyl)
Magnetic properties of copper(II) bromide complex of 2-acetylpyridine-3-(4-methyl)
Magnetic properties of copper(II) complex of indol-3-β-acrylic acid . . . . . . . . . . . . . . . . . . . . 338
Magnetic properties of copper(II) acetate complex with piperazine . . . . . . . . . . . . . . . . . . . . . 340
Magnetic properties of copper(II) acetate complex with 1-methyl piperazine . . . . . . . . . . . . . 342
Magnetic properties of copper(II) acetate complex with
bis(piperazinemonohydrochloride) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344
Magnetic properties of copper(II) acetate complex with half mole(0.5) piperazine . . . . . . . . . . 346
Magnetic properties of copper(II) acetate complex with piperazinemonohydrochloride . . . . . 348
Magnetic properties of copper(II) acetate complex of 1-methylpiperazine . . . . . . . . . . . . . . . . 350
half-mole(0.5)-1-methylpiperazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 352
1-methylpiperazinemonohydrochloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 354
Magnetic properties of copper(II) acetate complex with half-mole(0.5)-1,
4-dimethylpiperazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 356
Magnetic properties of copper(II) acetate complex with 1,
4-dimethylpiperazinemonohydrochloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 358
Magnetic properties of copper(II) chloride complex of potassium
dihydrobis(5-nitroindolyl)borate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 360
Magnetic properties of copper(II) chloride complex of potassium
hydrotris(5-nitroindolyl)borate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 362
Magnetic properties of copper(II) chloride complex of tetrakis(5-nitroindolyl)borate . . . . . . . 364
Magnetic properties of benzoate copper(II) dioxygen complex . . . . . . . . . . . . . . . . . . . . . . . . . 366
Magnetic properties of 2-furylcarboxylatocopper(II) dioxygen complex . . . . . . . . . . . . . . . . . 367
Magnetic properties of 2-pyridylcarboxylatocopper(II) dioxygen complex . . . . . . . . . . . . . . . . 369
Magnetic properties of heterobinuclear copper(II)-Nickel(II) complex with N,
N0 -bis(2-aminopropyl)oxamide and 2, 20 -bipyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 371
Magnetic properties of heterobinuclear copper(II)-Nickel(II) complex with N,
N0 -bis(2-aminopropyl)oxamide and 1, 10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . 373
Magnetic properties of heterobinuclear copper(II)-nickel(II) complex with N,
N0 -bis(2-aminopropyl)oxamide and 5-nitro-1, 10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . 375
Magnetic properties of imidazolate-bridged copper(II) with 6-amino-1,
3- dimethyl- 5(2-carboxyphenyl)azouracil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377
Magnetic properties of imidazole-bridged dinuclear copper(II) with 1,
3-dimethyl- 5(2-carboxyphenyl)azobarbituric acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 379
xiv Contents
Magnetic properties of dimeric copper(II) complex of fluorenone thiosemicarbazonate . . . . . . 381

Magnetic properties of copper(II) complex with fluorenone thiosemicarbazone . . . . . . . . . . . . 383
Magnetic properties of copper(II) O-nitrato complex with fluorenone thiosemicarbazone . . . . 385
Magnetic properties of copper(II) sulphate complex with fluorenone thiosemicarbazone . . . . . 387
6-diformyl-4-methylphenol and 3-amino-1-propanol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 389
Magnetic properties of copper(II) chelate of 1-phenyl-4-methylpent-4-en-1, 3-dione . . . . . . . . 391
Magnetic properties of copper(II) complex of 5-(p-tolyl)-2-phenyl-6H-pyrazolo-
[1, 5-c]pyrimidine-7-thione . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 393
Magnetic properties of copper(II) complex of 5-(p-methoxyphenyl)-2-phenyl-6H-pyrazolo-
[1, 5-c]pyrimidine-7-thiones . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 395
Magnetic properties of copper(II) complex of 5, 2-diphenyl-6H-pyrazolo-[1, 5-c]
pyrimidine-7-thiones . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 397
Magnetic properties of copper(II) complex of 5-p-chlorophenyl-2-phenyl-6H-pyrazolo-
Magnetic properties of copper(II) complex of 5-p-bromophenyl-2-phenyl-6H-pyrazolo-
Magnetic properties of copper(II) complex of 2, 9-di(o-tolyl)-1, 10-phenanthroline . . . . . . . . . 403
Magnetic properties of copper(II) complex of 2, 9-di(2-methoxyphenyl)-1,
10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 405
Magnetic properties of copper(II) complex of 2, 9-di(2-ethoxyphenyl)-1,
10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 407
Magnetic properties of copper(II) complex of 2-(o-tolyl)-1,10-phenanthroline . . . . . . . . . . . . . 409
Magnetic properties of copper(II) complex of 2-(2-ethoxyphenyl)-1, 10-phenanthroline . . . . . 411
Magnetic properties of copper(II) chelate of N-(2-pyridyl) methacrylamide . . . . . . . . . . . . . . 413
Magnetic properties of copper(II) chloride complex of 2-(1-indazolyl)-pyridine . . . . . . . . . . . 415
Magnetic properties of copper(II) chloride complex of 2-(1-indazolyl)-pyrimidine . . . . . . . . . 417
Magnetic properties of dichlorotetrakis(3, 4-dicyano- 5-aminopyrazole)-copper(II) . . . . . . . . . 419
6-diformyl-4-methylphenol and aniline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 421
Magnetic properties of 2-(3, 5-dimethyl-pyrazole-1-yl) benzothiazole complex of
copper(II) chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 423
copper(II) bromide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 425
copper(II) nitrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 427
Magnetic properties of 2-(3, 5-dimethyl-pyrazole-1-yl) benzothiazole complex of copper(II)
sulphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 429
Magnetic properties of 2-(3, 5-dimethyl-pyrazole-1-yl) benzothiazole complex of copper(II)
perchlorate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 431
Contents xv
Magnetic properties of acetylacetonato derivative of mono (dizirconium-ennea-isopropoxy)

copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 433
Magnetic properties of hexafluoroacetylacetonato derivative of
mono(dizirconium-ennea-isopropoxy)copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 435
Magnetic properties of trifluoroacetylacetonato derivative of
mono(dizirconium-ennea-isopropoxy)copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 437
Magnetic properties of dimeric μ-(2, 6-dimethylphenolato)- mono(dizirconium-
ennea-isopropoxy)copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 439
Magnetic properties of dimeric μ-(3, 5-dimethylphenolato)- mono(dizirconium-
ennea-isopropoxy)copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 441
Magnetic properties of dimeric μ-(p-chlorophenolato)- mono(dizirconium-ennea-
isopropoxy)copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 443
Magnetic properties of polymeric μ-(chloro)-mono (dizirconium-ennea-methoxy)copper(II) . . . 445
Magnetic properties of dimeric μ-(chloro)-mono (dizirconium-ennea-ethoxy)copper(II) . . . . . 447
Magnetic properties of dimeric μ-(chloro)-mono (dizirconium-ennea-n-butoxy) copper(II) . . . 449
Magnetic properties of dimeric μ-(chloro)-mono (dizirconium-ennea-s-butoxy) copper(II) . . . 451
Magnetic properties of dimeric μ-(chloro)-mono (dizirconium-tris-isopropoxy-hexa-
t-butoxy) copper(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 453
Magnetic properties of acetylpyrazine-3-azabicyclo[3.2.2] nonylthiosemicarbazone
complex of copper(II) bromide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 454
Magnetic properties of acetylpyrazine-3-azabicyclo[3.2.2] nonylthiosemicarbazone
complex of copper(II) chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 456
Magnetic properties of copper(II) chloride complex of 2-acetylpyridine
4
N-(2-methylpyridinyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 458
Magnetic properties of copper(II) bromide complex of 2-acetylpyridine
4
N-(2-methylpyridinyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 460
4
N-(2-ethylpyridinyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 462
4
N-(2-ethylpyridinyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 464
4
N-methyl(2-ethylpyridinyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 466
4
N-methyl(2-ethylpyridinyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 468
Magnetic properties of copper(II) complex of N-salicylidene anthranilamide . . . . . . . . . . . . . 470
Magnetic properties of 6-nitrobenzimidazolate bridged copper(II) complex . . . . . . . . . . . . . . 472
Magnetic properties of imidazolate bridged copper(II) complex . . . . . . . . . . . . . . . . . . . . . . . 478
Magnetic properties of dinuclear copper(II) complex of Schiff base derived from
8-aminoquinoline and salicylaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 480
xvi Contents

8-aminoquinoline and 2-hydroxy-1-naphthaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 482
Magnetic properties of copper(II) complex of Schiff base derived from 8-aminoquinoline
and 2, 4-dihydroxybenzaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 484
Magnetic properties of copper(II) complex of Schiff base derived from 8-aminoquinoline
and 2, 3-dihydroxybenzaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 486
8-aminoquinoline and 5-chlorosalicylaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 488
Magnetic properties of allopurinol complex with copper(II) perchlorate . . . . . . . . . . . . . . . . . 490
Magnetic properties of complex of copper(II) with tridentate Schiff base derived by
the condensation of salicylaldehyde and furfuraldehyde with o-phenyldiamine . . . . . . . . . . . . 492
Magnetic properties of copper(II) chelate of acetoacetanilide thiosemicarbazone . . . . . . . . . . 494
Magnetic properties of copper(II) complex with acetylacetone bis(benzoyl-hydrazone) . . . . . . 496
Magnetic properties of copper(II) complex with acetylacetone
bis-(isonicotinoyl hydrazone) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 498
Magnetic properties of complex of copper(II) with Schiff base derived from
2-aminocyclopent-1-ene- 1-dithiocarboxylic acid and benzaldehyde . . . . . . . . . . . . . . . . . . . . . 500
Magnetic properties of complex of copper(II) chloride with Schiff base derived from
2-aminocyclopent-1-ene-1- dithiocarboxylic acid and salicylaldehyde . . . . . . . . . . . . . . . . . . . 502
Magnetic properties of complex of copper(II) bromide with Schiff-base derived from
2-aminocyclopent-1-enedithiocarboxylic acid and salicylaldehyde . . . . . . . . . . . . . . . . . . . . . . 504
Magnetic properties of copper(II) chloride complex of 2, 6-diacetyl-pyridinesalicylaldazine . . . . 506
Magnetic properties of copper(II) complex of 2, 6-diacetylpyridine salicylaldazine . . . . . . . . . 508
Magnetic properties of copper(II) complex of 1, 3, 8, 10, 15, 17, 22,
24-octanitrophthalocyanine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 510
Magnetic properties of copper(II) chloride complex of 1, 3-bis(aminomethyl)
cyclohexane-N, N, N’, N’-tetrakisbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 512
Magnetic properties of copper(II) perchlorate complex of 1,
3-bis-aminomethylcyclohexane-N, N, N’, N’-tetrakis-benzimidazolato-copper(II) chloride . . . . 514
Magnetic properties of copper(II) chloride complex of pyridine-2-carboxaldehyde
Schiff-base of S-methyl-β-N-(2-aminophenyl) methylenedithiocarbazate . . . . . . . . . . . . . . . . . 516
Magnetic properties of copper(II) chloride complex of 6-methyl-pyridine-2-carboxaldehyde
Magnetic properties of copper(II) nitrate complex of pyridine-2-carboxaldehyde
Magnetic properties of copper(II) bromide complex of pyridine-2-carboxaldehyde
Schiffbase of S-methyl-β-N-(2-aminophenyl)methylenedithiocarbazate . . . . . . . . . . . . . . . . . . 522
Magnetic properties of copper(II) complex with 2-pyridinone . . . . . . . . . . . . . . . . . . . . . . . . . 524
Magnetic properties of copper(II) complex with 1-hydroxy-2-pyridine-thione . . . . . . . . . . . . . 526
Magnetic properties of copper(II) complex with 2-pyridinemethane thiole-1-oxide . . . . . . . . . 528
Contents xvii
Magnetic properties of copper(II) mixed ligand complex with 2-pyridinone and

phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 530
Magnetic properties of benzoylacetoneisonicotinoylhydrazone complex of copper(II) . . . . . . . 532
Magnetic properties of copper(II) complex derived from N-isonicotinamido-N0 -
benzoylthiocarbamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 534
Magnetic properties of copper(II) complex derived from N-isonicotinamido-N0 -
Magnetic properties of complex of copper(II) chloride with tetradentate Schiff-base
ligand 1,2-bis(20 -pyridylmethyleneimino)benzene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 538
Magnetic properties of copper(II) complex of 2-benzylthio- 4-formyl-1-
p-methoxyphenylimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 540
Magnetic properties of 1, 3-pyrimidinyl(2, 4, 6-pyrimidinetrione) chelate of copper(II) . . . . . . 542
Magnetic properties of o-vanillin-isonicotinoyl hydrazine complex of copper(II) . . . . . . . . . . . 544
Magnetic properties of copper(II) complex of N, N’-bis (1-ferrocenyl-1-oxo-3-methyl)
propenylethylenediamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 546
Magnetic properties of dinuclear copper(II) acetate complex with ligand derived from
the condensation of triazolo-2, 4-pentanedione with 1, 6-diaminohexane . . . . . . . . . . . . . . . . . 548
Magnetic properties of dinuclear copper(II) chloride complex with ligand derived from
the condensation of triazolo-2, 4-pentanedione with 1, 6-diaminohexane . . . . . . . . . . . . . . . . . 550
Magnetic properties of dinuclear copper(II) acetate complex with ligand derived from
the condensation of thiazolo-2, 4-pentanedione with 1, 6-diaminohexane . . . . . . . . . . . . . . . . . 552
Magnetic properties of dinuclear copper(II) chloride complex with ligand derived from
the condensation of thiazolo-2, 4-pentanedione with 1, 6-diaminohexane . . . . . . . . . . . . . . . . . 554
Magnetic properties of praseodymium(III) complex of an 18-membered dioxatetraaza
Magnetic properties of mixed ligand complex of praseodymium(III) with
bis(phenylsulphinyl)propane and bipyridyl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 558
Magnetic properties of neodymium(III) complex of 18-membered dioxatetraaza
Magnetic properties of mixed ligand complex of neodymium(III) with
Magnetic properties of samarium(III) complex of 18-membered dioxatetraaza macrocycle
ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 564
Magnetic properties of europium(III) complex of 18-membered dioxatetraaza macrocycle
ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 566
Magnetic properties of binuclear complex of europium(II) with the bridging naphthalene
dianion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 568
Magnetic properties of binuclear complex of europium(II) with the bridging naphthalene
dianion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 569
Magnetic properties of mixed ligand complex of europium (III) with
xviii Contents
Magnetic properties of gadolinium(III)-copper(II) squarate . . . . . . . . . . . . . . . . . . . . . . . . . . 572

Magnetic properties of mixed ligand complex of gadolinium(III) with
Magnetic properties of heterodinuclear nickel(II)-gadolinium(III)-complex with an
acyclic Schiff base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 576
Magnetic properties of heterodinuclear copper(II)-gadolinium(III)-complex with an
Magnetic properties of heterotetranuclear copper(II)-gadolinium(III)-complex with an
Magnetic properties of mixed ligand complex of terbium(III) with
Magnetic properties of mixed ligand complex of holmium(III) with bis(phenylsulphinyl)
propane and bipyridyl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 584
Magnetic properties of mixed ligand complex of erbium(III) with bis(phenylsulphinyl)
propane and bipyridyl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 586
Magnetic properties of tris diazabutadiene ytterbium complex . . . . . . . . . . . . . . . . . . . . . . . . 588
Magnetic properties of mixed ligand complex of ytterbium(III) with bis(phenylsulphinyl)
propane ands bipyridyl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 590
Magnetic properties of polymeric, two-dimensional, multidecker complex of
bis(cyclopentadienyl)vanadium with naphthaleneytterbium . . . . . . . . . . . . . . . . . . . . . . . . . . . 592
Magnetic properties of uranium triiodide tetrakis (acsetonitrile) . . . . . . . . . . . . . . . . . . . . . . . 594
Magnetic properties of uranyl(VI) complex derived from N-isonicotinamido-N0 -
Magnetic properties of dichloro(phthalocyano)silicon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 597
Magnetic properties of bis(p-nitrophenoxy) (phthalocyanino)silicon . . . . . . . . . . . . . . . . . . . . 599
Magnetic properties of trimetallic lanthanum(III)-europium(III), La2-Eu complex of
12-membered tetraaza macrocycle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 601
Magnetic properties of trimetallic lanthanum(III)-gadolinium(III), La2-Gd complex of
Magnetic properties of trimetallic lanthanum(III)-terbium(III), La2-Tb complex of
Magnetic properties of trimetallic lanthanum(III)-dysprosium(III), La2-Dy complex
of 12-membered tetraaza macrocycle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 607
Magnetic properties of heterodinuclear titanium lithium chloro complex supported by
amide ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 609
Magnetic properties of heterodinuclear titanium lithium methyl complex supported by
amide ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 611
Magnetic properties of dinuclear chlorotitanium(III)derivative with bridging
μ-(dimethylsilyl)biscyclopentadienyl ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 613
Magnetic properties of trans-bis(4-picoline)tetratolylporphyrinato)- titanium(II) . . . . . . . . . . 615
Contents xix
Magnetic properties of μ-(dichloro)bis[(trimethylsilyl) benzamidinato]-N, N, N0 , N0 -

tetramethylethylenediaminetitanium(III)-lithium(I) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 617
Magnetic properties of bis[(trimethylsilyl)benzamidinato] titanium(III) borohydride . . . . . . . 619
Magnetic properties of bis[(trimethylsilyl)benzamidinato] titanium(III)-η3-allyl complex . . . . 621
Magnetic properties of trisaminopyridinatotitanium(III)complex . . . . . . . . . . . . . . . . . . . . . . 623
Magnetic properties of dimeric titanium(III) complex with chloride and tetrahydrofuran . . . 625
Magnetic properties of oxysulfide of mixed metals (Nd2Ti2) . . . . . . . . . . . . . . . . . . . . . . . . . . . 627
Magnetic properties of complex obtained by intercalation of η-cycloheptatrienyl
molybdenum into ZrS2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 629
Magnetic properties of complex obtained by intercalation of η-cycloheptatrienyl
tungeston into ZrS2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 631
Magnetic properties of hafnium(III) nitride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 633
Magnetic properties of carbonylbis(pentadienyl)vanadium(II) . . . . . . . . . . . . . . . . . . . . . . . . . 634
Magnetic properties of (triethylphosphine)bis(pentadienyl)vanadium(II) . . . . . . . . . . . . . . . . . 636
Magnetic properties of (trimethyl phosphite)bis (pentadienyl) vanadium(II) . . . . . . . . . . . . . . 638
Magnetic properties of (trimethylphosphine)bis (2, 4-dimethylpentadienyl) vanadium(II) . . . . 640
Magnetic properties of (trimethyl phosphite)bis(2, 4-dimethylpentadienyl) vanadium(II) . . . . 642
Magnetic properties of triethylphosphine adduct of half-open, cyclopentadienyl
(3-methylpentadienyl)vanadocene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 644
Magnetic properties of trimethylphosphine adduct of half-open, cyclopentadienyl
(2, 4-dimethylpentadienyl)vanadocene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 646
Magnetic properties of triphenylphosphine adduct of half-open, cyclopentadienyl
Magnetic properties of trifluorophosphine adduct of half-open, cyclopentadienyl
Magnetic properties of carbonyl adduct of half-open, cyclopentadienyl
Magnetic properties of trimethyl phosphite adduct of half-open, cyclopentadienyl
(pentadienyl)vanadocenes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 654
Magnetic properties of trimethyl phosphite adduct of half-open, cyclopentadienyl
Magnetic properties of trimethylphosphite adduct of half-open, cyclopentadienyl
Magnetic properties of 4-methyl-2, 6,7-trioxa-1-phosphabicyclo [2.2.2]octane adduct of
half-open, cyclopentadienyl(2, 4-dimethyl pentadienyl)vanadocene . . . . . . . . . . . . . . . . . . . . . 660
Magnetic properties of triphenyl phosphite adduct of half-open,
cyclopentadienyl(2, 4-dimethylpentadienyl)vanadocene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 662
Magnetic properties of t-butylcyanide adduct of half-open, cyclopentadienyl
xx Contents
Magnetic properties of t-butylcyanide adduct of half-open, 2,

4-dimethylpentadienylvanadocene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 666
Magnetic properties of binuclear hexamethyldisilazanato vanadium(III) compound . . . . . . . . 668
Magnetic properties of four membered vanadacycle ring supported by bulky silazanate . . . . . 670
Magnetic properties of pyridine adduct of four membered vanadacycle ring supported by
bulky silazanate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 672
Magnetic properties of diphenylacetylene adduct of six membered vanadacycle ring
supported by bulky silazanate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 674
Magnetic properties of bis(trimethylsilyl)lacetylene adduct of six membered vanadacycle
ring supported by bulky silazanate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 676
Magnetic properties of asymmetric dinuclear oxocitrato vanadate(IV) . . . . . . . . . . . . . . . . . . 678
Magnetic properties of hexavanadium(IV) polyoxo alkoxide anion cluster with rubidium
cation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 680
Magnetic properties of mixed valence hexavanadium (V, IV) polyoxo alkoxide anion
cluster with trimethylammonium cation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 683
Magnetic properties of a new perovskite-related vanadate with VIII/VIV ordering . . . . . . . . . . 685
Magnetic properties of oxovanadium(IV) complex with 3-salicyliden-
acetylacetonediimino-N, N-bis(anthranilic acid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 687
Magnetic properties of oxovanadium(IV) complex of Schiff-base ligand . . . . . . . . . . . . . . . . . 689
Magnetic properties of oxovanadium(IV) sulphate complex with 2, 3-dihydrazinoquinoxaline 691
Magnetic properties of mixed ligand oxovanadium(IV) complex with salicylic
acid and bipyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 693
Magnetic properties of mixed ligand oxovanadium(IV)complex with salicylic acid and 1,
10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 695
Magnetic properties of heptachlorodivanadium(III) as tetraethyl- ammonium salt . . . . . . . . . 697
Magnetic properties of trisaminopyridinatovanadium(III)complex . . . . . . . . . . . . . . . . . . . . . 699
Magnetic properties of oxovanadium(IV) complex of kojic acid . . . . . . . . . . . . . . . . . . . . . . . . 701
Magnetic properties of vanadyl(IV) complex with thioglycolic acid . . . . . . . . . . . . . . . . . . . . . 703
Magnetic properties of vanadyl(IV) complex of Schiff-base derived from anthranilic
acid and acetylacetone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 705
Magnetic properties of vanadyl(IV) complex with Schiff-base derived from anthranilic
acid and salicylaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 707
Magnetic properties of vanadyl(IV) complex with Schiff-base derived from anthranilic
acid and 5-bromo-salicylaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 709
Magnetic properties of vanadyl(IV) complex with Schiff -base derived from
anthranilic acid and 3-methoxysalicylaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 711
Magnetic properties of triclinic form of decahydrated Keggin anion . . . . . . . . . . . . . . . . . . . . 713
Magnetic properties of monoclinic form of nano-hydrated Keggin anion . . . . . . . . . . . . . . . . . 715
Magnetic properties of oxovanadiun complex with dinucleating tetraaminodiphenol . . . . . . . 717
Contents xxi
Magnetic properties of oxovanadiun complex with dinucleating tetraaminodiphenol . . . . . . . 719

Magnetic properties of dimeric vanadium(III) complex with chloride and
tetrahydrofuran . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 722
Magnetic properties of electrogenerated oxo-vanadium complex with a tridentate
ONO ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 724
Magnetic properties of electrogenerated oxo-vanadium complex with a tridentate
ONO ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 726
Magnetic properties of electrogenerated oxo-vanadium complex with azobenzene-2, 20 -diolate . . . 728
Magnetic properties of diiodo vanadium(IV) complex with a Schiff-base . . . . . . . . . . . . . . . . . 730
Magnetic properties of oxovanadium(IV) complex with a Schiff-base . . . . . . . . . . . . . . . . . . . 732
Magnetic properties of diiodo vanadium(IV) complex with a Schiff-base . . . . . . . . . . . . . . . . . 734
Magnetic properties of diiodovanadium(IV) complex with Schiff-base . . . . . . . . . . . . . . . . . . . 736
Magnetic properties of diiodovanadium(IV) complex with a Schiff-base . . . . . . . . . . . . . . . . . 738
Magnetic properties of chloro-bridged vanadium(III) complex with tetrahydrofuran . . . . . . . 740
Magnetic properties of dinuclear copper(II) complex anion with oxovanadium cation . . . . . . 743
Magnetic properties of octanuclear mixed-metal (vanadium-tungsten) cluster . . . . . . . . . . . . . 745
Magnetic properties of oxo-vanadium(IV) complex with tetradentate Schiff-base . . . . . . . . . . 747
Magnetic properties of vanadium(IV) complex with tetradentate Schiff-base as
tetrafluoroborate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 749
Magnetic properties of oxo-vanadium(IV) complex with tetradentate Schiff-base as
Magnetic properties of bis(μ-oxo) vanadium(IV) complex with tetradentate Schiff-base as
Magnetic properties of tris(μ-oxo) vanadium(IV) complex with tetradentate Schiff-base as
Magnetic properties of tris(μ-oxo) vanadium(IV) complex with tetradentate Schiff-base, as
tetraphenylborate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 759
trifluoromethanesulfonate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 761
Magnetic properties of bis(μ-oxo) vanadium(III, IV) complex with tetradentate
Schiff-base, as triiodate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 763
Magnetic properties of hexakis(acetonitrile)vanadium(II) tetraiodide . . . . . . . . . . . . . . . . . . . 765
Magnetic properties of mixed valence organic-based layered vanadium oxide . . . . . . . . . . . . . 767
Magnetic properties of arsenic rich polyoxovanadium anion . . . . . . . . . . . . . . . . . . . . . . . . . . 769
Magnetic properties of homobimetallic vanadium d1-d1 complex . . . . . . . . . . . . . . . . . . . . . . . 771
Magnetic properties of homobimetallic vanadium d1-d1 complex . . . . . . . . . . . . . . . . . . . . . . . 773
xxii Contents
Magnetic properties of homobimetallic vanadium d2-d2 complex with triyne . . . . . . . . . . . . . 775

Magnetic properties of vanadium(IV) complex with kojic acid . . . . . . . . . . . . . . . . . . . . . . . . 777
Magnetic properties of vanadyl-biguanide complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 779
Magnetic properties of vanadyl-metformin complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 781
Magnetic properties of vanadyl-phenformin complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 783
Magnetic properties of vanadyl complex with metformin and dimethylformin . . . . . . . . . . . . 785
Magnetic properties of vanadyl(IV) sulphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 787
Magnetic properties of vanadyl complex with 2-mercaptopyridine-N-oxide . . . . . . . . . . . . . . . 788
Magnetic properties of mononuclear mixed ligand complex of oxovanadium(IV) with
heterocyclic β-diketone and 2, 2’-bipyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 790
heterocyclic β-diketone and 2, 2’-bipyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 792
heterocyclic β-diketone and 1, 10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 794
heterocyclic β-diketone and 1, 10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 796
Magnetic properties of binuclear mixed ligand complex of oxovanadium(IV) with
heterocyclic β-diketone, 2, 20 -bipyridine a heterocyclic nitrogen base . . . . . . . . . . . . . . . . . . . 798
heterocyclic β-diketone 2, 2’-bipyridine and 2, 6-diaminopyridine . . . . . . . . . . . . . . . . . . . . . . 800
heterocyclic β-diketone, 2, 2’-bipyridine and m-phenylenediamine . . . . . . . . . . . . . . . . . . . . . 802
heterocyclic β-diketone, 2, 6-diaminopyridine and 2, 2’-bipyridine . . . . . . . . . . . . . . . . . . . . . 804
heterocyclic β-diketone, 1, 10-phenanthroline and m-phenylenediamine . . . . . . . . . . . . . . . . . 806
heterocyclic β-diketone, 1, 10-phenanthroline and 2, 6-diaminopyridine . . . . . . . . . . . . . . . . . 808
heterocyclic β-diketone, 1, 10-phenanthroline and m-phenylenediamine . . . . . . . . . . . . . . . . . 810
heterocyclic β-diketone, 1, 10-phenanthroline and 2, 6-diaminopyridine . . . . . . . . . . . . . . . . . 812
Magnetic properties of bis(acetylacetonato)-chloro- (4-nitrophenoxo)- vanadium(IV) . . . . . . . 814
Magnetic properties of bis(acetylacetonato)-chloro- (4-methoxyphenoxo)-vanadium(IV) . . . . . 816
Magnetic properties of bis(acetylacetonato)-chloro- {4-methyl-2,6-di(tert-butyl)phenoxo}-
vanadium(IV) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 818
Magnetic properties of bis(acetylacetonato)-bis (4-methoxyphenoxo)- vanadium(IV) . . . . . . . . 820
Magnetic properties of vanadium(IV) complex with Schiff-base ligand derived from
benzoylacetophenone and ethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 821
Contents xxiii

benzoylacetone and ethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 823
acetylacetone and ethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 825
Magnetic properties of oxovanadium(IV) complex with Schiff-base ligand derived from
benzoylacetophenone and ethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 827
benzoylacetone and ethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 829
acetylacetone and ethanolamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 831
benzoylacetophenone and o-aminophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 833
benzoylacetone and o-aminophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 835
acetylacetone and o-aminophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 837
Magnetic properties of pyridine adduct of oxovanadium(IV) complex of Schiff-base
complex derived from benzoylacetophenone and o-aminophenol . . . . . . . . . . . . . . . . . . . . . . . 839
Magnetic properties of n-pentylamine adduct of oxovanadium(IV) Schiff-base complex
derived from benzoylacetophenone and o-aminophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 841
Magnetic properties of thiophene adduct of oxovanadium(IV) Schiff-base complex
derived from benzoylacetophenone and o-aminophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 843
Magnetic properties of vanadium(III) complex of salicylaldehyde-4-phenyl
thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 845
Magnetic properties of vanadium(III) complex of salicylaldehyde-4-p-bromophenyl-
Magnetic properties of vanadium(III) complex of salicylaldehyde-4-p-chlorophenyl-
Magnetic properties of vanadium(III) complex of salicylaldehyde-4-p-tolyl-
Magnetic properties of vanadium(III) complex of 5-bromo-salicylaldehyde-p-tolyl-
Magnetic properties of vanadium(III) complex of 5-chloro-salicylaldehyde-p-tolyl-
Magnetic properties of first oxalate-bridged dinuclear CoII-VIVO complex . . . . . . . . . . . . . . . 857
Magnetic properties of first oxalate-bridged dinuclear CoII- VIVO complex . . . . . . . . . . . . . . . 859
Magnetic properties of niobium(IV) tetrachloride adduct of 7-azaindole . . . . . . . . . . . . . . . . . 861
Magnetic properties of tetrakis(hexafluoroacetylacetato) niobium(IV) . . . . . . . . . . . . . . . . . . . 863
Magnetic properties of tetrakis(acetylacetato)niobium(IV) . . . . . . . . . . . . . . . . . . . . . . . . . . . 865
Magnetic properties of niobium(IV) complex with anionic organic amides . . . . . . . . . . . . . . . 867
xxiv Contents
Magnetic properties of tetravalent niobium phenyl stabilized by anionic organic amides . . . . 869
Magnetic properties of tetravalent niobium methyl stabilized by anionic organic amides . . . . 871
Magnetic properties of tetravalent niobium enolate stabilized by anionic organic amides . . . . 873
Magnetic properties of 3-indole carboxylate complex of niobocene dichloride . . . . . . . . . . . . . 875
Magnetic properties of mononuclear tantalum(0) carbonyl compound . . . . . . . . . . . . . . . . . . 877
Magnetic properties of monomeric chromium(II) aryl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 879
Magnetic properties of monomeric pyridine adduct of chromium(II) aryl . . . . . . . . . . . . . . . . 881
Magnetic properties of dimeric chromium(II) aryl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 883
Magnetic properties of monomeric chromium(III) aryl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 885
Magnetic properties of monomeric chromium(III) aryl . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 887
Magnetic properties of polycyclophosphane complex of cyclopentadienyl chromium(I) . . . . . . 889
Magnetic properties of heteronuclear sulfide bridged chromium and rhenium containing
cluster (cis-isomer) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 890
Magnetic properties of heteronuclear sulfide bridged chromium and rhenium containing
cluster (trans-isomer) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 892
Magnetic Properties of Tetranuclear Sulfide Bridged Chromium and Rhenium Cluster
Containing Carbonyl and Nitrosyl Ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 894
Magnetic properties of triangular sulfide bridged chromium and rhenium cluster
containing carbonyl and nitrosyl ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 896
Magnetic properties of tetranuclear sulfide bridged chromium and rhenium cluster
containing carbonyl ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 898
Magnetic properties of triangular sulfide and oxothiolate bridged chromium and
rhenium cluster containing chloro, carbonyl and nitrosyl ligands . . . . . . . . . . . . . . . . . . . . . . 900
Magnetic properties of sulfide and thiolate bridged triangular cluster with CrRe2 core
Magnetic properties of sulfide and thiolate bridged triangular cluster with CrRe2 core
Magnetic properties of sulfide and thiolate bridged antiferromagnetic cluster with Cr2Re
core containing carbonyl and nitrosyl ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 906
Magnetic properties of fac(S)-tris(2-aminoethanethiolato) chromium(III) . . . . . . . . . . . . . . . . 908
Magnetic properties of S-bridged zinc bromide polynuclear complex composed of
fac-(S)-[Cr(aet)3] units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 909
Magnetic properties of S-bridged nickel bromide polynuclear complex composed of
fac-(S)-[Cr(aet)3] units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 911
Magnetic properties of S-bridged zinc nitrate polynuclear complex composed of
fac-(S)-[Cr(aet)3] units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 914
Magnetic properties of S-bridged nickel nitrate polynuclear complex composed of
fac-(S)-[Cr(aet)3] units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 915
Magnetic properties of imidodiphosphinoselenido complex of chromium(III) . . . . . . . . . . . . . 916
Contents xxv
Magnetic properties of chromium(III) complex with 5-(2-hydroxy-benzylidene)

aminobenzopyrazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 918
Magnetic properties of chromium(III) tellurolate as 1, 2-bis(dimethyl- phosphino)ethane . . . . 920
Magnetic properties of mixed ligand complex of chromium(III) picrates with isonicotinic
acid hydrazide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 922
Magnetic properties of chromium(III) complex with indan-1, 3-dione-2-isonicotinoyl
hydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 924
Magnetic properties of chromium(III) complex of monophenylbutazone . . . . . . . . . . . . . . . . . 926
Magnetic properties of chromium(III) complex with tetrasodium calix[4]arene sulphonate
(a phenolic macrocycle) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 928
Magnetic properties of chromium(III) complex with oxyphenbutazone . . . . . . . . . . . . . . . . . . 930
Magnetic properties of chromium(III) complex of bis(bismuthiol-1-yl)- borate . . . . . . . . . . . . 932
Magnetic properties of chromium(III) complex with 3-hydrazino-5, 6-diphenyl-1,
2, 4-triazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 934
Magnetic properties of chromium(III) complex with diclofenac sodium . . . . . . . . . . . . . . . . . 936
Magnetic properties of tetracyanonotrosylchromate(I) complex with 8-hydroxyquinoline . . . . 938
Magnetic properties of tetracyanonotrosylchromate(I) complex with benzothiazole . . . . . . . . 940
Magnetic properties of tetracyanonotrosylchromate(I) complex with
2-methylbenzothiazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 942
Magnetic properties of tetracyanonotrosylchromate(I) complex with imidazole . . . . . . . . . . . 944
Magnetic properties of tetracyanonotrosylchromate(I) with phenir amine maleate . . . . . . . . . 946
Magnetic properties of chromium(III) chloride complex with 1, 3-disuccinimide
(4-phenyl-5-ethoxycarbonyl-6- methylpyrimidine-2-one) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 948
Magnetic properties of polynuclear chromium(III) chloride complex with 2,
3-dihydrazinoquinoxaline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 950
Magnetic properties of Cr(III) complex of 3-(3, 5-dimethylpyrazol-1-yl)quinoxaline-2-one . . . 952
Magnetic properties of heterotetranuclear Cr2III-Fe2III complex of 1, 4, 7-trimethyl-1,
4, 7-triazacyclononane and salicylaldehyde oxime . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 954
Magnetic properties of a novel 14-membered metallamacrobicycle containing two
chromium(III) ions as part of the ring skeleton . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 956
Magnetic properties of a novel heterotetranuclear [CrIII2MnIII2(μ3-O)2]8+ core with an
ST = 0 spin ground state . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 958
Magnetic properties of 5-fluorouracil complex with Cr(III) . . . . . . . . . . . . . . . . . . . . . . . . . . . 961
Magnetic properties of mixed ligand, 5-fluorouracil and histidine complex with Cr(III) . . . . . 963
Magnetic properties of trisaminopyridinatochromium(III) complex . . . . . . . . . . . . . . . . . . . . 965
Magnetic properties of heterodinuclear copper(II)- chromium(III) complex with N,
N0 -bis(3-aminopropyl) oxamide and 2, 20 -bipyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 967
N0 -bis(3-aminopropyl) oxamide and 1, 10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . 970
xxvi Contents

N0 -bis(3-aminopropyl) oxamide and 5-nitro-1, 10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . 973
N0 -bis(3-aminopropyl) oxamide and 5-chloro-1, 10-phenanthroline . . . . . . . . . . . . . . . . . . . . . 975
Magnetic properties of 2, 20 -bipyridyl-oxalate bridged heterotrinuclear complex, NiCr2 . . . . . 977
Magnetic properties of chromium(II) methylphosphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 979
Magnetic properties of chromium(III) complex with L(-)cysteine . . . . . . . . . . . . . . . . . . . . . . 981
Magnetic properties of dinuclear chromium(III) complex with L(-)cysteine . . . . . . . . . . . . . . 983
Magnetic properties of chromium(III) complex with L(-)cystine . . . . . . . . . . . . . . . . . . . . . . . 985
Magnetic properties of dinuclear chromium(III) complex with L(-)cystine . . . . . . . . . . . . . . . 987
Magnetic properties of chromium(III) mixed ligand 5, 50 -dithiobisnitrobenzoic acid and
L(-)cysteine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 989
Magnetic properties of chromium(III) chloride complex with dibenzyldisulphide . . . . . . . . . . 991
Magnetic properties of chromium(III) complex with α-mercaptosuccinic acid . . . . . . . . . . . . 993
Magnetic properties of dinuclear chromium(III) complex with 5,
5’-dithiobisnitrobenzoic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 995
Magnetic properties of a molecular cluster compound Cr6Te8(PEt3)6 . . . . . . . . . . . . . . . . . . . 997
Magnetic properties of chromium(III) trispicolinate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 999
Magnetic properties of di-μ hydroxotetrapicolinatodichromium(III) . . . . . . . . . . . . . . . . . . . . 1001
Magnetic properties of chromium(II) complex with permethylindenyl . . . . . . . . . . . . . . . . . . 1003
Magnetic properties of chromium(III) complex with permethylindenyl . . . . . . . . . . . . . . . . . . 1005
Magnetic properties of chromium(II) diphenylamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1006
Magnetic properties of chromium(II) dicyclohexylamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1008
Magnetic properties of chromium(II) di-isopropylamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1010
Magnetic properties of tetrahydrofuran complex with chromium(II) diphenylamide . . . . . . . 1012
Magnetic properties of pyridine complex with chromium(II) diphenylamide . . . . . . . . . . . . . . 1014
Magnetic properties of tetrahydrofuran complex with chromium(II) diphenylamide . . . . . . . 1016
Magnetic properties of chromium(II) complex with phenothiazinyl and excess
tetrahydrofuran . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1018
Magnetic properties of sodium diphenylamidochromate(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . 1020
Magnetic properties of lithium diethylamidochromate(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1022
Magnetic properties of lithium diethylamidochromate(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1023
Magnetic properties of dimeric chromium(II) complex with 2-methylaminopyridine . . . . . . . 1025
Magnetic properties of dimeric chromium(II) complex with aminopyridine . . . . . . . . . . . . . . 1027
Magnetic properties of dithioxalato-bridged heterometallic chromium(III)-trinickel(II)
complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1029
Magnetic properties of binuclear bis(acetylacetonato) chromium(III) complex bridged by
imidazole-4, 5-dicarboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1032
Contents xxvii
Magnetic properties of binuclear bis(acetylacetonato) chromium(III) complex bridged by 1,

2, 3-triazole-4, 5-dicarboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1034
pyrazole 3, 5-dicarboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1036
Magnetic properties of chromium(III) aldonate complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1038
Magnetic properties of chromium(III) complex with methylhydrazine- carboxylate ligand . . . 1040
pyrazolate and hydroxide groups . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1042
Magnetic properties of dinuclear chromium(III) complex with
bis(2-diisopropylphosphinoethyl)amidolithium reagent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1044
Magnetic properties of tetra-n-butylammonium tetraisothiocyanato chromate(II)
(red-form) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1046
Magnetic properties of tetra-n-butylammonium tetraisothiocyanato chromate(II)
(blue form) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1048
Magnetic properties of half-sandwich, imidochromium(V) compound . . . . . . . . . . . . . . . . . . . 1050
Magnetic properties of half-sandwich imidochromium(V) compound . . . . . . . . . . . . . . . . . . . 1052
Magnetic properties of imidochromium(V) Schiff-base compound . . . . . . . . . . . . . . . . . . . . . . 1054
Magnetic properties of imidochromium(V) Schiff-base compound . . . . . . . . . . . . . . . . . . . . . . 1056
Magnetic properties of octanuclear mixed metal (chromium-molybdenum) cluster . . . . . . . . . 1058
Magnetic properties of octanuclear mixed-metal (chromium-tungsten) cluster . . . . . . . . . . . . 1060
Magnetic properties of octanuclear mixed-metal (Cr + Fe-Mo) cluster . . . . . . . . . . . . . . . . . . 1062
Magnetic properties of μ-oxo, tetranuclear Cr2-Mn2 complex with 1,
4, 7-triazacyclononane and salicylaldehyde oxime . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1064
Magnetic properties of pentanuclear μ-cyano CrIIINiII (radical)2 complex . . . . . . . . . . . . . . . 1067
Magnetic properties of dodecanuclear chromium(III) cage with carboxylate ligand . . . . . . . . 1069
Magnetic properties of two-dimensional, cyano-bridged Ni(II)-Cr(I) complex with 3,
10-dimethyl-1, 3, 5, 8, 10, 12-hexaazacyclotetradecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1071
Magnetic properties of tetraacetatodimolybdenum(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1074
Magnetic properties of molybdenum complex of the anticancer drug
6-mercaptopurine(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1076
Magnetic properties of molybdenum complex of the anticancer drug
6-mercaptopurine(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1078
Magnetic properties of molybdenum(V) complex with polystyrene-anchored
Schiff base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1080
Magnetic properties of oxomolybdenum(V) chloride complex of
salicylaldehydemorpholine-N-thiohydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1082
Magnetic properties of oxomolybdenum(V) chloride complex of
2-hydroxyacetophenonemorpholine- N-thiohydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1084
Magnetic properties of oxomolybdenum(V) thiocyanate complex of
salicylaldehydemorpholine-N-thiohydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1086
xxviii Contents
Magnetic properties of hydrotris(pyrazolyl)borate complex of molybdenum carbonyl . . . . . . 1088

Magnetic properties of hydrotris (pyrazolyl) borate complex of molybdenum carbonyl . . . . . 1090
Magnetic properties of cyclopentadienylmolybdenum(IV) chloride . . . . . . . . . . . . . . . . . . . . . 1092
Magnetic properties of cyclopentadienylmolybdenum(IV) bromide . . . . . . . . . . . . . . . . . . . . . 1094
Magnetic properties of cyclopentadienylmolybdenum(IV) iodide . . . . . . . . . . . . . . . . . . . . . . . 1096
Magnetic properties of trinuclear complex MoCu2 possessing a
hexathiolatomolybdenum(IV) core . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1098
Magnetic properties of triiodo molybdenum(III) complex with 1, 4, 7-trimethyl-1,
4, 7-triazacyclononane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1099
Magnetic properties of diiodo oxomolybdenum(V) complex with 1, 4, 7-trimethyl-1,
Magnetic properties of dimethoxy oxomolybdenum(V) complex with 1, 4, 7-trimethyl-1,
Magnetic properties of dinuclear mixed valent (MoV, MoVI) oxo bridged iodo
dioxomolybdenum complex with 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane . . . . . . . . . . . . . . 1105
Magnetic properties of η-cycloheptatrienyl derivative of molybdenum . . . . . . . . . . . . . . . . . . 1107
Magnetic properties of oxomolybdenum(V) complex with 2-aminocyclopent-1-ene-1-
carbodithiolate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1113
Magnetic properties of mononuclear oxomolybdenum(V) complex with N-ethyl-
2-aminocyclopent-1-ene-1- carbodithiolate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1115
Magnetic properties of mononuclear oxomolybdenum(V) complex with N-propyl-
Magnetic properties of mononuclear oxomolybdenum(V) complex with N-butyl-
Magnetic properties of (η-cyclopentadienyl)imido derivative of molybdenum . . . . . . . . . . . . . 1121
Magnetic properties of mononuclear, 15-electron molybdenum complex with 1,
2-bis(diisopropylphosphino) ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1123
Magnetic properties of mononuclear, 16-electron molybdenum complex with 1,
2-bis(diisopropylphosphino) ethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1125
Magnetic properties of oxomolybdenum(V) complex with hydrazone derived from
6-methyl-4-hydroxy-2- hydrozinopyrimidine and salicylaldehyde . . . . . . . . . . . . . . . . . . . . . . 1127
6-methyl-4-hydroxy-2- hydrazinopyrimidine and 5-methyl- salicylaldehyde . . . . . . . . . . . . . . 1129
6-methyl-4-hydroxy-2- hydrazinopyrimidine and 5-chloro-salicylaldehyde . . . . . . . . . . . . . . . 1131
6-methyl-4-hydroxy-2- hydrazinopyrimidine and 5-bromo- salicylaldehyde . . . . . . . . . . . . . . . 1133
Contents xxix

6-methyl-4-hydroxy-2- hydrazinopyrimidine and 3-methoxysalicylaldehyde . . . . . . . . . . . . . 1135
6-methyl-4-hydroxy-2- hydrazinopyrimidine and 2-hydroxy-1-naphthaldehyde . . . . . . . . . . . . 1137
Magnetic properties of bimetallic, phosphido-bridged complex of tungsten . . . . . . . . . . . . . . . 1139
Magnetic properties of mer-trichlorotris(tetrahydrofuran) tungsten(III) . . . . . . . . . . . . . . . . . 1141
Magnetic properties of trinuclear complex WCu2 possessing a hexathiolatotungsten(II) . . . . . 1143
Magnetic properties of (2, 4-dimethylpentadienyl)bis (cyclopentadienyl)- dimanganese(II) . . . 1144
Magnetic properties of dinuclear manganese complex of N, N0 -ethylenebis(acetylacetimine) . . . 1146
Magnetic properties of methyl manganese Schiff base complex . . . . . . . . . . . . . . . . . . . . . . . . 1148
Magnetic properties of hexamesityltrimanganese(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1150
Magnetic properties of dimeric phenylmanganese(II) ion-pair with tetraphenylborate . . . . . . 1153
Magnetic properties of monomeric mesitylmanganese(II) ion-pair with tetraphenylborate . . . 1156
Magnetic properties of manganese(II) complex of isoorotic acid . . . . . . . . . . . . . . . . . . . . . . . 1158
Magnetic properties of manganese(II) complex of nitronyl nitroxide carboxylic acid . . . . . . . 1160
Magnetic properties dinuclearmanganese(II) complex with 2, 20 -bipyrimidine and
thiocyanate ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1162
Magnetic properties dinuclearmanganese(II) complex with 2, 20 -bipyrimidine and
selenocyanate ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1164
Magnetic properties of dimer of trinuclear manganese complex . . . . . . . . . . . . . . . . . . . . . . . 1166
Magnetic properties of octadecanuclear manganese(II) complex . . . . . . . . . . . . . . . . . . . . . . . 1168
Magnetic properties of diaqua-bis(1, 3, 6, 7-tetramethylpteridine-2,
4-(1H, 3H)-dione-O4, N5)manganese(II) perchlorate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1170
Magnetic properties of manganese(II) tellurostannates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1172
Magnetic properties of 2-(4-chlorophenyl)-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-
3-oxide-bis (hexafluoroacetylacetonato)manganese(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1174
Magnetic properties of hexa[2-(4-methylphenyl)-4, 4, 5, 5-tetramethyl imidazoline-
1-oxyl-3-oxide-bis (hexafluoroacetylacetonato)manganese(II)] . . . . . . . . . . . . . . . . . . . . . . . . . 1176
Magnetic properties of di[1-hydroxo-2-furfural-4, 4, 5, 5-tetramethyl-4,
5-dihydro-1H-imidazoline-bis (hexafluoroacetylacetonato)manganese(II)] . . . . . . . . . . . . . . . . 1178
Magnetic properties of di(2-furfural-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-3-oxide)-bis
(hexafluoroacetylacetonato)manganese(II) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1180
Magnetic properties of dinuclear copper(II)-manganese(II) complex of a phenol-based
macrocycle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1182
Magnetic properties of one-dimensional azide-bridged manganese(III) uniform chain . . . . . . 1184
Magnetic properties of tris{[bis(triphenylphospho)amide} hexacyano- manganate(III) . . . . . . 1186
Magnetic properties of oxo-centered trinuclear manganese complex . . . . . . . . . . . . . . . . . . . . 1188
Magnetic properties of oxo-centered trinuclear manganese complex . . . . . . . . . . . . . . . . . . . . 1191
Another random document with
no related content on Scribd:
fashion, now and then raising itself or lifting the prothorax in a
stealthy quiet manner, perhaps to judge accurately of its distance;
when near enough, with one swift dart the victim is secured. The
prey is held firmly in the formidable trap formed by the anterior leg,
and is thus brought near the mouth. The Mantis usually commences
its feast by taking off some portions of the head of its wretched
victim, and displays an absolute indifference to its struggling or
kicking; the mandibles having seized a portion of the food, the legs
holding it move away, thus leaving a fragment in the mouth. Portions
only of a captured Insect are consumed, much being cast away; and
Mr. Potts states that he has seen one of these voracious creatures
kill and devour parts of fourteen small flies within a very brief space
of time. This voracity and waste of animal food is very remarkable
when we recollect that many Insects have such perfect powers of
assimilation that during their whole period of growth they only
consume a mass of food—and that vegetable—but little larger in size
than the bulk they themselves attain. This fact is well known in the
case of Bruchus, Caryoborus, and other seed-feeding Insects.
Burmeister has stated good grounds for believing that some of the
larger Mantidae do not confine themselves to Insect diet, but attack
and devour small Vertebrates.[177] He has given a circumstantial
account of a case at Buenos Ayres, where a small bird was secured
by the wingless female of a large Mantis, which had commenced
devouring its head when the observer took possession of the
creature and its booty. Dubois states[178] that when a decapitated,
but living, Mantis was suspending itself to a roll of drapery by its four
posterior legs, a person could detach with the fingers the left anterior
leg (of the four) and the right posterior, or conversely the left
posterior and right anterior, without the interference producing any
action on the part of the creature; but if one of the other legs was
also interfered with, which would necessarily have changed the
position of the body, then immediately one of the two unoccupied
legs was placed by the creature in a proper position to assure its
stability. This reflex action altogether resembled in appearance a
conscious action, and was as effectually performed.
The combination in Mantidae of voracious and destructive instincts
with helpless and inert attitudes gives rise to the idea that these
latter are adopted for the purpose of deceiving the living prey and of
thus more easily obtaining the means of subsistence. It appears,
however, more probable that the helpless attitudes have no such
origin, but are due to the structure and form of the creature. The front
legs being wonderfully well formed for raptorial purposes, have no
capacity for locomotion or for supporting the Insect in the usual
manner, so that the body has to be borne by the hinder two pairs of
legs; at the same time the raptorial pair of limbs—which, it will be
recollected, are of great size and attached to the anterior part of an
unusually long prothorax—have to be held in such a position as will
not derange the equilibrium maintained by the posterior part of the
body; moreover, these large raptorial legs are entirely exserted, and
have no trace of any articulatory cavity that might act as a
mechanical aid to their support. Thus they could not be held
extended without great muscular exhaustion; hence we can well
believe that the sedentary and helpless attitudes of the creature are
not the results of any guile.
A Mantis has been recorded as bearing a close resemblance to a

Phasmid of the genus Bacillus and having only small front legs; it
was suggested by Bates[179] that the Mantis would probably be
found to feed on the Bacillus. Though the case is of considerable
interest, no further information about it has been obtained.
Fig. 141.—Mantoida luteola Westw., male. Santarem.
The simplest forms of the family are found in the groups

Amorphoscelides and Orthoderides. From our figure of one of these
(Fig. 141, Mantoida luteola ♂), it will be seen that the peculiarities of
the family can scarcely be detected, the raptorial legs being very little
developed and the prothorax short. The sexes, too, differ but little in
these simple forms. Most of them are very rare in collections, but
Wood-Mason states[180] that Amorphoscelis annulicornis is
frequently found about Calcutta on the trunks of trees, to the bark of
which it is so similar that it is only discovered with difficulty. In its
rapid movements it resembles the cockroaches or Machilis, more
than it does the more differentiated forms of its own group.
In the genus Pyrgomantis (Fig. 142, P. singularis, female) the male

has the tegmina and wings of normal size, while in the female they
are rudimentary.
Fig. 142.—Pyrgomantis singularis, female. S. Africa. (After Westwood.)
Fig. 143.—Outline of Chaeradodis cancellata ♀, nymph. (After Wood-

Mason.)
The variety of shape and external appearance in this family is very

great; de Saussure considers it to be a mimetic group. In certain
species some parts of the body—more especially the tegmina—have
very much the appearance of foliage, and usually in such cases this
appearance is confined to the female, the males in this family
having, as we have said, the organs of flight more transparent and
colourless; in the former sex the alar organs, when present, are
frequently but little adapted for flying. In some species the prothorax
is expanded at the sides (Fig. 135, Deroplatys sarawaca; and Fig.
143, Choeradodis cancellata), and in such cases the outline of the
natural thorax—if we may use such an expression—may be detected
occupying the middle of the unusual expansion. The European
Mantis religiosa varies much in colour; in some examples the
tegmina are leaf-green, while in others they are brown or gray. There
is some evidence extant making it probable that in some species the
colour of an individual changes at different times—Colonel Bowker
saying of Harpax ocellata that it "beats the Chameleon hollow in
changing colour."
Some of the species of the old genus Eremiaphila (Fig. 144) are of
very unusual form. De Saussure considers that some species of this
genus are more highly modified than any other animals for
maintaining their existence in desert regions. They are said to be
found in places where no vegetation exists, and to assimilate in
appearance with the sandy soil, the species varying in colour, so that
the individuals agree in tint with the soil on which they dwell. These
Insects are referred to the group Orthoderides, and have a short
prothorax, the alar organs being unsuited for flight. What they live on
is not actually known; although other Insects are the natural food of
Mantids, it is said that these desert-frequenting species occur in
spots where no other Insect life is known to exist. Lefebvre[181] met
with these Eremiaphilas in the desert between the Nile and the
Northern Oasis, El Bahryeh, but was quite unable to discover their
mode of subsistence. These Insects are very rare in collections, and
the information we possess about them is very meagre.
Fig. 144.—Eremiaphila turcica. (After Westwood.)

Mr. Graham Kerr found on the Pilcomayo river a species of Mantidae
living on branches of trees amongst lichens, which it so exactly
resembled that it was only detected by the movement of a limb; it
was accompanied by a Phaneropterid grasshopper, which bore a
similar resemblance to the lichens. One of the rarest and most
remarkable forms of Mantidae is the genus Toxodera, in which the
eyes project outwards as pointed cones (Fig. 145). These Insects
offer an interesting problem for study, since we are entirely ignorant
about them. Brunner places the Toxoderae in his tribe Harpagides,
but with the remark that "these Insects of antediluvian shapes differ
essentially from all other Mantidae."
Wood-Mason informs us[182] that the young of Hymenopus bicornis

beautifully simulate blossoms of different colours. And it has been
stated by Dr. Wallace, on the authority of a communication made to
him by Sir Charles Dilke, that a small Mantis found in Java exactly
resembles a pink Orchis-flower, and this species "was not only said
to attract Insects, but even the kind of Insects (butterflies) which it
allures and devours was mentioned." We do not know of what
species or genus this Insect may be, but Hymenopus bicornis is a
peculiar form of the tribe Harpagides, and has, together with its
younger state, been figured long ago by Caspar Stoll in his quaint
and interesting old book.[183] Though it has very peculiar foliaceous
expansions on the two hinder pairs of legs, these dilatations are very
different from those seen in the curious Gongylus gongylodes, the
female of which we figure (Fig. 146). This latter, according to the
information we shall quote, is also a "floral simulator." Specimens of
G. gongylodes were shown to the members of the Asiatic Society of
Bengal in 1877 by Dr. J. Anderson,[184] who at the same gave some
information about them which we shall reproduce in full, because,
incomplete as it is, it is apparently almost the sole piece of definite
information we possess as to this curious Insect, or any of its
congeners:—
Fig. 145.—Toxodera denticulata, male. Java. (After Serville.)
"These Insects all came from the same locality, having been
forwarded to Mr. Buckland by Mr. Larymore of the Central Jail at
Midnapur. Mr. Larymore had procured them from the neighbouring
country district, where Santál women and children had hunted them
out and brought them in, hanging on branches or twigs of a bush,
somewhat like a wild plum-tree. They are also said to be found upon
rose-bushes, and in connexion with this it was observed that, in
Midnapur, they were known as rose-leaf Insects, from the
circumstance that when the Insect is more developed and furnished
with wings, the foliaceous appendages are said greatly to increase in
size, and exactly to resemble rose-leaves. Dr. Anderson, however,
was disposed to think that more than one species might probably
occur in the Midnapur district, and that these Insects with the larger
foliaceous expansions might be distinct from the species now before
the Society.
Fig. 146.—Gongylus gongylodes, female. East India.
"Mr. Buckland had made over these Insects to Dr. Anderson, and
since that time they have been regularly fed upon house-flies and
grasshoppers; the latter, however, appear to be rather too strong for
them, and they therefore prefer the flies. They have been tried with
small fragments of plaintain and custard-apple, which they not only
eat, but the juice of which they seem to suck with considerable
avidity, Dr. Anderson, however, thought that it was the moisture of
these fruits that was the chief attraction to these Insects, for the
entire character of their organisation indicated a raptorial habit.
"Dr. Anderson went on to say that he had succeeded in identifying

the three larger Insects by means of a single dried specimen in the
Indian Museum, which, however, was fully mature and provided with
wings. These remarkable Insects proved to be the pupae of a
peculiar species of Mantis which was known to Aldrovandus, who
figured it more than a century and a half before the first appearance
of the Systema Naturae of Linnaeus, to whom it was known as
Gryllus gongylodes, and also as Mantis gongylodes; and since the
time of Aldrovandus it had been figured in a variety of works on
Natural History, but apparently in every instance from mature, and
seemingly dried specimens, so that the colours of the Insect during
life had never been correctly described.
"So much by way of introduction to these remarkable pupal
Mantises, the recognised scientific name of which is Gongylus
gongylodes L.
"The reason which induced Dr. Anderson to bring them to the notice
of the Society had now to be pointed out. On looking at the Insects
from above, they did not exhibit any very striking features beyond the
leaf-like expansion of the prothorax and the foliaceous appendages
to the limbs, both of which, like the upper surface of the Insect, are
coloured green, but on turning to the under surface the aspect is
entirely different. The leaf-like expansion of the prothorax; instead of
being green, is a clear, pale lavender-violet, with a faint pink bloom
along the edges of the leaf, so that this portion of the Insect has the
exact appearance of the corolla of a plant, a floral simulation which is
perfected by the presence of a dark, blackish brown spot in the
centre, over the prothorax, and which mimics the opening to the tube
of a corolla. A favourite position of this Insect is to hang head
downwards among a mass of green foliage, and, when it does so, it
generally remains almost motionless, but, at intervals, evinces a
swaying movement as of a flower touched by a gentle breeze; and
while in this attitude, with its fore-limbs banded violet and black, and
drawn up in front of the centre of the corolla, the simulation of a
papilionaceous flower is complete. The object of the bright colouring
of the under surface of the prothoracic expansion is evident, its
purpose being to act as a decoy to Insects, which, mistaking it for a
corolla, fly directly into the expectant, serrated, sabre-like, raptorial
arms of the simulator. It is no new fact that many Insects resemble
the leaves of plants and trees, and that they manifest forms and
colours which serve to protect them in the struggle for existence, but
so far as Dr. Anderson had ascertained, this was the first recorded
instance of an Insect simulating the corolla of a flower for the evident
purpose of attracting Insects towards it for its sustenance. It is even
more remarkable than this, for it is a localised adaptation for such a
purpose, a portion of the Insect being so modified in form and colour
that the appearance of the corolla of a plant is produced, in
conjunction with the remainder of the long attenuated prothorax,
which at a distance resembles the flower stem; the anterior limbs
when in repose even adding to and heightening the deception."
That we should have no more precise information as to a large

Insect of such remarkable habits and appearance, and one that has
been known to naturalists for upwards of three centuries, is a matter
for regret. Careful observation as to the habits, food, and variation of
these floral simulators, and as to whether they seek for spots
specially suitable to their coloration, would be of great interest. A
European congener of this Insect, Empusa pauperata, has small
foliaceous expansions on the legs, but its habits have not been
noticed in detail.
The very curious Insect represented in Fig. 147, Stenophylla

cornigera, is a member of the tribe Vatides; the form of the cerci at
the end of the body is very peculiar. This extremely rare, if not
absolutely unique, Insect is a native of the interior of Brazil.
Dufour has recorded that Mantis religiosa possesses the power of

producing a mournful sound by rubbing the extremity of the body
against the wings; it is stated that a hissing sound is produced by
other species, and Wood-Mason has suggested[185] that a special
structure exists on the tegmina for the purpose.
There are probably about 600 species of Mantidae known; they are
distributed over all the warmer parts of the earth, but there are none
in the cooler regions. Europe possesses some twelve or fourteen
species, most of them confined to the Mediterranean sub-region; a
single species, Mantis religiosa, is frequently found in Central
France, and has been recorded as occurring as far north as Havre.
Although no species is a native of Britain, it is not difficult to keep
them alive here. Denny records[186] that an egg-case of a Mantis
was sent from Australia to England, and that the hatching of the
eggs was completed after its arrival. The young fed readily on flies,
and we are informed that in the neighbourhood of Melbourne, where
this Mantis is plentiful, specimens are placed by the citizens on the
window-blinds of their houses, so that the rooms may be cleared
from flies by means of the indefatigable voracity of the Mantis.
Fig. 147.—Stenophylla cornigera. Brazil. (After Westwood.)
The geological record as to Mantidae is very meagre and

unsatisfactory. The genus Mantis is said to occur in amber, and Heer
has referred to the same genus an ill-preserved fossil from the upper
Miocene beds of Central Europe; a fragment of a hind wing found in
the Jurassic strata of Siberia has been assigned to the family; and
until recently Lithomantis from the Carboniferous beds of Scotland
was considered to belong to Mantidae. Scudder, however, has
rejected it therefrom, placing it in the Neuropteroid division of
Palaeodictyoptera, and Brongniart, adding another species to the
genus from the Carboniferous strata in France, proposed to treat the
two as a distinct family, which he called Palaeomantidae.[187] This
naturalist has, however, since renewed his study[188] of these
Insects, has become convinced that they have no relations with
existing Mantidae, and has consequently removed them to the family
Platypterides in the Order Neuroptera.
Six tribes of Mantidae are recognised by Brunner and de Saussure.
Table of the tribes of Mantidae:—
1. Anterior tibiae with the outer edge unarmed beneath or only furnished with
very minute tubercles. (Pronotum not longer than the anterior coxae.)
Tribe 1. Amorphoscelides. (Fig. 141, Mantoidea luteola.)
1′. Anterior tibiae with the outer edge spinose beneath.
2. Anterior femora having the inner edge armed beneath with equal
spines, or with spines in which only the alternate are smaller.
Antennae of the male simple, rarely unipectinate.
3. Tibiae and also the intermediate and hind femora even above.
4. Legs and body with no lobe-like processes. (Antennae simple in
each sex.)
5. Pronotum not forming any dilatation above the insertion of the
coxae, its lateral margins straight or (in the genus Choeradodis)
strongly dilated with the anterior margin not rounded. Tribe 2.
Orthoderides. (Fig. 142, Pyrgomantis; Fig. 143, Choeradodis;
Fig. 144, Eremiaphila turcica.)
5′. Pronotum dilated above the insertion of the coxae, there with the
lateral margins broadened in a round manner, the anterior
margin rounded. Tribe 3. Mantides. (Fig. 140, Iris oratoria.)
4′. Legs or body furnished with lobes. (Posterior femora or segments
of the body with lobes, or vertex of the head conically prolonged.)
Tribe 4. Harpagides. (Fig. 136, Harpax variegatus; Fig. 135,
Deroplatys sarawaca.)
3′. Tibiae as well as the intermediate and hind femora carinate above.
(Pronotum elongate, with the posterior part, behind the transverse
groove, three times as long as the anterior part.) Tribe 5. Vatides.
(Fig. 147, Stenophylla cornigera.)
2′. Anterior femora beneath, with the inner edge armed between the longer
teeth with shorter teeth, usually three in number. Antennae of the
male bipectinate. (Vertex conically prolonged.) Tribe 6. Empusides.
(Fig. 146, Gongylus gongylodes.)
CHAPTER XI
ORTHOPTERA CONTINUED—PHASMIDAE—WALKING-LEAVES—STICK-
INSECTS
Fam. V. Phasmidae—Stick and Leaf Insects.

Head exserted; prothorax small, not elongate; mesothorax very
elongate; the six legs differing but little from one another, the
front pair not raptorial, the hind pair not saltatorial. The cerci of
the abdomen not jointed, consisting of only one piece; the tarsi
five-jointed. Tegmina usually small, or entirely absent, even
when the wings are present and ample. The sexes frequently
very dissimilar. Absence of alar organs frequent.
These Insects are amongst the most curious of natural objects. They
are frequently of large size, some attaining 9 inches in length (Fig.
162, Palophus centaurus, one-half natural length). Their variety of
form could scarcely be surpassed; their resemblance to products of
the vegetable kingdom is frequently very great: some of the more
linear species (Fig. 148, Lonchodes nematodes) look like sticks or
stems of grass; some have a moss-like appearance, while others
resemble pieces of lichen-covered bark. The members of the tribe
Phylliides are leaf-like. A certain number of other Phasmids are
covered with strong spines, like thorns (Fig. 149). The plant-like
appearance is greatest in the female sex. When there is a difference
between the two sexes as to the organs of flight, these are more fully
developed in the male.
Fig. 148.—Lonchodes nematodes. Malay Archipelago. (After

Westwood.)
The antennae are usually many-jointed, but the number of joints
varies from 8 to more than 100; the head is exserted; the eyes are
more or less prominent; ocelli are present in some cases. The
prothorax is always small, and it is a remarkable fact that it
undergoes but little elongation even in those species that are most
linear and elongate in form (see Fig. 148, Lonchodes nematodes),
and that have the meso- and metathoraces extremely long; it is very
simple in structure, consisting apparently merely of a dorsal and of a
sternal plate, nearly the whole of the side being occupied by the
large space in which the coxae are inserted; the edges of the
pronotum are not free. The mesothorax is frequently six times as
long as the prothorax, though in the leaf-like and a few other forms it
does not possess this great extension; still it is always of large size
relatively to the other two thoracic segments. This is peculiar
inasmuch as in other groups where the mesothorax is relatively large
there are powerful mesothoracic wings; whereas the Phasmidae are
remarkable for the obsolescence of the mesothoracic alar
appendages. The middle legs and the tegmina or elytra, when
present, are attached only to the posterior part of the mesothorax;
the notum and the sternum are separated by two narrow slips on
each side, the epimeron and episternum. The metathorax is formed
like the mesothorax, except that the posterior part of the dorsal
surface is considered to consist of the first ventral segment
consolidated with the posterior part of the metanotum, the two being
distinct enough in the winged forms. The hind body or abdomen is
elongated except in the Phylliides; it consists of ten dorsal plates; the
first frequently looks like a portion of the metanotum, and is treated
as really such by Westwood, who describes the abdomen as
consisting of nine segments. The flat apical appendages are
attached behind the tenth dorsal plate. The ventral plates are similar
to the dorsal in arrangement, except that in the female the eighth
plate forms a sort of spoon-like or gutter-like process to assist in
carrying or depositing the eggs, and that the two following segments
are concealed by it, and are sometimes of more delicate texture. The
legs vary greatly in the details of their shape: the coxae are short,
oval, or round, never large; the trochanter is small; the front femora
often have the basal part narrower than the apical, and they are
frequently so formed that they can be stretched out in front of the
head, concealing its sides and outline and entirely encasing the
antennae. There is an arolium or cushion between the claws of the
five-jointed tarsi. The front legs are frequently longer than the others.
Only a very slight study has been made of the alar organs of
Phasmidae; but according to Redtenbacher and Brauer, they differ
greatly from those of Blattidae and Mantidae, inasmuch as the costal
vein is placed not on the actual margin of the wing but in the field
thereof, and in this respect they more resemble the Orthoptera
saltatoria.
Very little information exists as to the internal anatomy of the

Phasmidae. Many years ago a memoir of a fragmentary and
discursive nature was published on the subject by J. Müller,[189] but
his conclusions require confirmation; the nervous system, according
to his account, which refers to Arumatia ferula, has the anterior
ganglia small, the supra-oesophageal ganglion being apparently not
larger than those forming the ventral chain.
Fig. 149.—Heteropteryx grayi, male. Borneo. One-half natural size.
Joly's more recent memoir on the anatomy of Phyllium

crurifolium[190] is also meagre; he states that the nervous system
resembles that of the locusts (Acridiidae), though there are at least
ten pairs of ganglia—one supra-, one infra-oesophageal, three
thoracic, and five abdominal. He found no salivary glands; the
Malpighian tubules are slender, elongate, and very numerous. The
tracheal system has no air-vesicles. He found no distinction of crop
and proventriculus, but the true stomach appears to consist of two
different parts, the anterior being remarkably uneven externally,
though destitute of coeca, while on the posterior part there are
peculiar vermiform processes. There are eighteen or twenty tubes in
each ovary.
Fig. 150.—Aschipasma catadromus, female. Sumatra. Natural size.

(After Westwood.)
When the young Insect is in the egg, ready for emergence, the
meso- and meta-thorax are not remarkably elongate, so that the
femora are not very far apart, but by the time the creature has fairly
emerged from the prison of its embryonic life the thoracic segments
have attained their usual proportions; much expansion of the body
takes place as the Insect leaves the egg, so that it appears a marvel
how it could have been contained therein; this expansion affects the
parts of the body unequally.
The records as to the post-embryonic development of Phasmidae

are very scanty, but indicate great differences in the length of time
occupied by it. Bacillus patellifer is said to moult several times,
Diapheromera femorata only twice. This latter species becomes full
grown in six weeks, while, according to Murray,[191] Phyllium scythe
required fifteen or sixteen months for growth, and did not moult until
ten months after hatching; the number of ecdyses in the case of the
Phyllium was three. At each change of skin an immediate increase in
size, similar to that we have noticed as occurring on leaving the egg,
takes place; each limb on being freed becoming about a fourth
longer and larger than the corresponding part of the envelope from
which it has just been withdrawn. After the second moult of Phyllium
the tegmina and wings made their appearance, but remained of very
small size until after the third moult, when they suddenly shot out to
their full size; they came out of little cases about a quarter of an inch
long, and in the course of a few minutes attained their full size of
about two and a half inches of length. In the apterous species the
difference between the young and adults in external characters is
very slight.
Fig. 151.—Ceroys saevissima. Brazil. (After Westwood.)
Phasmidae are very sensitive to cold; both in North America and

Australia their lives are terminated by the occurrence of frost. They
are all vegetable feeders, the cannibalism that has been attributed to
them by several writers being probably imaginary. They are,
however, excessively voracious, so that a pair will destroy a great
quantity of foliage; they are consequently in some parts of the world
classed amongst injurious Insects. In Fiji and the Friendly Islands,
Lopaphus cocophagus eats the cocoa-nut foliage and causes a
scarcity of food, so that it becomes a matter of necessity to destroy
these Insects. One writer has gone so far as to attribute the
occurrence of cannibal habits amongst the inhabitants of some of
these islands to the want of food caused by the ravages of this
Insect. Some, if not all, of the Phasmidae have the habit of ejecting a
stinking fluid, that is said to be very acrid, and occasionally, when it
strikes the eye, to cause blindness; this liquid comes from glands
placed in the thorax. Some Phasmidae are much relished as food by
birds; Diapheromera femorata is sucked by several bugs as well as
eaten by birds, and another species is recorded to have harboured
Ichneumon-flies in its body without suffering any apparent
inconvenience from their presence or from their emergence.
Notwithstanding the great amount of food they consume and their
want of activity, they produce comparatively few eggs. From twelve
to twenty or thirty is frequently mentioned as about the number, but
in the case of Diapheromera femorata Riley speaks of upwards of
one hundred. These eggs are not deposited in any careful way, but
are discharged at random, simply dropping from the female; the
noise caused by the dropping of the eggs of Diapheromera femorata
from the trees on which the Insects are feeding to the ground is said
to resemble the pattering of raindrops. The eggs of this species often
remain till the second year before they hatch. The eggs in the
Phasmidae generally are of a most remarkable nature, and nearly
every one who mentions them speaks of their extreme resemblance
to seeds. Göldi[192] has suggested that this is for the purpose of
deceiving Ichneumons; it is, however, on record that the eggs are
actually destroyed by Ichneumons. It is worthy of notice that the
eggs are shed like seeds, being dropped loosely and, as we have
said, remaining on the ground or elsewhere, sometimes for nearly
two years, without other protection than that they derive from their
coverings. Each egg is really a capsule containing an egg, reminding
us thus of the capsule of the Blattidae, which contains, however,
always a number of eggs. Not only do the eggs have a history like
that of seeds, and resemble them in appearance, but their capsule in
minute structure, as we shall subsequently show, greatly resembles
vegetable tissue. The egg-capsule in Phasmidae is provided with a
lid, which is pushed off when the Insect emerges (Fig. 157). This
capsule induced Murray to suppose that the egg contained within is
really a pupa, and he argued therefrom that in the Orthoptera the
larval stages are passed in the egg, and that the Insect after its
emergence should be looked on as an active pupa that takes food.
Fig. 152.—Eggs of Phasmidae: A, Lonchodes duivenbodi; B,
Platycrania edulis; C, Haplopus grayi; D, Phyllium siccifolium.
(After Kaup.)
The individuals of this group of Insects possess the power of

reproducing a lost limb; and Scudder, who has made some
experiments as to this,[193] states that if a leg be cut off beyond the
trochantero-femoral articulation, the parts remaining outside of this
joint are dropped before the next moult, and are afterwards renewed
either as a straight short stump in which the articulations are already
observable, or as a miniature leg, the femur of which is straight and
the tibia and tarsus curved into a nearly complete circle; in the
former case, the leg assumes at the next moult the appearance that
it has in the second case; this latter form is always changed at the
succeeding moult into a leg resembling the normal limb in every
respect excepting size, and the absence of the fourth tarsal joint
(Fig. 153). If the leg be removed nearer to the body than the
trochantero-femoral articulation the limb is not replaced.
The sexes are frequently extremely different; the female is usually

very much larger than the male. This latter sex often possesses
wings when they are quite wanting in the other sex; the resemblance
to portions of plants is often very much greater in the female than it
is in the male.
Fig. 153.—Cyphocrania aestuans; individual in which the right front leg
has been renewed. Senegal. (After Westwood.)
We have pointed out that the tegmina or upper wings are usually of
small size or absent (Fig. 150, Aschipasma catadromus), even in the
species where the lower wings are very largely developed; in such
cases the latter organs are folded in a complicated, fan-like manner,
and repose on the back, looking as if they were really the tegmina
(Fig. 159, Calvisia atrosignata); this appearance, moreover, is in
some species enhanced much by the fact that the part of the wing
which is outermost in the folded state is quite differently coloured
from the rest of the organ. The colour of the body in many
Phasmidae is said to be very variable, and if the tints be owing to
chlorophyll or other plant juices, finding their way amongst the
Insect-tissues, this is readily understood; in Diapheromera the young
Insect is brownish on hatching, becomes green after feeding, and
turns brown again when the leaves do so. The ocelli, too, are said to
be very variable, and M‘Coy goes so far as to state[194] that they
may be either present or absent in different individuals though of the
same species and sex,—a statement so remarkable as to require
minute examination, though it is to some extent confirmed by the
remarks of other entomologists.
Fig. 154.—Phyllium scythe, female. Sylhet. (After Westwood.)
The resemblance presented by different kinds of Orthoptera to

leaves is so remarkable that it has attracted attention even in
countries where Natural History is almost totally neglected; in many
such places the inhabitants are firmly convinced that the Insects are
truly transformed leaves, by which they understand a bud developing
into a leaf and subsequently becoming a walking-leaf or Insect. To
them the change is a kind of metamorphosis of habit; it grew as a
leaf and then took to walking.[195] It is usually the tegmina that
display this great resemblance to vegetable structures, and there is
perhaps no case in which the phenomenon is more marked than it is
in the genus Phyllium, the members of which occur only in the
tropical regions of the Old World, where they extend from Mauritius
and the Seychelles to the Fiji Islands—possibly even more to the
East—and have, it would appear, a peculiar penchant for insular life.
Fig. 155.—Phyllium scythe, male. Sylhet. (After Murray.)
The genus Phyllium constitutes by itself the tribe Phylliides. Although

the characters and affinities of this group have been only very

Textbook Magnetic Properties of Paramagnetic Compounds Magnetic Susceptibility Data Part 3 1St Edition R T Pardasani Ebook All Chapter PDF

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Textbook Magnetic Properties of Paramagnetic Compounds Magnetic Susceptibility Data Part 3 1St Edition R T Pardasani Ebook All Chapter PDF

Uploaded by

Copyright:

Available Formats

Magnetic Properties of Paramagnetic

Compounds Magnetic Susceptibility

Magnetic Properties of Paramagnetic Compounds Magnetic

Magnetic Properties of Paramagnetic Compounds Magnetic

Magnetic Properties of Paramagnetic Compounds Magnetic

Advances in magnetic materials : processing,

Fundamentals and applications of magnetic materials 1st

Rare earth and transition metal doping of semiconductor

Nuclear Magnetic Resonance Vasudevan Ramesh

Magnetic Monopole Noise Ritika Dusad

Magnetic Susceptibility Data

Group II: Molecules and Radicals

Units and Fundamental Constants in Physics and Chemistry

Elementary Particles, Nuclei and Atoms (Group I)

Molecules and Radicals (Group II)

Condensed Matter (Group III)

Physical Chemistry (Group IV)

Astronomy and Astrophysics (Group VI)

Biophysics (Group VII)

Advanced Materials and Technologies (Group VIII)

Magnetic Susceptibility Data – Part 3

ISSN 1615-1852 ISSN 1616-9530 (electronic)

Library of Congress Control Number: 2015940003

© Springer-Verlag Berlin Heidelberg 2016

Printed on acid-free paper

This Springer imprint is published by Springer Nature

New Delhi Archana Gupta

Magnetic properties of (nitrato)tetrakis(pyridazine)copper(II)nitrate . . . . . . . . . . . . . . . . . . . 61

Magnetic properties of copper(II) bromide complex with 1, 2, 4-triazole . . . . . . . . . . . . . . . . . 124

Magnetic properties of binuclear copper(II) complexes of pyridoxal picolinoyl hydrazine . . . . 178

Magnetic properties of mixed ligand copper(II) chelate containing N, N-dimethyl-1,

Magnetic properties of bis(dimethyl sulfoxide) adduct of tetra-μ-formato-dicopper(II);

Magnetic properties of copper(II) dibromide complex of 2-acetylpyridine-3-(4-methyl)

Magnetic properties of dimeric copper(II) complex of fluorenone thiosemicarbazonate . . . . . . 381

Magnetic properties of acetylacetonato derivative of mono (dizirconium-ennea-isopropoxy)

Magnetic properties of dinuclear copper(II) complex of Schiff base derived from

Magnetic properties of copper(II) mixed ligand complex with 2-pyridinone and

Magnetic properties of gadolinium(III)-copper(II) squarate . . . . . . . . . . . . . . . . . . . . . . . . . . 572

Magnetic properties of μ-(dichloro)bis[(trimethylsilyl) benzamidinato]-N, N, N0 , N0 -

Magnetic properties of t-butylcyanide adduct of half-open, 2,

Magnetic properties of oxovanadiun complex with dinucleating tetraaminodiphenol . . . . . . . 719

Magnetic properties of homobimetallic vanadium d2-d2 complex with triyne . . . . . . . . . . . . . 775

Magnetic properties of vanadium(IV) complex with Schiff-base ligand derived from

Magnetic properties of chromium(III) complex with 5-(2-hydroxy-benzylidene)

Magnetic properties of heterodinuclear copper(II)- chromium(III) complex with N,

Magnetic properties of binuclear bis(acetylacetonato) chromium(III) complex bridged by 1,

Magnetic properties of hydrotris(pyrazolyl)borate complex of molybdenum carbonyl . . . . . . 1088

Magnetic properties of oxomolybdenum(V) complex with hydrazone derived from

A Mantis has been recorded as bearing a close resemblance to a

Fig. 141.—Mantoida luteola Westw., male. Santarem.

The simplest forms of the family are found in the groups

In the genus Pyrgomantis (Fig. 142, P. singularis, female) the male

Fig. 142.—Pyrgomantis singularis, female. S. Africa. (After Westwood.)

Fig. 143.—Outline of Chaeradodis cancellata ♀, nymph. (After Wood-

The variety of shape and external appearance in this family is very

Fig. 144.—Eremiaphila turcica. (After Westwood.)

Wood-Mason informs us[182] that the young of Hymenopus bicornis

"Dr. Anderson went on to say that he had succeeded in identifying

That we should have no more precise information as to a large

The very curious Insect represented in Fig. 147, Stenophylla

Dufour has recorded that Mantis religiosa possesses the power of

Fig. 147.—Stenophylla cornigera. Brazil. (After Westwood.)

The geological record as to Mantidae is very meagre and