THC HIN:

V TN LUT_0605393
PHM XUN NGUYN_0604441
LP DHHO2A

Bi 08
XC NH DN IN CA DUNG DCH CHT IN LY
Nhn xt ca Gio vin im

Tng trnh th nghim

Ta o c LKCL= 1139.10-6 S/cm 310C
Tra bng dn in ring ca dd KCl 0.01 N nhit 310C ta c
c KCl = 1580.10-6 ( S .cm -1 )
Nh ta bit c = k .L ( S / cm) (1)
Hng s bnh ic cc
c KCl 1580.10-6
k= = = 1.3872
LKCl 1139.10-6
i vi dd CH3COOH
Ta xc nh dn in ng lng l theo biu thc sau :
1000.c
l= ( S .cm -1.dl -1 )
CN
Cch xc nh c theo biu thc (1) trn v do CH3COOH l 1 cht
l
in ly yu nn :H s phn ly a=
l0
Trong l0 l dn in ng lng nng dd v cng long
hay cn gi l dn in ng lng ti hn c xc nh qua biu thc
hng s in ly :
l 2 .C
K=
l0 (l0 - l )
Nng dd cht in
0.125 0.0625 0.0313 0.0156
ly C (N)
dn in ca cht
2234 1592 1114 789
in ly L(S/cm )
dn in ring ca
0.0031 0.0022 0.0015 0.0011
dd in ly (S/cm)
dn in ng
24.7917 35.3343 49.4503 70.0471
lng (S.cm-1. l-1)
1/ 0.0403 0.0283 0.0202 0.0143

C 3.0990 2.2084 1.5453 1.0945

1
th - l .C
l

1 1
T th - l.C trn ta c c = 7.10 -5 l0 = 14285.7143 ( S.cm1.dl -1 )
l l0

1
V = 0, 0129 K = 3,8.10-7
l0 .K
 ng vi mi nng dd ca cht in ly ta c mt h s phn ly khc
l
nhau a =
l0

CCH 3COOH ( N ) 0.125 0.0625 0.0313 0.0156

a 0.0017 0.0025 0.0035 0.0049

Vy h s phn ly ca dd in ly yu CH3COOH l

0.0017 + 0.0025 + 0.0035 + 0.0049

a= = 0.0031
4
i vi dd HCl

V HCl l mt cht in ly mnh nn ta c h s phn ly a 1

Cc thng s ta tnh tan tng t nh i vi dd CH3COOH trn

Nng dd cht in
0.001 0.002 0.003 0.004
ly C (N)
dn in ca cht
1767 863 563 346
in ly L(S/cm )
dn in ring
ca dd in ly 0.0025 0.0012 0.0008 0.0005
(S/cm)
dn in ng
2451.1506 598.5690 260.3278 119.9912
lng (S.cm-1. l1)
C 0.0316 0.0447 0.0548 0.0632

Da vo h thc Onsager Kohirauch p dng cho dd long ca cht

in ly mnh:

l = l0 - A. C
 th l - C

T th l - C trn ta c c l0 = 4401.2
1 -1
( S .cm .dl )
Nhn xt
dn n ca dung dch ph thuc rt nhiu vo nng ban
du ca dung dch , nng dung dch cng ln th dn in cng ln
nhng dung dch c nng qu ln (m c) th dn in ca dung
dch tng i thp.cho nn s bin i dn in y ch cn qui v
mi lin h vi s bin i nng , m s bin i nng c s nh
hng trc tip n phn ly ( tc l n s ion thc t tn ti trong dung
dch). Mt khc nh hng n tc chuyn ng cc ion.
Da vo th ta thy nng tng ln khi dai lng l gim xung,
lc u gim nhanh lc sau gim chm.